• Journal of Inorganic Materials
  • Vol. 38, Issue 12, 1475 (2023)
Haidong WANG1,2,3, Yan WANG1,3, Zhaojie ZHU1,3, Jianfu LI1,3..., Gandham LAKSHMINARAYANA4 and Chaoyang TU1,3,*|Show fewer author(s)
Author Affiliations
  • 11. Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
  • 22. University of Chinese Academy of Sciences, Beijing 100049, China
  • 33. Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China
  • 44. Intelligent Construction Automation Center, Kyungpook National University, Daegu 41566, Republic of Korea
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    DOI: 10.15541/jim20230059 Cite this Article
    Haidong WANG, Yan WANG, Zhaojie ZHU, Jianfu LI, Gandham LAKSHMINARAYANA, Chaoyang TU. Crystal Growth and Structural, Optical, and Visible Fluorescence Traits of Dy3+-doped SrGdGa3O7 Crystal [J]. Journal of Inorganic Materials, 2023, 38(12): 1475 Copy Citation Text show less

    Abstract

    Dy3+-doped SrGdGa3O7 crystal was successfully grown through the Czochralski method and investigated in detail for its structural and optical features. Its crystallographic lattice parameters were optimized by Rietveld refinement based on XRD data. Polarized absorption spectra, polarized emission spectra, and fluorescence decay curves of Dy: SrGdGa3O7 crystal were analyzed. Absorption cross-sections at 452 nm corresponding to π- and σ-polarization were computed as 0.594×10-21 and 0.555×10-21 cm2, respectively. Calculated effective J-O intensity parameters Ω2, Ω4, and Ω6 were 5.495×10-20, 1.476×10-20, and 1.110×10-20 cm2, respectively. J-O analysis and emission spectra show that transition 4F9/26H13/2 of Dy: SrGdGa3O7 crystal has the highest fluorescence branching ratio and fluorescence intensity under 452 nm excitation within the visible spectral region, the emission cross-sections of π- and σ-polarization were 1.84×10-21 and 2.49×10-21 cm2 at the wavelength of 574 nm, respectively. The measured radiative lifetime and fluorescence decay time of the Dy3+: 4F9/2 level were 0.768 and 0.531 ms with a quantum efficiency of 69.1%. All these results reveal that Dy3+: SrGdGa3O7 crystal is a promising material for yellow lasers pumped with blue laser diodes.
    ${{\sigma }_{\text{abs}}}=\frac{\alpha }{{{N}_{\text{c}}}}$

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    ${{S}_{\text{calc}}}(J,\ {J}')=\underset{t=2,\ 4,\ 6}{\mathop \sum }\,{{\Omega }_{t}}|\left\langle S,L,J||{{U}^{(t)}}||{S}',{L}',{J}' \right\rangle {{|}^{2}}$

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    ${{S}_{\exp }}(J,{J}')=\frac{\left( 2J+1 \right)}{{{N}_{\text{c}}}}\frac{3hc}{8{{\text{ }\!\!\pi\!\!\text{ }}^{3}}\bar{\lambda }{{e}^{2}}}\frac{9n}{{{({{n}^{2}}+2)}^{2}}}\frac{\mathop{\int }^{}\text{OD}(\lambda )\text{d}\lambda }{0.43l}$

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    $RMS=\sqrt{\frac{\sum\limits_{i=1}^{N}{{{({{S}_{\text{calc}}}-{{S}_{\text{exp}}})}^{2}}}}{N-3}}$

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    ${{A}_{\text{total}}}={{A}_{\text{md}}}+{{A}_{\text{ed}}}$

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    ${{A}_{\text{ed}}}\text{ }\!\!~\!\!\text{ }(J,{J}')=\frac{64{{\text{ }\!\!\pi\!\!\text{ }}^{4}}{{e}^{2}}}{3h(2J+1){{{\bar{\lambda }}}^{3}}}\frac{n{{({{n}^{2}}+2)}^{2}}}{9}{{S}_{\text{ed}}}$

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    ${{A}_{\text{md}}}(J,{J}')=\frac{64{{\text{ }\!\!\pi\!\!\text{ }}^{4}}{{e}^{2}}{{n}^{3}}}{3h(2J+1){{{\bar{\lambda }}}^{3}}}{{S}_{\text{md}}}$

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    $\beta (J,{J}')=\frac{A(J,{J}')}{\sum\limits_{{{J}'}}{A(J,{J}')}}$

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    ${{\tau }_{\text{r}}}=\frac{1}{\sum\limits_{{{J}'}}{A(J,{J}')}}$

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    ${{\sigma }_{\text{em}}}(\lambda )=\frac{{{\lambda }^{5}}I(\lambda )\beta }{8\text{ }\!\!\pi\!\!\text{ }c{{n}^{2}}{{\tau }_{\text{r}}}\mathop{\int }^{}I(\lambda )\lambda \text{d}\lambda }$

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    ${{\sigma }_{\text{em}}}(\lambda )=\frac{3{{\lambda }^{5}}{{I}_{\text{ }\!\!\sigma\!\!\text{, }\!\!\pi\!\!\text{ }}}(\lambda )\beta }{8\text{ }\!\!\pi\!\!\text{ }c{{n}^{2}}{{\tau }_{\text{r}}}\mathop{\int }^{}[2{{I}_{\text{ }\!\!\sigma\!\!\text{ }}}(\lambda )+{{I}_{\text{ }\!\!\pi\!\!\text{ }}}(\lambda )]\lambda \text{d}\lambda }$

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    $\text{CCT}=-449{{N}^{3}}+3525{{N}^{2}}-6823.3N+5520.33$

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    Haidong WANG, Yan WANG, Zhaojie ZHU, Jianfu LI, Gandham LAKSHMINARAYANA, Chaoyang TU. Crystal Growth and Structural, Optical, and Visible Fluorescence Traits of Dy3+-doped SrGdGa3O7 Crystal [J]. Journal of Inorganic Materials, 2023, 38(12): 1475
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