Fig. 1. Preliminary study of pure 3D perovskites and their blue PeLEDs. (
a) Schematic diagram of the structure of 3D perovskites. (
b) Photoluminescence spectra of MAPb(Br
1−xCl
x)
3 perovskite film with different ratios of Cl
-. (
c) SEM image of MAPb(Br
1−xCl
x)
3 perovskite film on ITO/PEDOT:PSS substrate. (
d) Normalized EL spectra of CH
3NH
3Pb(Br
xCl
1−x)
3 [0 ≤
x ≤ 1] perovskite thin-film-based LEDs with different chloride−bromide ratios, as indicated and measured at 77 K. Figure reproduced with permission from: (a-c) ref.
35, American Chemical Society; (d) ref.
36, American Chemical Society.
Fig. 2. Morphology and PLQY modification for 3D perovskites and their blue PeLEDs. (
a) The calculated coverage degree and average grain size of perovskite films with various CsBr:RbBr molar ratios. (
b) EL spectra of the device fabricated with cocktail cation strategy operating under different voltages. The inset shows a digital photograph of a device in operation. (
c) PLQY measurements with various Mn doping ratios. (
d) Time-resolved photoluminescence (TRPL) decays of samples A (deep-blue region), B (blue region), and C (sky-blue region). Figure reproduced with permission from: (a) ref.
39, Royal Society of Chemistry; (b) ref.
40, American Chemical Society; (c) ref.
41, American Chemical Society; (d) ref.
42, American Chemical Society.
Fig. 3. Spectral tuning strategies for PQDs and their blue PeLEDs. (
a) Schematic diagram of CsPbBr
xCl
3-x QD-based blue PeLED device structure by the DDAB/DDAC post-treatment strategy. (
b) EL spectra of CsPbBr
xCl
3−x QD-based PeLEDs with various ratios of DDAB and DDAC in precursor solution. The inset shows a digital photograph of the device in operation. (
c) Schematic diagram of the halogen exchange process in PQDs enhanced by benzenesulfonates. Figure reproduced with permission from: (a) ref.
53, American Chemical Society; (b) ref.
54, American Chemical Society; (c) ref.
55, American Chemical Society.
Fig. 4. Defects passivation strategies for PQDs and their blue PeLEDs. (
a) TRPL curves of pristine, RbBr-modified, and FABr/RbBr-modified PQD films. (
b) PLQY of Ni
2+ ion-doped CsPbCl
xBr
3−x PQDs in dispersion with NiCl
2 precursor feeding amounts of 0, 0.01, 0.02, 0.04, and 0.08 ml. The inset shows photographs of the Ni
2+ ion-doped CsPbCl
xBr
3−x PQDs under 365 nm UV lamp illumination. (
c) Illustration of Cl vacancy-induced trap site formation, electron trapping, and self-assembly of DAT on the defect sites of perovskite films. (
d) EL spectra of Cs
3Cu
2I
5 QD-based PeLEDs measured before aging, after running for 108 and 170 h, and after a relaxation time of 1 h. Figure reproduced with permission from: (a) ref.
63, Royal Society of Chemistry; (b) ref.
65, American Chemical Society; (c) ref.
68, American Chemical Society; (d) ref.
70, American Chemical Society.
Fig. 5. Dimension tuning and surface passivation strategies for PNLs and their blue PeLEDs. (
a) A digital photograph of the first colloidal PNL-based pure-blue LED in operation (area: 3 mm × 5 mm). (
b) Schematic diagram of colloidal NPLs treated by DDAB. (
c) EL spectra of the colloidal PNL-based PeLEDs fabricated by Bohn et al. with PbBr
2 post-treatment strategy. The inset shows digital photographs of a device in operation. (
d) Illustration of in-situ passivation strategy of PbBr
64− octahedra. Figure reproduced with permission from: (a) ref.
74, American Chemical Society; (b) ref.
75, American Chemical Society; (c) ref.
76, American Chemical Society; (d) ref.
78, American Chemical Society.
