• Journal of Inorganic Materials
  • Vol. 38, Issue 2, 184 (2023)
Jingwei SUN*, Honglei WANG, Chuhan SUN, Xingui ZHOU, and Xiaoyu JI
DOI: 10.15541/jim20220553 Cite this Article
Jingwei SUN, Honglei WANG, Chuhan SUN, Xingui ZHOU, Xiaoyu JI. Effects of Carbon Sources on Structure and Properties of TaC Ceramic Powder Prepared by Polymer Derived Ceramics[J]. Journal of Inorganic Materials, 2023, 38(2): 184 Copy Citation Text show less
Preparation process of TaC ceramic powder
. Preparation process of TaC ceramic powder
FT-IR of different carbon sources and crosslinked products
. FT-IR of different carbon sources and crosslinked products
TG curves of different tantalum carbon sources and crosslinked products
. TG curves of different tantalum carbon sources and crosslinked products
XRD patterns of ceramic products obtained at different pyrolysis temperatures and tantalum/carbon ratios
. XRD patterns of ceramic products obtained at different pyrolysis temperatures and tantalum/carbon ratios
Raman spectra of TaC powders obtained at different tantalum/carbon ratios
. Raman spectra of TaC powders obtained at different tantalum/carbon ratios
Histograms of the granularity distributions of TaC powders obtained at optimal tantalum/carbon mass ratios
. Histograms of the granularity distributions of TaC powders obtained at optimal tantalum/carbon mass ratios
SEM images of TaC powders obtained at different tantalum/carbon mass ratios
. SEM images of TaC powders obtained at different tantalum/carbon mass ratios
Elemental distributions of TaC powders obtained at optimal tantalum/carbon mass ratios
. Elemental distributions of TaC powders obtained at optimal tantalum/carbon mass ratios
TEM and HRTEM images of TaC powders obtained at optimal tantalum/carbon ratios
. TEM and HRTEM images of TaC powders obtained at optimal tantalum/carbon ratios
SampleL/nm SampleL/nm
PTC1-1062.5PTC2-2071.3
PTC1-1573.9PTC2-3067.9
PTC1-2067.2PTC2-3566.0
PTC1-2547.2PTC2-4060.9
PTC1-3045.5PTC2-4554.8
PTC1-3539.7
PTC1-4037.5
Table 1. Average grain size of TaC powder with different carbon source ratios
Temperature/℃ωD/cm-1ωG/cm-1${{I}_{\text{D}}}/{{I}_{\text{G}}}$
1200131315762.045
1300131515791.641
1400131315801.605
Table 2. Center positions of D and G peaks of PTC1-25 products obtained at different pyrolysis temperatures and ratios of ${{I}_{\mathbf{D}}}/{{I}_{\mathbf{G}}}$
SampleTa/%C/%O/%Cfree/%
PTC1-2591.725.021.312.19
PTC2-4092.146.420.891.75
Table 3. Elements mass contents of TaC powders obtained at optimal tantalum/carbon ratio
Jingwei SUN, Honglei WANG, Chuhan SUN, Xingui ZHOU, Xiaoyu JI. Effects of Carbon Sources on Structure and Properties of TaC Ceramic Powder Prepared by Polymer Derived Ceramics[J]. Journal of Inorganic Materials, 2023, 38(2): 184
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