Author Affiliations
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou , Zhejiang 310014, Chinashow less
Fig. 1. Energy band model of one trap energy level and one luminescence center
[38] Fig. 2. Influences of different kinetic processes [the first order kinetics (
b=1), the second order kinetics (
b=2), and the general kinetics (
b=1.5)] on shape of TL peak
[46] Fig. 3. TL peak location and trap depth of CaMgSi
2O
6∶Mn
2+,Ln
3+(Ln=Dy, Pr, Ce, Nd). (a) Normalized TL curves; (b) diagram of energy level relative position in gaps of CaMgSi
2O
6∶Mn
2+,Ln
3+ for different rare earth ions
[12] Fig. 4. TL curves with different heating rates and trap depth analysis
[16]. (a) SSON∶Eu; (b) SSON∶Eu,Ce; (c) SSON∶Eu,Nd; (d) SSON∶Eu, Dy; (e) plots of
Fig. 5. Trap analysis of CaS∶Eu2+,Sm3+[20]. (a) Analysis of TL curves by peak shape method; (b) photostimulated excitation spectrum of CaS∶Eu2+,Sm3+
Fig. 6. Diagrams of initial rise method
[58]. (a) Selection of initial rise part; (b) Arrhenius plot of ln(
I) and 1/
T Fig. 7. Fitted results of TL curves of Ba
2SiO
4∶Dy
3+ obtained by computer fitting method (FOM∶1.6)
[25] Fig. 8. Process of trap depth-density distribution analysis
[59]. (a) Schematic of trap depth distribution as a function of excitation temperature
Texc; (b) TL curves under different excitation temperatures
Texc; (c) density of trap at a certain depth estimated according to difference of TL integral intensities at two different excitation temperatures; (d) depth-density distribution of trap
Fig. 9. Analysis method of depth-density-time
[13]. (a) TL curves for different delay time; (b) trap depth-density-action time distribution
Fig. 10. Thermal quenching curves of SrAl
2O
4∶Eu,Dy and TL curves before and after correction
[60] Method | Phosphor | TL peak /K | Trap depth /eV | Ref. No |
---|
Peak position method | CaMgSi2O6∶Mn2+, Pr3+ | 350 | 0.70 | [12] | Ba2SiO4∶Eu2+,Ho3+ | 355‒380 | 0.71‒0.76 | [13] | Zn1.1Ga1.8Si0.1O4∶Cr3+ | 355, 417 | 0.71, 0.83 | [14] | Y3Sc1.95Ga3O12∶0.05Cr3+ | 360 | 0.72 | [15] | Heating rate method | SrSi2N2O2∶Eu2+,Dy3+ | 375‒400 | 1.04 | [16] | BaSi2O5∶Eu2+,Nd3+ | 450‒500 | 0.94 | [17] | YPO4∶Tb3+,Sm3+ | - | 1.54 | [18] | Peak shape method | CaZnOS | 193,293 | 0.17, 0.58 | [19] | CaS∶Eu2+,Sm3+ | 361, 442, 518 | 0.47, 0.76, 1.08 | [20] | BaSi2O5∶Eu2+,Nd3+ | 468 | 1.29 | [17] | Initial rise method | SrAl2O4∶Eu2+,Dy3+ | - | 0.55, 0.60, 0.65, 0.70 | [21] | CaAl2O4∶Eu2+,Nd3+ | - | 0.55, 0.65 | [22] | NaLuGeO4∶Bi3+ | - | 0.53‒1.37 | [23] | Y3Al2Ga3O12∶Ce3+,V3+ | - | 0.85‒1.21 | [24] | Computerized curve fitting method | Ba2SiO4 | 410(peak 2) | 0.55 | [25] | LiMgPO4 | 489 (peak 3) | 0.84 | [26] |
|
Table 1. Calculated trap depths of persistent luminescence materials by different analysis methods of PL curve