• Journal of Semiconductors
  • Vol. 40, Issue 3, 032201 (2019)
Shihua Huang1, Zhe Rui1, Dan Chi1, and Daxin Bao2
Author Affiliations
  • 1Provincial Key Laboratory of Solid State Optoelectronic Devices, Zhejiang Normal University, Jinhua 321004, China
  • 2Hengdian Group DMEGC Magnetics Co., Ltd, Dongyang 322118, China
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    DOI: 10.1088/1674-4926/40/3/032201 Cite this Article
    Shihua Huang, Zhe Rui, Dan Chi, Daxin Bao. Influence of defect states on the performances of planar tin halide perovskite solar cells[J]. Journal of Semiconductors, 2019, 40(3): 032201 Copy Citation Text show less

    Abstract

    Although tin halide perovskite has shown excellent photoelectric performance, its efficiency of solar cell is low compared with that of lead halide. In order to enhance the efficiency of tin halide perovskite solar cell, a deep understanding of the role of the defects in the perovskite absorption layer and at the electron transport layer (ETL)/absorber or absorber/hole transport layer (HTL) interface is very necessary. In this work, the planar heterojunction-based CH3NH3SnI3 perovskite solar cells were simulated with the SCAPS-1D program. Simulation results revealed a great dependence of device efficiency on defect density and interface quality of the perovskite absorber. The defect density at the front interface is critical for high efficiency, and the polarity of the interface charge has a different impact on the device efficiency. Strikingly, an efficiency over 29% was obtained under the moderate simulation conditions.
    ${V_{{\rm{OC}}}} = \frac{{kT}}{q}{\rm{ln}}\left( {\frac{{{I_{\rm{L}}}}}{{{I_{\rm{0}}}}} + 1} \right),$ (1)

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    ${I_0} = AkTn_{\rm{i}}^2\left( {\frac{{{\mu _{\rm{n}}}}}{{{L_{\rm{n}}}{N_{\rm{A}}}}} + \frac{{{\mu _{\rm{p}}}}}{{{L_{\rm{p}}}{N_{\rm{D}}}}}} \right),$ (2)

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    ${L_{\rm{n,p}}} = \sqrt {\frac{{{\mu _{\rm{n,p}}}kT}}{q}\frac{1}{{{\sigma _{\rm{n,p}}}{v_{\rm{th}}}{N_{\rm{t}}}}}} .$ (3)

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    Shihua Huang, Zhe Rui, Dan Chi, Daxin Bao. Influence of defect states on the performances of planar tin halide perovskite solar cells[J]. Journal of Semiconductors, 2019, 40(3): 032201
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