• Laser & Optoelectronics Progress
  • Vol. 57, Issue 11, 111428 (2020)
Zhaodi Chen, Jichao Li, Shanlin Xiao, Han Yang**, Yuchen Zhang, Ziying Zhao, and Yonglai Zhang*
Author Affiliations
  • State Key Laboratory of Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun, Jilin 130012, China
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    DOI: 10.3788/LOP57.111428 Cite this Article Set citation alerts
    Zhaodi Chen, Jichao Li, Shanlin Xiao, Han Yang, Yuchen Zhang, Ziying Zhao, Yonglai Zhang. Laser Reduced Graphene Oxide for Thin Film Flexible Electronic Devices[J]. Laser & Optoelectronics Progress, 2020, 57(11): 111428 Copy Citation Text show less
    Schematic diagram of graphene oxide and laser reduction of graphene oxide. The big, middle, and small spheres represent oxygen, carbon, and hydrogen atoms, respectively[69]
    Fig. 1. Schematic diagram of graphene oxide and laser reduction of graphene oxide. The big, middle, and small spheres represent oxygen, carbon, and hydrogen atoms, respectively[69]
    Oxygen content and conductivity of graphene oxide are controlled by laser. (a) C1s XPS spectra of GO and LRGO prepared by TBLI at different laser power; (b) relationship between C-C, C-O,C=O and O atom percentage and laser power; (c) I-V curve of LRGO prepared by TBLI at 0.15, 0.2, 0.3 W laser power[79]
    Fig. 2. Oxygen content and conductivity of graphene oxide are controlled by laser. (a) C1s XPS spectra of GO and LRGO prepared by TBLI at different laser power; (b) relationship between C-C, C-O,C=O and O atom percentage and laser power; (c) I-V curve of LRGO prepared by TBLI at 0.15, 0.2, 0.3 W laser power[79]
    Laser micropatterning reduction of graphene oxide. (a) Arcuate microcircuit; (b)comb electrode; (c)involute microcircuit; (d) school emblem of Jilin University; (e) word of “graphene”; (f) letter “G”; (g) molecular structure of benzene ring; (h) hexagonal grid, scale is 10 μm; (i) photo of LRGO electrode array[83]
    Fig. 3. Laser micropatterning reduction of graphene oxide. (a) Arcuate microcircuit; (b)comb electrode; (c)involute microcircuit; (d) school emblem of Jilin University; (e) word of “graphene”; (f) letter “G”; (g) molecular structure of benzene ring; (h) hexagonal grid, scale is 10 μm; (i) photo of LRGO electrode array[83]
    Laser enabled micro/nanostructure of graphene. (a) Schematic diagram of graphene film with micro/nanostructure prepared by TBLI; (b) optical microscope pictures of graphene film with one-dimensional grating structure and (c) two-dimensional grating structure; (d)(e) diffraction spots of 405 nm laser on the LRGO film with one-dimensional and two-dimensional grating structure; (f) structural color of graphene film with micro/nano structure[76]
    Fig. 4. Laser enabled micro/nanostructure of graphene. (a) Schematic diagram of graphene film with micro/nanostructure prepared by TBLI; (b) optical microscope pictures of graphene film with one-dimensional grating structure and (c) two-dimensional grating structure; (d)(e) diffraction spots of 405 nm laser on the LRGO film with one-dimensional and two-dimensional grating structure; (f) structural color of graphene film with micro/nano structure[76]
    N-doped LRGO. (a) C1s XPS spectra of GO and NLRGO prepared at different laser power; (b)(c) N1s spectra of GO and NLRGO prepared at different laser powers; (c) schematic diagram of N-doped graphene and corresponding formation energy calculated from the first principle; (d) relationship between the percentages of pyridine-N/ pyrrole-N and graphite-N and laser power[83]
    Fig. 5. N-doped LRGO. (a) C1s XPS spectra of GO and NLRGO prepared at different laser power; (b)(c) N1s spectra of GO and NLRGO prepared at different laser powers; (c) schematic diagram of N-doped graphene and corresponding formation energy calculated from the first principle; (d) relationship between the percentages of pyridine-N/ pyrrole-N and graphite-N and laser power[83]
