• Journal of Semiconductors
  • Vol. 43, Issue 9, 090202 (2022)
Yunye Wang1, Zuo Xiao2, Shanxin Xiong1、*, and Liming Ding2、**
Author Affiliations
  • 1College of Chemistry and Chemical Engineering, Xi’an University of Science and Technology, Xi’an 710054, China
  • 2Center for Excellence in Nanoscience (CAS), Key Laboratory of Nanosystem and Hierarchical Fabrication (CAS), National Center for Nanoscience and Technology, Beijing 100190, China
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    DOI: 10.1088/1674-4926/43/9/090202 Cite this Article
    Yunye Wang, Zuo Xiao, Shanxin Xiong, Liming Ding. COF-based electrochromic materials and devices[J]. Journal of Semiconductors, 2022, 43(9): 090202 Copy Citation Text show less
    (Color online) (a) Chemical structures for TAPA, TTDA, and COFTAPA-TTDA. (b) Schematic for the electrochromic phenomenon of oriented COFTAPA-TTDA thin film. Reprinted with permission[12], Copyright 2019, American Chemical Society. (c) The preparation of COFTAPA-TFPA nanofibers. Reprinted with permission[14], Copyright 2020, Elsevier.
    Fig. 1. (Color online) (a) Chemical structures for TAPA, TTDA, and COFTAPA-TTDA. (b) Schematic for the electrochromic phenomenon of oriented COFTAPA-TTDA thin film. Reprinted with permission[12], Copyright 2019, American Chemical Society. (c) The preparation of COFTAPA-TFPA nanofibers. Reprinted with permission[14], Copyright 2020, Elsevier.
    (Color online) (a) Schematic for the redox process of COFTAPA-TFPA nanofibers. Reprinted with permission[14], Copyright 2020, Elsevier. (b) Synthetic route for COFTPBD-BTDD. Reprinted with permission[15], Copyright 2020, Springer Nature.
    Fig. 2. (Color online) (a) Schematic for the redox process of COFTAPA-TFPA nanofibers. Reprinted with permission[14], Copyright 2020, Elsevier. (b) Synthetic route for COFTPBD-BTDD. Reprinted with permission[15], Copyright 2020, Springer Nature.
    (Color online) (a) Color switching of COFTPBD-BTDD device. Reprinted with permission[15], Copyright 2020, Springer Nature. (b) Chemical structures for TPDA, PDA, and COFTPDA-PDA. (c) The three-state electrochromic behavior of COFTPDA-PDA thin film. Reprinted with permission[16], Copyright 2021, Wiley.
    Fig. 3. (Color online) (a) Color switching of COFTPBD-BTDD device. Reprinted with permission[15], Copyright 2020, Springer Nature. (b) Chemical structures for TPDA, PDA, and COFTPDA-PDA. (c) The three-state electrochromic behavior of COFTPDA-PDA thin film. Reprinted with permission[16], Copyright 2021, Wiley.
    EC materialλmax (nm)tc/tb (s)Coloration efficiency (cm2/C)T (%)Ref.
    COFTAPA-TTDA610130017.5/10.518/131021522141[12]
    COFTAPA-TFPA5304.5/4.911530[14]
    COFTPBD-BTDD5747301.8/7.22.6/3.52842463312[15]
    COFPy-ttTII5506608800.38/0.20.29/0.14–318620858–––[9]
    COFTPDA-PDA10507401.3/0.73.4/1.83202275257[16]
    Table 1. Electrochromic properties of COF-based EC materials.
    Yunye Wang, Zuo Xiao, Shanxin Xiong, Liming Ding. COF-based electrochromic materials and devices[J]. Journal of Semiconductors, 2022, 43(9): 090202
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