• Laser & Optoelectronics Progress
  • Vol. 58, Issue 15, 1516006 (2021)
Cong Zhang, Di Yang, Kang Shao, and Zaifa Pan*
Author Affiliations
  • College of Chemical Engineering, Zhejiang University of Technology, Hangzhou , Zhejiang 310014, China
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    DOI: 10.3788/LOP202158.1516006 Cite this Article Set citation alerts
    Cong Zhang, Di Yang, Kang Shao, Zaifa Pan. Progress in Thermoluminescence Spectroscopy for Characterization of Trap Distribution in Persistent Luminescence Materials[J]. Laser & Optoelectronics Progress, 2021, 58(15): 1516006 Copy Citation Text show less
    Energy band model of one trap energy level and one luminescence center[38]
    Fig. 1. Energy band model of one trap energy level and one luminescence center[38]
    Influences of different kinetic processes [the first order kinetics (b=1), the second order kinetics (b=2), and the general kinetics (b=1.5)] on shape of TL peak[46]
    Fig. 2. Influences of different kinetic processes [the first order kinetics (b=1), the second order kinetics (b=2), and the general kinetics (b=1.5)] on shape of TL peak[46]
    TL peak location and trap depth of CaMgSi2O6∶Mn2+,Ln3+(Ln=Dy, Pr, Ce, Nd). (a) Normalized TL curves; (b) diagram of energy level relative position in gaps of CaMgSi2O6∶Mn2+,Ln3+ for different rare earth ions[12]
    Fig. 3. TL peak location and trap depth of CaMgSi2O6∶Mn2+,Ln3+(Ln=Dy, Pr, Ce, Nd). (a) Normalized TL curves; (b) diagram of energy level relative position in gaps of CaMgSi2O6∶Mn2+,Ln3+ for different rare earth ions[12]
    TL curves with different heating rates and trap depth analysis[16]. (a) SSON∶Eu; (b) SSON∶Eu,Ce; (c) SSON∶Eu,Nd; (d) SSON∶Eu, Dy; (e) plots of InTm2β~1Tm
    Fig. 4. TL curves with different heating rates and trap depth analysis[16]. (a) SSON∶Eu; (b) SSON∶Eu,Ce; (c) SSON∶Eu,Nd; (d) SSON∶Eu, Dy; (e) plots of InTm2β~1Tm
    Trap analysis of CaS∶Eu2+,Sm3+[20]. (a) Analysis of TL curves by peak shape method; (b) photostimulated excitation spectrum of CaS∶Eu2+,Sm3+
    Fig. 5. Trap analysis of CaS∶Eu2+,Sm3+[20]. (a) Analysis of TL curves by peak shape method; (b) photostimulated excitation spectrum of CaS∶Eu2+,Sm3+
    Diagrams of initial rise method[58]. (a) Selection of initial rise part; (b) Arrhenius plot of ln(I) and 1/T
    Fig. 6. Diagrams of initial rise method[58]. (a) Selection of initial rise part; (b) Arrhenius plot of ln(I) and 1/T
    Fitted results of TL curves of Ba2SiO4∶Dy3+ obtained by computer fitting method (FOM∶1.6)[25]
    Fig. 7. Fitted results of TL curves of Ba2SiO4∶Dy3+ obtained by computer fitting method (FOM∶1.6)[25]
    Process of trap depth-density distribution analysis[59]. (a) Schematic of trap depth distribution as a function of excitation temperature Texc; (b) TL curves under different excitation temperatures Texc; (c) density of trap at a certain depth estimated according to difference of TL integral intensities at two different excitation temperatures; (d) depth-density distribution of trap
    Fig. 8. Process of trap depth-density distribution analysis[59]. (a) Schematic of trap depth distribution as a function of excitation temperature Texc; (b) TL curves under different excitation temperatures Texc; (c) density of trap at a certain depth estimated according to difference of TL integral intensities at two different excitation temperatures; (d) depth-density distribution of trap
    Analysis method of depth-density-time[13]. (a) TL curves for different delay time; (b) trap depth-density-action time distribution
    Fig. 9. Analysis method of depth-density-time[13]. (a) TL curves for different delay time; (b) trap depth-density-action time distribution
    Thermal quenching curves of SrAl2O4∶Eu,Dy and TL curves before and after correction[60]
    Fig. 10. Thermal quenching curves of SrAl2O4∶Eu,Dy and TL curves before and after correction[60]
    MethodPhosphorTL peak /KTrap depth /eVRef. No
    Peak position methodCaMgSi2O6∶Mn2+, Pr3+3500.7012
    Ba2SiO4∶Eu2+,Ho3+355‒3800.71‒0.7613
    Zn1.1Ga1.8Si0.1O4∶Cr3+355, 4170.71, 0.8314
    Y3Sc1.95Ga3O12∶0.05Cr3+3600.7215
    Heating rate methodSrSi2N2O2∶Eu2+,Dy3+375‒4001.0416
    BaSi2O5∶Eu2+,Nd3+450‒5000.9417
    YPO4∶Tb3+,Sm3+-1.5418
    Peak shape methodCaZnOS193,2930.17, 0.5819
    CaS∶Eu2+,Sm3+361, 442, 5180.47, 0.76, 1.0820
    BaSi2O5∶Eu2+,Nd3+4681.2917
    Initial rise methodSrAl2O4∶Eu2+,Dy3+-0.55, 0.60, 0.65, 0.7021
    CaAl2O4∶Eu2+,Nd3+-0.55, 0.6522
    NaLuGeO4∶Bi3+-0.53‒1.3723
    Y3Al2Ga3O12∶Ce3+,V3+-0.85‒1.2124
    Computerized curve fitting methodBa2SiO4410(peak 2)0.5525
    LiMgPO4489 (peak 3)0.8426
    Table 1. Calculated trap depths of persistent luminescence materials by different analysis methods of PL curve
    Cong Zhang, Di Yang, Kang Shao, Zaifa Pan. Progress in Thermoluminescence Spectroscopy for Characterization of Trap Distribution in Persistent Luminescence Materials[J]. Laser & Optoelectronics Progress, 2021, 58(15): 1516006
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