Author Affiliations
1College of Media Engineering, Communication University of Zhejiang, Hangzhou 310018, China2Beijing Institute of Metrology, Beijing 100029, China3College of Electronic Engineering, Heilongjiang University, Harbin 150080, Chinashow less
Fig. 1. Absorption spectra of the CdTe/CdS quantum dots
Fig. 2. Open/closed aperture Z-scan normalized transmittance curves of water-soluble CdTe/CdS, S1-S2 quantum dots
Fig. 3. Open/closed aperture Z-scan normalized transmittance curves of water-soluble CdTe/CdS, S3-S4 quantum dots
Fig. 4. Open/closed aperture Z-scan normalized transmittance curves of water-soluble CdTe/CdS, S5-S6 quantum dots
Fig. 5. Transient absorption spectra of water-soluble CdTe/ CdS, S1-S2 quantum dots
Fig. 6. Transient absorption spectra of water-soluble CdTe/ CdS, S3-S4 quantum dots
Fig. 7. Transient absorption spectra of water-soluble CdTe/ CdS, S5-S6 quantum dots
Fig. 8. Ultrafast kinetic curves of water-soluble CdTe/CdS, S1-S2 quantum dots
Fig. 9. Ultrafast kinetic curves of water-soluble CdTe/CdS, S3-S4 quantum dots
Fig. 10. Ultrafast kinetic curves of water-soluble CdTe/CdS, S5-S6 quantum dots
Fig. 11. Transient absorption spectrum of the solvent water
Sample number | Quantum dots | Size /nm | Core color | Cladding time | S1 | CdTe/CdS-1 | 3.2 | Orange | 30 min | S2 | CdTe/CdS-2 | 3.3 | orange | 1 h | S3 | CdTe/CdS-3 | 3.0 | Yellow | 30 min | S4 | CdTe/CdS-4 | 3.1 | Yellow | 1 h | S5 | CdTe/CdS-5 | 2.6 | Green | 30 min | S6 | CdTe/CdS-6 | 2.7 | Green | 1 h |
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Table 1. Six kinds of the CdTe/CdS core-shell quantum dots
Sample name | Core color | Shell | Size/nm | β/10-13 m·W-1 | n2/10−12esu
| χ3/10−14esu
| S1 | Orange | CdS-30 min | 3.2 | 4.39 | 1.42 | 3.85 | S2 | Orange | CdS-1 h | 3.3 | 5.01 | 1.49 | 4.12 | S3 | Yellow | CdS-30 min | 3.0 | 5.07 | 1.38 | 3.90 | S4 | Yellow | CdS-1 h | 3.1 | 5.29 | 1.85 | 4.92 | S5 | Green | CdS-30 min | 2.6 | 5.23 | 1.18 | 3.58 | S6 | Green | CdS-1 h | 2.7 | 6.42 | 1.73 | 4.92 |
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Table 2. Nonlinear optical parameters obtained from Z-scan measurement data for CdTe/CdS quantum dots
Sample name | Size | τ-rise/ps
| τ1/ps
| τ2/ps
| S1 | 3.2 | 0.34 | 1.06 | 17.81 | S2 | 3.3 | 0.33 | 1.98 | 18.43 | S3 | 3.0 | 0.35 | 1.13 | 13.79 | S4 | 3.1 | 0.59 | 2.13 | 38.24 | S5 | 2.6 | 0.31 | 1.74 | 12.77 | S6 | 2.7 | 0.32 | 1.79 | 16.78 |
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Table 3. CdTe/CdS quantum dots fitting parameters