The luminescence properties of two kinds of ruthenium complexes, ［Ru(bpy)3］(ClO4)2 and ［Ru(bpy)2HPIP］(ClO4)2, are studied by steady-state and transient emission spectroscopy. The steady-state luminescence spectrum shows that ［Ru(bpy)2HPIP］(ClO4)2 has a weaker luminescence intensity. And the transient emission spectrum exhibits that there is a fast component within the excited-state relaxation of ［Ru(bpy)2HPIP］(ClO4)2, which may be due to the hydrogen-bonding between metal-ligand-charge-transfer (MLCT) state and solvent molecules. But the measured result of their nanosecond transient luminescence indicates that they have the same transient luminescence decay process. And this decay process accords with the energy gap law. It maybe corresponds to the excited-state relaxation of the MLCT state without combination with the solvent molecules.