Fig. 6. Phases modulation strategies for quasi-2D perovskite and their PeLEDs. (
a) EL spectra of BA cations-based quasi-2D PeLEDs. (
b) PLQY and trap density curves of quasi-2D perovskite film with various concentration of PEABr. (
c) PL spectra of Rb-Cs alloyed perovskite films with various composition. (
d) Transient absorption spectra of PEA
2MA
1.5Pb
2.5Br
8.5 with various molar ratio of IPABr from 0 to 40%. Figure reproduced with permission from: (a) ref.
85, American Chemical Society; (b) ref.
87, Springer Nature; (c) ref.
89, Springer Nature; (d) ref.
91, Springer Nature.
Fig. 7. Spectral stability modification strategies for quasi-2D perovskite and their PeLEDs. (
a) Schematic diagram of the yttrium gradient distribution in the CsPbBr
3:PEACl (1:1) film and its function in increasing the bandgap around the grain surface. (
b) Stable EL spectra of DPPOCl-treated PeLEDs before and after operation. The inset is the schematic diagram of the mechanism of the DPPOCl induced chlorides-insertion-immobilization process. (
c) EL spectra of moisture-treated blue emissive device operated under a different bias with moral ratio of CsBr: PbBr
2 of 2.2. Figure reproduced with permission from: (a) ref.
98, Springer Nature; (b) ref.
99, American Chemical Society; (c) ref.
104, American Chemical Society.
Fig. 8. Interface modification strategies for blue PeLEDs. (
a) Device structure of quasi-2D blue PeLEDs with LiF as the interface modification layer. (
b) Energy level alignment diagram of blue PeLEDs with device structure of LiF-perovskite-LiF. (
c) Device structure and (
d) cross-section picture of quasi-2D PeLEDs with RbCl as the interface modification layer. Figure reproduced from: (a) ref.
86, American Chemical Society; (b) ref.
40, American Chemical Society; (c) and (d) ref.
110, American Chemical Society.
Fig. 9. Energy level alignments of various ETL, HTL, and emissive layer materials.
Year | Type | Device Structure | Device performance | λ(EL)/FWHM (nm/nm)
| EQE (%) | Max lumin (cd/m2)
| CE (cd/A) | VT (V)
