• Journal of Inorganic Materials
  • Vol. 35, Issue 3, 337 (2020)
Wei ZHANG1、2, Chen LIU2, Yuantao CHEN2, and Wangsuo WU1、*
Author Affiliations
  • 1School of Nuclear Science and Technology, Lanzhou University, Lanzhou 730000, China
  • 2School of Chemistry and Chemical Engineering, Qinghai Normal University, Xining 810008, China
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    DOI: 10.15541/jim20190383 Cite this Article
    Wei ZHANG, Chen LIU, Yuantao CHEN, Wangsuo WU. Removal of Boron from Water by Mg-Al-Ce Hydrotalcite Adsorption[J]. Journal of Inorganic Materials, 2020, 35(3): 337 Copy Citation Text show less
    TG-DSC curve of Mg-Al-Ce-HT precursor
    . TG-DSC curve of Mg-Al-Ce-HT precursor
    XRD patterns of Mg-Al-Ce precursor (a), Mg-Al-Ce-HT before adsorption (b), and Mg-Al-Ce-HT after adsorption(c)
    . XRD patterns of Mg-Al-Ce precursor (a), Mg-Al-Ce-HT before adsorption (b), and Mg-Al-Ce-HT after adsorption(c)
    FT-IR spectra of Mg-Al-Ce-HT precursor (a); Mg-Al-Ce-HT materials (b) and adsorbed materials (c)
    . FT-IR spectra of Mg-Al-Ce-HT precursor (a); Mg-Al-Ce-HT materials (b) and adsorbed materials (c)
    SEM images of Mg-Al-Ce-HT (a) and EDS analysis of Mg-Al-Ce-HT (b) and the corresponding EDS mappings of O (c), Mg (d), Ce (e), and Al (f) elements
    . SEM images of Mg-Al-Ce-HT (a) and EDS analysis of Mg-Al-Ce-HT (b) and the corresponding EDS mappings of O (c), Mg (d), Ce (e), and Al (f) elements
    Schematic of the B(OH)3 adsorption process on the surface of Mg-Al-Ce-HT material(a), and XPS patterns of full elemental spectrogram (b)
    . Schematic of the B(OH)3 adsorption process on the surface of Mg-Al-Ce-HT material(a), and XPS patterns of full elemental spectrogram (b)
    XPS spectra of Mg 2p, Al 2p, Ce 3d, C 1s, and O 1s in Mg-Al-Ce-HT before and after adsorption
    . XPS spectra of Mg 2p, Al 2p, Ce 3d, C 1s, and O 1s in Mg-Al-Ce-HT before and after adsorption
    Effect of initial pH on adsorption efficiency (a) and the relationship between the conversion of H3BO3 and B(OH)4- (b)
    . Effect of initial pH on adsorption efficiency (a) and the relationship between the conversion of H3BO3 and B(OH)4- (b)
    Effect of adsorbents, adsorption percentages, and adsorption capacity
    . Effect of adsorbents, adsorption percentages, and adsorption capacity
    Effect of initial concentration of boric acid (a) and the Langmuir model (b)
    . Effect of initial concentration of boric acid (a) and the Langmuir model (b)
    Effect of contact time on boron adsorption and kinetics model
    . Effect of contact time on boron adsorption and kinetics model
    Van’s Hoff plot of boron adsorption on Mg-Al-Ce-HT
    . Van’s Hoff plot of boron adsorption on Mg-Al-Ce-HT
    T/KΔGθ/ (kJ· mol-1)ΔHθ/ (kJ·mol-1)ΔSθ/ (kJ· mol-1·K-1)R2
    30812.1689.900.250.99
    31310.90
    3238.37
    Table 1.

    Thermodynamic parameters for boron adsorption on Mg-Al-Ce-HT

    Wei ZHANG, Chen LIU, Yuantao CHEN, Wangsuo WU. Removal of Boron from Water by Mg-Al-Ce Hydrotalcite Adsorption[J]. Journal of Inorganic Materials, 2020, 35(3): 337
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