• Journal of Inorganic Materials
  • Vol. 36, Issue 9, 999 (2021)
Ying WANG1, Wenlong ZHANG1, Yanfeng XING1、*, suqun CAO2, Xinyi DAI3, and Jingze LI4、*
Author Affiliations
  • 11. School of Mechanical and Automobile Engineering, Shanghai University of Engineering Science, Shanghai 201620, China
  • 22. Faculty of Electronic Information Engineering, Huaiyin Institute of Technology, Huaian 223003, China
  • 33. College of Materials and Metallurgy, Guizhou University, Guiyang 550025, China
  • 44. School of Microelectronics and Solid-state Electronics, University of Electronic Science and Technology of China, Chengdu 610054, China
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    DOI: 10.15541/jim20200576 Cite this Article
    Ying WANG, Wenlong ZHANG, Yanfeng XING, suqun CAO, Xinyi DAI, Jingze LI. Performance of Amorphous Lithium Phosphate Coated Lithium Titanate Electrodes in Extended Working Range of 0.01-3.00 V[J]. Journal of Inorganic Materials, 2021, 36(9): 999 Copy Citation Text show less
    XRD patterns of pristine electrode LTOLPO00 and coated electrodes LTOLPO10, LTOLPO20 and LTOLPO40
    1. XRD patterns of pristine electrode LTOLPO00 and coated electrodes LTOLPO10, LTOLPO20 and LTOLPO40
    SEM images of pristine electrode LTOLPO00 (a) and coated electrodes LTOLPO10 (b), LTOLPO20 (c), and LTOLPO40 (d)
    2. SEM images of pristine electrode LTOLPO00 (a) and coated electrodes LTOLPO10 (b), LTOLPO20 (c), and LTOLPO40 (d)
    (a, c) First two discharge-charge curves at 35 mA∙g-1, 22nd discharge-charge curve at 175 mA∙g-1 and (b, d) the corresponding differential capacity plots of (a, b) pristine electrode LTOLPO00 and (c, d) coated electrode LTOLPO20
    3. (a, c) First two discharge-charge curves at 35 mA∙g-1, 22nd discharge-charge curve at 175 mA∙g-1 and (b, d) the corresponding differential capacity plots of (a, b) pristine electrode LTOLPO00 and (c, d) coated electrode LTOLPO20
    (a) Rate performance and (b) long cycle performance of LTOLPO00-LTOLPO40
    4. (a) Rate performance and (b) long cycle performance of LTOLPO00-LTOLPO40
    XRD patterns and (b) Raman spectra of LTOLPO00 and LTOLPO20 before and after discharge-charge tests with inset in (b) showing magnification of Raman shift at 233 cm-1
    5. XRD patterns and (b) Raman spectra of LTOLPO00 and LTOLPO20 before and after discharge-charge tests with inset in (b) showing magnification of Raman shift at 233 cm-1
    EIS plots and the fitted data of (a) LTOLPO00 and (b) LTOLPO20 after discharge-charged for 10 and 100 cycles with insets showing the corresponding equivalent circuits
    6. EIS plots and the fitted data of (a) LTOLPO00 and (b) LTOLPO20 after discharge-charged for 10 and 100 cycles with insets showing the corresponding equivalent circuits
    FT-IR absorption spectra of Li3PO4 sputtered on copper foil for 60 min
    S1. FT-IR absorption spectra of Li3PO4 sputtered on copper foil for 60 min
    EDS result of Li4Ti5O12 electrode sputtered for 40 min (LTOLPO40)
    S2. EDS result of Li4Ti5O12 electrode sputtered for 40 min (LTOLPO40)
    SEM images of (a)primary electrode and (b)Li3PO4 modified electrode (LTOLPO40) after being cycled for 100 times
    S3. SEM images of (a)primary electrode and (b)Li3PO4 modified electrode (LTOLPO40) after being cycled for 100 times
    Cycle performance and galvanostatic discharge-charge test profiles of LTOLPO60
    S4. Cycle performance and galvanostatic discharge-charge test profiles of LTOLPO60
    SampleCycle No.Rs/Ω Rf1/Ω Rf2/Ω Rct/Ω
    LTOLPO0010515-86
    LTOLPO201052118054
    LTOLPO001005364-1019
    LTOLPO20100725146216
    Table 1.

    Fitted data for EIS plots of LTOLPO00 and LTOLPO20 at given cycles

    Ying WANG, Wenlong ZHANG, Yanfeng XING, suqun CAO, Xinyi DAI, Jingze LI. Performance of Amorphous Lithium Phosphate Coated Lithium Titanate Electrodes in Extended Working Range of 0.01-3.00 V[J]. Journal of Inorganic Materials, 2021, 36(9): 999
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