• Journal of Semiconductors
  • Vol. 40, Issue 10, 101801 (2019)
Jun Hu1、2, Hongyuan Wei1、2, Shaoyan Yang1、2, Chengming Li1、2, Huijie Li1、2, Xianglin Liu1、2, Lianshan Wang1、2, and Zhanguo Wang1、2
Author Affiliations
  • 1Key Laboratory of Semiconductor Materials Science, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, China
  • 2Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
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    DOI: 10.1088/1674-4926/40/10/101801 Cite this Article
    Jun Hu, Hongyuan Wei, Shaoyan Yang, Chengming Li, Huijie Li, Xianglin Liu, Lianshan Wang, Zhanguo Wang. Hydride vapor phase epitaxy for gallium nitride substrate[J]. Journal of Semiconductors, 2019, 40(10): 101801 Copy Citation Text show less

    Abstract

    Due to the remarkable growth rate compared to another growth methods for gallium nitride (GaN) growth, hydride vapor phase epitaxy (HVPE) is now the only method for mass product GaN substrates. In this review, commercial HVPE systems and the GaN crystals grown by them are demonstrated. This article also illustrates some innovative attempts to develop homebuilt HVPE systems. Finally, the prospects for the further development of HVPE for GaN crystal growth in the future are also discussed.
    ${\rm{Ga}\left({\rm{l}} \right) + {\rm{HCl}}\left({\rm{g}} \right) \Leftrightarrow {\rm{GaCl}}\left({\rm{g}}\right) + \frac{1}{2}{{\rm{H}}_2}\left({\rm{g}} \right).} $ (1)

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    ${\rm{GaCl}\left({\rm{g}}\right) + {\rm{NH}_3}\left({\rm{g}}\right) \Leftrightarrow {\rm{GaN}}\left({\rm{s}}\right) + {\rm{HCl}} \left({\rm{g}} \right) + {{\rm{H}}_2}\left({\rm{g}} \right).} $ (2)

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    ${\rm{Ga}\left({\rm{g}}\right) + {\rm{NH}_3}\left({\rm{g}} \right) \to {\rm{GaN}}\left({\rm{s}}\right) + \frac{3}{2}{{\rm{H}}_2}\left( {\rm{g}} \right).} $ (3)

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    ${\rm{Ga}}\left({\rm l}\right) +\dfrac{1}{2}{\rm{Cl}}_2({\rm{g}}) \to {\rm{GaCl}}\left({\rm{g}}\right),$ (4)

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    ${\rm{GaCl}}\left({\rm{g}}\right) +{\rm{Cl}}_2({\rm{g}}) \to {\rm{GaCl}}_3\left({\rm{g}}\right).$ (5)

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    ${\rm{GaCl}}_3\left({\rm{g}}\right) +{\rm{NH}}_3({\rm{g}}) \Leftrightarrow {\rm{GaN}}\left({\rm{s}}\right)+3{\rm{HCl}}({\rm{g}}).$ (6)

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    Jun Hu, Hongyuan Wei, Shaoyan Yang, Chengming Li, Huijie Li, Xianglin Liu, Lianshan Wang, Zhanguo Wang. Hydride vapor phase epitaxy for gallium nitride substrate[J]. Journal of Semiconductors, 2019, 40(10): 101801
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