Yiqing ZHANG, Shujuan ZHANG, Zhengrui WAN, Han MO, Niangui WANG, Liqun ZHOU. RuFe Nanoparticles Modified Sheet-like BiVO4 : High-efficient Synergistic Catalyst for Ammonia Borane Hydrolytic Dehydrogenation [J]. Journal of Inorganic Materials, 2020, 35(7): 809
- Journal of Inorganic Materials
- Vol. 35, Issue 7, 809 (2020)
1. XRD patterns of BiVO4, Ru@BiVO4, Fe@BiVO4, Ru1Fe0.1@BiVO4 and Ru1Fe0.1@BiVO4 after five cycles
2. TEM images of BiVO4 (A, B), Ru1Fe0.1@BiVO4 (C) and RuFe NPs (E); particle size distributions of Ru1Fe0.1@BiVO4 (D) and RuFe NPs (F)
3. FESEM image (A); elemental mappings of Ru and Fe (B) and EDS pattern of Ru1Fe0.1@BiVO4 (C)
4. XPS spectra of the Ru1Fe0.1@BiVO4 catalysts
5. FT-IR spectra of BiVO4, Ru1Fe0.1@BiVO4 and Ru1Fe0.1@BiVO4 after five cycles
6. Plots of n (H2)/n (AB) vs. time from the hydrolysis of AB (18.5 mg)
7. Mechanism of AB hydrolysis catalyzed by the Ru1Fe0.1@BiVO4 catalyst
8. Plots of n (H2)/n (AB) vs. time for the hydrolysis of AB catalyzed by Ru1Fe0.1@BiVO4 at different temperatures(A) and corresponding Arrhenius plots (B), and cycling test for the Ru1Fe0.1@BiVO4 within five cycles (C)
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Table 1. ICP-AES analyses results of RuFe@BiVO4 catalyst
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Table 2. Catalytic activities of different Ru-based catalysts used for the hydrolytic dehydrogenation of AB
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