Author Affiliations
1College of Chemistry and Chemical Engineering, Xi’an University of Science and Technology, Xi’an 710054, China2Center for Excellence in Nanoscience (CAS), Key Laboratory of Nanosystem and Hierarchical Fabrication (CAS), National Center for Nanoscience and Technology, Beijing 100190, Chinashow less
Fig. 1. (Color online) (a) Chemical structures for TAPA, TTDA, and COFTAPA-TTDA. (b) Schematic for the electrochromic phenomenon of oriented COFTAPA-TTDA thin film. Reprinted with permission[12], Copyright 2019, American Chemical Society. (c) The preparation of COFTAPA-TFPA nanofibers. Reprinted with permission[14], Copyright 2020, Elsevier.
Fig. 2. (Color online) (a) Schematic for the redox process of COFTAPA-TFPA nanofibers. Reprinted with permission[14], Copyright 2020, Elsevier. (b) Synthetic route for COFTPBD-BTDD. Reprinted with permission[15], Copyright 2020, Springer Nature.
Fig. 3. (Color online) (a) Color switching of COFTPBD-BTDD device. Reprinted with permission[15], Copyright 2020, Springer Nature. (b) Chemical structures for TPDA, PDA, and COFTPDA-PDA. (c) The three-state electrochromic behavior of COFTPDA-PDA thin film. Reprinted with permission[16], Copyright 2021, Wiley.
EC material | λmax (nm) | tc/tb (s) | Coloration efficiency (cm2/C) | ∆T (%) | Ref. |
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COFTAPA-TTDA | 6101300 | 17.5/10.518/13 | 102152 | 2141 | [12] | COFTAPA-TFPA | 530 | 4.5/4.9 | 115 | 30 | [14] | COFTPBD-BTDD | 574730 | 1.8/7.22.6/3.5 | 284246 | 3312 | [15] | COFPy-ttTII | 550660880 | 0.38/0.20.29/0.14– | 318620858 | ––– | [9] | COFTPDA-PDA | 1050740 | 1.3/0.73.4/1.8 | 320227 | 5257 | [16] |
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Table 1. Electrochromic properties of COF-based EC materials.