• Acta Optica Sinica
  • Vol. 41, Issue 14, 1430003 (2021)
Hao Liu1、2, Mai Hu2、3, Xiang Chen2, Hao Deng2, Zhenyu Xu2, Qiang Wang4, Xiang Li2, Ruifeng Kan2、aff******, and Xianyi Zhang1、aff***
Author Affiliations
  • 1School of Physics and Electronic Information, Anhui Normal University, Wuhu, Anhui 241002, China
  • 2Key Laboratory of Environmental Optics and Technology, Anhui Institute of Optics and Fine Mechanics, Institute of Physical Science, Chinese Academy of Sciences, Hefei, Anhui 230031, China
  • 3University of Science and Technology of China, Hefei, Anhui 230026, China
  • 4State Key Laboratory of Applied Optics, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun, Jilin 130033, China
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    DOI: 10.3788/AOS202141.1430003 Cite this Article Set citation alerts
    Hao Liu, Mai Hu, Xiang Chen, Hao Deng, Zhenyu Xu, Qiang Wang, Xiang Li, Ruifeng Kan, Xianyi Zhang. Sensitive Detection of CH4 and CO2 Using Frequency-Division-Multiplexing Based Quartz-Enhanced Photoacoustic Spectroscopy[J]. Acta Optica Sinica, 2021, 41(14): 1430003 Copy Citation Text show less

    Abstract

    A compact double-gas sensing system was constructed for the simultaneous sensitive detection of CH4 and CO2,which combines quartz-enhanced photoacoustic spectroscopy (QEPAS) and frequency division multiplexing technique. Two continuous wave distributed feedback (DFB) diode lasers operating at central wavelengths of 1654 nm and 2004 nm were employed as the light sources. The photoacoustic signals were first excited by simultaneously injecting sinusoidal modulation currents with independent frequencies near the resonant frequency of the quartz tuning fork into the lasers, and were then demodulated to obtain the corresponding second harmonic components of CH4 and CO2,and finally the simultaneous detection of CH4 and CO2 was realized. The experimental results showed that there was no disturbance between the photoacoustic signals of these two gases. The relationships of CH4 and CO2 concentrations with their corresponding second harmonic signals were calibrated, and a good linear response result was obtained, in which the linear correlation coefficients were all larger than 0.994. The long time measurement of CH4 with volume fraction of 500×10-6 and CO2 with volume fraction of 2000×10-6 was conducted and the system performance was further evaluated through the Allan deviation analysis. The results indicated that the minimum detection limits of CH4 and CO2 for the system were obtained as 0.58×10-6 and 1.32 ×10-6, corresponding to the normalized noise equivalent absorption coefficients of 7.2×10-9 cm-1·W·Hz1/2 and 9×10-9 cm-1·W·Hz1/2, respectively.
    Hao Liu, Mai Hu, Xiang Chen, Hao Deng, Zhenyu Xu, Qiang Wang, Xiang Li, Ruifeng Kan, Xianyi Zhang. Sensitive Detection of CH4 and CO2 Using Frequency-Division-Multiplexing Based Quartz-Enhanced Photoacoustic Spectroscopy[J]. Acta Optica Sinica, 2021, 41(14): 1430003
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