| Ref | 2016 | 3D Bulk | ITO/PEDOT:PSS/Pero/TPBi/Ca/Al | 490/30 | - | 154 | 0.08 | 4.1 | Ref.37 | 2017 | 3D Bulk | ITO/ZnO/Pero/NPD/MoO3/Al | 475/- | 1.7 | 3567 | 11.31 | 3.2 | Ref.38 | 2018 | 3D Bulk | ITO/AZO:Cs/Pero/CuS-GaSnO/WO3/Ag | 475/19 | 2.58 | 6426 | 15.21 | 3.1 | Ref.105 | 2019 | 3D Bulk | ITO/PEDOT:PSS/Pero/TPBi/LiF/Al | 490/ | 0.58 | 1470 | - | ~4.2 | Ref.41 | 2019 | 3D Bulk | ITO/PEDOT:PSS/Pero/TyPmPb/LiF/Al | 468/20, 492/20 | 0.062, 0.17 | 112,244 | 0.06, 0.32 | 4.4,3.4 | Ref.39 | 2019 | 3D Bulk | ITO/NiOx/Pero/TPBi/LiF/Al | 456/24, 468/23, 480/20 | 0.15, 0.38, 0.05 | 51,121,87 | 0.07, 0.21, 0.04 | 4,3.5,4 | Ref.42 | 2020 | 3D Bulk | ITO/PEDOT:PSS/RbCl/pero/Tmpypb/LiF/Al | 484/12 | 1.66 | 9243 | 2.15 | 2.6 | Ref.110 | 2020 | 3D Bulk | ITO/LiF/pero//LiF/Bphen/Al | 484/22 | 2.01 | 4015 | 2.11 | ~4 | Ref.40 | 2015 | NC | ITO/PEDOT:PSS/PVK/Pero/TPBi/LiF/Al | 455/20 | 0.07 | 742 | 0.14 | 5.1 | Ref.43 | 2016 | NC | ITO/ZnO/Pero/TFB/MoO3/Ag | 480/17 | 0.0074 | 8.7 | - | 5.5 | Ref.48 | 2016 | NC | ITO/PEDOT:PSS/PVK/Pero/TPBi/LiF/Al | 445/30 | 1.18 | 2473 | - | ~7.8 | Ref.50 | 2016 | NC | ITO/PEDOT:PSS/PVK/Pero/TPBi/LiF/Al | 490/19 | 1.9 | 35 | - | 3 | Ref.45 | 2017 | NC | ITO/NiOx/Pero/TPBi/LiF/Al | 470/20 | 0.07 | 350 | 0.18 | ~5 | Ref.51 | 2018 | NC | ITO/PEDOT:PSS/PVK/Pero/TPBi/LiF/Al | 465/15.6 | ~0.2 | ~100 | 0.1 | ~6 | Ref.52 | 2018 | NC | ITO/TFB/PFI/Pero/TPBi/LiF/Al | 469/25 | 0.5 | 111 | - | ~5 | Ref.107 | 2018 | NC | ITO/POLY-TPD/Pero/TPBi/LiF/Al | 466/23, 502/23 | 0.61, 3.6 | 39, 750 | 8.5@502 nm | ~4 | Ref.63 | 2018 | NC | ITO/PEDOT/TFB/PFI/Pero/TPBi/LiF/Al | 466/17.1 | 2.12 | 389 | - | 4 | Ref.64 | 2019 | NC | ITO/PEDOT:PSS/POLY-TPD/CBP/Pero/B3PyMpM/LiF/Al | 463/14 | 1.4 | 318 | - | 2.9 | Ref.49 | 2019 | NC | ITO/PEDOT:PSS/POLY-TPD/Pero/TPBi/LiF/Al | 458/18,469/18, 479/18 | 0.1,0.44,0.86 | 3.87, 11.95, 29.95 | 0.06, 0.28, 0.77 | 4.5,4,3.5 | Ref.53 | 2019 | NC | ITO/PEDOT:PSS/POLY-TPD/PVK/Pero/B3PYMPM/TPBi/LiF/Al | 463/18, 476/18, 490/18 | 1.03, 2.25,3.5 | 193, 678, 2063 | - | 3-3.4 | Ref.54 | 2019 | NC | ITO/PEDOT:PSS/POLY-TPD/Pero/TPBi/LiF/Al | 476/20 | 1.96 | 212.9 | - | 3.2 | Ref.47 | 2020 | NC | ITO/TFB/PFI/Pero/3TPYMP/Liq/Al | 471/17 | 6.2 | 465 | - | - | Ref.68 | 2020 | NC | ITO/PEDOT:PSS/TFB/PFI/Pero/TPBi/LiF/Al | 470/- | 2.4 | 612 | - | 3.2 | Ref.65 | 2020 | NC | ITO/PEDOT:PSS/POLY-TPD/Pero/TPBi/Ca/Ag | 469/18, 479/18, 489/18, 496/18 | 0.65,1,1.8,2.6 | 30,119, 182,603 | 0.47, 0.94, 2.4,4.5 | 3.8,3.2,
