• Journal of Inorganic Materials
  • Vol. 39, Issue 11, 1205 (2024)
Qianyuan LI1, Jiwei LI1, Yuhan ZHANG2, Yankang LIU1..., Yang MENG1, Yu CHU1, Yijia ZHU1, Nuoyan XU1, Liang ZHU1, Chuanxiang ZHANG2,* and Haijun TAO1,*|Show fewer author(s)
Author Affiliations
  • 11. College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, China
  • 22. College of Material Science and Engineering, Nanjing Institute of Technology, Nanjing 211167, China
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    DOI: 10.15541/jim20240132 Cite this Article
    Qianyuan LI, Jiwei LI, Yuhan ZHANG, Yankang LIU, Yang MENG, Yu CHU, Yijia ZHU, Nuoyan XU, Liang ZHU, Chuanxiang ZHANG, Haijun TAO. Enhanced Photovoltaic Performance of Perovskite Solar Cells by PbTiO3 Modification and Polarization Treatment [J]. Journal of Inorganic Materials, 2024, 39(11): 1205 Copy Citation Text show less
    Preparative diagram of c-TiO2/PbTiO3 layer
    1. Preparative diagram of c-TiO2/PbTiO3 layer
    (a) SEM image and (b-d) EDS elemental mappings of c-TiO2/PbTiO3 surface
    2. (a) SEM image and (b-d) EDS elemental mappings of c-TiO2/PbTiO3 surface
    XPS spectra of c-TiO2 and c-TiO2/PbTiO3 layer
    3. XPS spectra of c-TiO2 and c-TiO2/PbTiO3 layer
    (a) UV-visible transmittance spectra and (b) I-V curves under dark state of c-TiO2/PbTiO3 layers with different reaction time
    4. (a) UV-visible transmittance spectra and (b) I-V curves under dark state of c-TiO2/PbTiO3 layers with different reaction time
    J-V curves of PSCs prepared by c-TiO2/PbTiO3 layers with different reaction time
    5. J-V curves of PSCs prepared by c-TiO2/PbTiO3 layers with different reaction time
    J-V curves of PSCs prepared by c-TiO2/PbTiO3 layers after polarization with different voltages
    6. J-V curves of PSCs prepared by c-TiO2/PbTiO3 layers after polarization with different voltages
    Mott-Schottky curves of c-TiO2 and c-TiO2/PbTiO3 layers
    7. Mott-Schottky curves of c-TiO2 and c-TiO2/PbTiO3 layers
    (a) Nyquist plots, (b) composite impedance plots at different bias voltages, (c) voltage attenuation curves, (d) dark current curves, (e) capacitance-frequency curves, and (f) photocurrent output curves of c-TiO2, c-TiO2/PbTiO3 and polarization-treated c-TiO2/PbTiO3 layers
    8. (a) Nyquist plots, (b) composite impedance plots at different bias voltages, (c) voltage attenuation curves, (d) dark current curves, (e) capacitance-frequency curves, and (f) photocurrent output curves of c-TiO2, c-TiO2/PbTiO3 and polarization-treated c-TiO2/PbTiO3 layers
    Reactiontime/s Rρ/(Ω·cm) σ/(mS·cm-1)
    022.615.65×1051.77×10-3
    1023.645.91×1051.69×10-3
    3024.896.22×1051.61×10-3
    12028.987.24×1051.38×10-3
    30055.2013.79×1057.25×10-4
    Table 1. Conductivities of c-TiO2/PbTiO3 layers with different reaction time
    Reaction time/sVoc/V Jsc/(mA·cm-2) FF/%PCE/%
    00.8813.8451.516.26
    100.8813.9251.556.31
    300.8914.1251.776.49
    1200.9311.9952.565.88
    3000.949.8142.003.85
    Table 2. Photovoltaic parameters of PSCs prepared by c-TiO2/PbTiO3 layers with different reaction time
    Polarization voltage/V Voc/V Jsc/(mA·cm-2) FF/%PCE/%
    00.8814.1251.186.41
    200.8914.3951.256.53
    400.9314.8351.167.11
    500.9314.9551.357.11
    600.9315.0051.207.12
    Table 3. Photovoltaic parameters of PSCs prepared by c-TiO2/PbTiO3 layers after polarization with different voltages
    Qianyuan LI, Jiwei LI, Yuhan ZHANG, Yankang LIU, Yang MENG, Yu CHU, Yijia ZHU, Nuoyan XU, Liang ZHU, Chuanxiang ZHANG, Haijun TAO. Enhanced Photovoltaic Performance of Perovskite Solar Cells by PbTiO3 Modification and Polarization Treatment [J]. Journal of Inorganic Materials, 2024, 39(11): 1205
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