    Flexible gas sensor fabricated by laser. (a) Fabrication diagram of flexible NO2 sensor based on In2O3@LRGO film; (b) photo of 2×4 NO2 sensor array processed by laser; (c)(d) sensing performance of NO2 sensor array[90]
    Fig. 6. Flexible gas sensor fabricated by laser. (a) Fabrication diagram of flexible NO2 sensor based on In2O3@LRGO film; (b) photo of 2×4 NO2 sensor array processed by laser; (c)(d) sensing performance of NO2 sensor array[90]
    Graphene-based pressure sensor fabricated by laser. (a) Schematic diagram of graphene-based pressure sensor; (b) sensing mechanism of graphene-based pressure sensor; (c) relationship between conductivity and pressure of graphene-based pressure sensor [sensitivity is 0.96 kPa-1 at low pressure (0-50 kPa), and 0.005 kPa-1 at high pressure (50-113 kPa)]; (d) stability test of graphene-based pressure sensor[93]
    Fig. 7. Graphene-based pressure sensor fabricated by laser. (a) Schematic diagram of graphene-based pressure sensor; (b) sensing mechanism of graphene-based pressure sensor; (c) relationship between conductivity and pressure of graphene-based pressure sensor [sensitivity is 0.96 kPa-1 at low pressure (0-50 kPa), and 0.005 kPa-1 at high pressure (50-113 kPa)]; (d) stability test of graphene-based pressure sensor[93]
    Comparison of mechanical and electrical properties of TGASSs and SSGs. (a) Change of relative resistance of TGASSs with tensile strain; (b) change of relative resistance of SSGs with tensile strain (inset picture showing the difference between TGASSs and SSGs, with the scale of 1cm in both pictures); (c) change of relative resistance of TGASSs and SSGs under different cyclic strains at 0.5 Hz; (d) at 0.1, 0.25, 0.5, and 1.25 Hz, the change of relative resistance of TGASSs under cyclic tension re
    Fig. 8. Comparison of mechanical and electrical properties of TGASSs and SSGs. (a) Change of relative resistance of TGASSs with tensile strain; (b) change of relative resistance of SSGs with tensile strain (inset picture showing the difference between TGASSs and SSGs, with the scale of 1cm in both pictures); (c) change of relative resistance of TGASSs and SSGs under different cyclic strains at 0.5 Hz; (d) at 0.1, 0.25, 0.5, and 1.25 Hz, the change of relative resistance of TGASSs under cyclic tension re
    Graphene-based supercapacitor fabricated by laser. (a) Structure schematic diagram of supercapacitor; (b) principle diagram of all solid state LSG-EC shows that the gel electrolyte can be used as electrolyte and can be used as a separator (inset photographs of the flexibility of supercapacitor); (c) comparison of properties of gel electrolyte and aqueous electrolyte LSG-EC; (d) relationship between the bending angle of the device and its performance[75
    Fig. 9. Graphene-based supercapacitor fabricated by laser. (a) Structure schematic diagram of supercapacitor; (b) principle diagram of all solid state LSG-EC shows that the gel electrolyte can be used as electrolyte and can be used as a separator (inset photographs of the flexibility of supercapacitor); (c) comparison of properties of gel electrolyte and aqueous electrolyte LSG-EC; (d) relationship between the bending angle of the device and its performance[75
    Graphene-based GHEG fabricated by laser. (a) Schematic diagram of GHEG preparation; (b) Voc and Isc of GHEG under periodic relative humidity change (ΔRRH=80%)[102]
    Fig. 10. Graphene-based GHEG fabricated by laser. (a) Schematic diagram of GHEG preparation; (b) Voc and Isc of GHEG under periodic relative humidity change (ΔRRH=80%)[102]
    Zhaodi Chen, Jichao Li, Shanlin Xiao, Han Yang, Yuchen Zhang, Ziying Zhao, Yonglai Zhang. Laser Reduced Graphene Oxide for Thin Film Flexible Electronic Devices[J]. Laser & Optoelectronics Progress, 2020, 57(11): 111428
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