3.4,3.2
| Ref.55 | 2020 | NC | ITO/NiOx/Pero/TPBi/LiF/Al | 445/- | 1.12 | 262.6 | | 4.5 | Ref.70 | 2020 | NC | ITO/PEDOT:PSS/POLY-TPD/Pero/TPBi/LiF/Al | 459/- | 0.3 | 76 | 0.3 | - | Ref.66 | 2020 | NC | ITO/PEDOT:PSS/PTAA/Pero/TPBi/LiF/Al | 479/20 | 12.3 | ~600 | - | 2.8 | Ref.48 | 2020 | NC | ITO/PEDOT:PSS/POLY-TPD/PVKPero/TyPmPB/LiF/Al | 462/19, 465/19, 468/20, 470/21 | 0.77,0.92,1.53,
2.15
| 450,518, 620,507 | 4.5, 5.1, 5.4,6.0 | 4.4,4.6,
4.8,4.9
| Ref.67 | 2020 | NC | ITO/PEDOT:PSS/TFB/OAM-ClPero/TPBi/Liq/Al | 456/16 | 1.1 | 43.2 | - | 5.4 | Ref.69 | 2020 | NC | ITO/PEDOT:PSS/TFB/PFI/Pero/TPBi/LiF/Al | 463/17 | 3.3 | 569 | - | 4 | Ref.46 | 2020 | NC | ITO/PEDOT:PSS/POLY-TPD/PFN-X/Pero/TPBi/LiF/Al | 470/17 | 1.34 | 46.7 | 1.24 | 3 | Ref.109 | 2016 | NPL | ITO/PEDOT:PSS/PVK/Host layer/Pero/TPBi/LiF/Al | 432/25, 456/25, 492/25 | 0.23, 0.0240.004 | 8.5 | - | 3.5 | Ref.74 | 2018 | NPL | ITO/PEDOT:PSS/POLY-TPD/Pero/TPBi/LiF/Al | 480/- | ~0.1 | 25 | - | 4.6 | Ref.77 | 2018 | NPL | ITO/PEDOT:PSS/POLY-TPD/Pero/TPBi/Ca/Ag | 464/20 | 0.057 | 38 | - | 3.6 | Ref.76 | 2018 | NPL | ITO/PEDOT:PSS/POLY-TPD/Pero/TPBi/LiF/Al | 463/12 | 0.124 | 62 | 0.117 | 4.2 | Ref.78 | 2019 | NPL | ITO/PEDOT:PSS/TFB or POLY-TPD/Pero/TPBi/Ca/Ag | 464/16, 489/25 | 0.3,0.55 | 48,40 | 0.3,1.1 | 4 | Ref.106 | 2019 | NPL | ITO/PEDOT:PSS/POLY-TPD/Pero/TPBi/LiF/Al | 464/18, 490/18 | 0.11, 0.87 | 71,186 | - | 4 | Ref.56 | 2019 | NPL | ITO/PEDOT/POLY-TPD/CBP/Pero/TPBi/LiF/Al | 469/- | 1.42 | 41.8 | - | 3 | Ref.75 | 2020 | NPL | ITO/POLY-TPD/MoO3/Pero/TyPmPB/LiF/Al | 439/14 | 0.14 | 9.7 | - | 3.6 | Ref.83 | 2016 | Quasi-2D | ITO/PEDOT:PSS/Pero/TPBi/Ca/Al | 410/14 | 0.038 | - | - | 2.5 | Ref.94 | 2016 | Quasi-2D | ITO/ZnO/PEIE/Pero/TFB/MoOx/Al | 491/broad | 0.015 | 186 | - | 2.9 | Ref.82 | 2016 | Quasi-2D | ITO/PEDOT:PSS/POLY-TPD/QW-Pero/TPBi/LiF/Al | 468/28 | 0.01 | 21 | 0.006 | 5.2 | Ref.74 | 2016 | Quasi-2D | ITO/PEDOT:PSS/Pero/TPBi/Ba/Al | 462/broad,
480/broad
