Photonic topological insulators protected by the lattice spatial symmetry (e.g., inversion and rotation symmetry) mainly support single type edge state, interpreted by either valley or pseudo-spin. Here, we demonstrate theoretically, numerically, and experimentally that a type of judiciously designed two-dimensional Kekulé photonic crystal with time reversal symmetry can possess topological valley and pseudo-spin edge states in different frequency bands. Topologically robust transportation of both the valley and pseudo-spin edge states was confirmed by measuring the transmission of straight and z-shaped interface supported edge mode and comparing with bulk modes in the microwave frequency regime. In addition, we show that due to the distinct topological origins, valley and pseudo-spin edge states can be distinguished by examining their end-scattering into the free space. Our system provides an alternative way in manipulating electromagnetic waves with additional degree-of-freedom, which has potential applications for robust and high-capacity waveguiding and multi-mode dividing.