• Photonics Research
  • Vol. 10, Issue 6, 1440 (2022)
Guohui Li1, Huihui Pi1, Yanfu Wei1, Bolin Zhou1, Ya Gao1, Rong Wen1, Yuying Hao1, Han Zhang2、4, Beng S. Ong3、5, and Yanxia Cui1、*
Author Affiliations
  • 1College of Physics and Optoelectronics, Key Laboratory of Interface Science and Engineering in Advanced Materials, Key Laboratory of Advanced Transducers and Intelligent Control System of Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, China
  • 2Collaborative Innovation Centre for Optoelectronic Science and Technology, Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Physics and Optoelectronic Engineering, Shenzhen Key Laboratory of Micro-Nano Photonic Information Technology, Guangdong Laboratory of Artificial Intelligence and Digital Economy (SZ), Shenzhen University, Shenzhen 518060, China
  • 3Department of Chemistry, Research Centre of Excellence for Organic Electronics, Institute of Advanced Materials, Hong Kong Baptist University, Kowloon Tong, Hong Kong, China
  • 4e-mail: hzhang@szu.edu.cn
  • 5e-mail: bong@hkbu.edu.hk
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    DOI: 10.1364/PRJ.452620 Cite this Article Set citation alerts
    Guohui Li, Huihui Pi, Yanfu Wei, Bolin Zhou, Ya Gao, Rong Wen, Yuying Hao, Han Zhang, Beng S. Ong, Yanxia Cui. Passivation of degradation path enables high performance perovskite nanoplatelet lasers with high operational stability[J]. Photonics Research, 2022, 10(6): 1440 Copy Citation Text show less

    Abstract

    MAPbI3 perovskite has attracted widespread interests for developing low-cost near infrared semiconductor gain media. However, it faces the instability issue under operation conditions, which remains a critical challenge. It is found that the instability of the MAPbI3 nanoplatelet laser comes from the thermal-induced degradation progressing from the surface defects towards neighboring regions. By using PbI2 passivation, the defect-initiated degradation is significantly suppressed and the nanoplatelet degrades in a layer-by-layer way, enabling the MAPbI3 laser to sustain for 4500 s (2.7×107 pulses), which is nearly three times longer than that of the nanoplatelet laser without passivation. Meanwhile, the PbI2 passivated MAPbI3 nanoplatelet laser with the nanoplatelet cavity displays a maximum quality factor up to 7800, the highest reported for all MAPbI3 nanoplatelet cavities. Furthermore, a high stability MAPbI3 nanoplatelet laser that can last for 8500 s (5.1×107 pulses) is demonstrated based on a dual passivation strategy, by retarding the defect-initiated degradation and surface-initiated degradation simultaneously. This work provides in-depth insights for understanding the operating degradation of perovskite lasers, and the dual passivation strategy paves the way for developing high stability near infrared semiconductor laser media.
    E(z,t)=E0exp[i(ωtkz)]·exp{[iΔk+γ(ω)/2]z},(C1)

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    γ(ω)=λ2ΔN8πn2τspg(v),(C2)

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    P0=VmIsl(γlLi+T1)T,(C3)

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    I=I0exp(αz),(C4)

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    Guohui Li, Huihui Pi, Yanfu Wei, Bolin Zhou, Ya Gao, Rong Wen, Yuying Hao, Han Zhang, Beng S. Ong, Yanxia Cui. Passivation of degradation path enables high performance perovskite nanoplatelet lasers with high operational stability[J]. Photonics Research, 2022, 10(6): 1440
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