| 0.06,1.1 | 1.62, 19.25 | 0.07,2.1 | - | Ref.79 | 2017 | Quasi-2D | ITO/PEDOT:PSS/Pero/TypmpB/CsF/Al | 485/broad | 2.6 | 200 | - | 3.4 | Ref.84 | 2018 | Quasi-2D | ITO/PEDOT:PSS/NiOx/PVK/Pero/TPBi/LiF/Al | 490/28 | 1.5 | 2480 | 2.8 | 5 | Ref.91 | 2018 | Quasi-2D | ITO/PEDOT:PSS/PVK/Pero/TPBi/LiF/Al | 465/23, 487/22 | 2.4,6.2 | 962, 3340 | 1 | 5, 4.5 | Ref.85 | 2018 | Quasi-2D | ITO/NiOx/LiF/Pero/TPBi/LiF/Al | 473/24, 481/24,490/24 | 0.16, 0.25, 0.52 | 217, 509, 1446 | - | 3.5 | Ref.86 | 2019 | Quasi-2D | ITO/PEDOT:PSS/Pero/TPBi/LiF/Al | 480/21 | 5.7 | 3780 | 6.2 | 3.2 | Ref.87 | 2020 | Quasi-2D | ITO/PVK:F4-TCNQ/Pero/TPPO/TPBi/LiF/Al | 492/18 | 8.2 | 1687 | 13.1 | ~3.8 | Ref.88 | 2019 | Quasi-2D | ITO/PEDOT:PSS/Pero/Tmpypb/LiF/Al | 475/25 | 1.35 | 100.6 | ~1 | ~3 | Ref.89 | 2019 | Quasi-2D | ITO/PVK/Pero/TPBi/LiF/Al | 474/34,484/34 | 0.002, 0.13 | 4,45 | 0.002, 0.14 | ~3 | Ref.102 | 2019 | Quasi-2D | ITO/PEDOT/PVK:10%TAPC/Pero/TPBi/Ca/Ag | 410/11.6 | 0.31 | 147.6 | 0.19 | 4.2 | Ref.95 | 2019 | Quasi-2D | ITO/NiOx/PSSNa/Pero/TPBi/LiF/Al | 493/25 | 1.45 | 5737 | 2.25 | 3.3 | Ref.108 | 2019 | Quasi-2D | ITO/NiOx/TFB/PVK/Pero/TPBi/LiF/Al | 483/26 | 9.5 | 700 | - | 3.3 | Ref.90 | 2019 | Quasi-2D | ITO/PVK/PFI/Pero/3TPYMB/Liq/Al | 465/21 | 2.6 | 211 | ~1.3 | 3 | Ref.92 | 2019 | Quasi-2D | ITO/PEDOT:PSS/Pero/TPBi/LiF/Al | 468/25 | 0.71 | 122 | 0.78 | 4.5 | Ref.97 | 2019 | Quasi-2D | ITO/PEDOT:PSS or NiOx/Pero/TPBi/LiF/Al | 480/-, 490/-, 499/- | 1.43,2.4,1.58 | 919,2825,7759 | 1.53, 3.67 | 3.5,3.3,
4.4
| Ref.102 | 2019 | Quasi-2D | ITO/PVK/Pero/PO-T2T/Liq/Al | 485/23 | 2.62 | 1200 | - | 2.6 | Ref.103 | 2019 | Quasi-2D | ITO/PEDOT:PSS/Pero/TPBi/LiF/Al | 487/- | 11 | 9048 | - | ~3 | Ref.98 | 2019 | Quasi-2D | ITO/NiOx:F6TCNNQ/PVK/Pero/TPBi/Cs2CO3/Al | 456/-, 468/- | 0.0150.026 | - | - | - | Ref.101 | 2020 | Quasi-2D | ITO/PEDOT:PSS/Pero/TPBi/LiF/Al | 450/-, 482/- | 0.7, 1.1 | - | - | - | Ref.96 | 2020 | Quasi-2D | ITO/PEDOT:PSS/Pero/TyPmPB/LiF/Al | 494/- | 2.7 | 465 | 4.3 | 3 | Ref.93 | 2020 | Quasi-2D | ITO/PEDOT:PSS:PFI or POLY-TPD/Pero/TPBi/LiF/Al | 489/18,479/18 | 1.3,5.2 | 5184, 412 | - | ~4 | Ref.99 | 2020 | Quasi-2D | ITO/PEDOT: PSS/Pero/TPBi/Ca/Al | 485/- | 7.84 | 1130 | - | 4.3 | Ref.100 |
|
Table 1. Summary of the main blue PeLEDs.