• Journal of Inorganic Materials
  • Vol. 36, Issue 3, 319 (2021)
Zhaoyang XIA1、2, Hui WANG1, Jinghong FANG1、2, Yang ZHANG1, Chaoyue WANG1, Huan HE1, Jinqi NI1, Yun SHI1, Qin LI1, and Jianding YU1、2、*
Author Affiliations
  • 11. Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
  • 22. University of Chinese Academy of Sciences, Beijing 100049, China
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    DOI: 10.15541/jim20200183 Cite this Article
    Zhaoyang XIA, Hui WANG, Jinghong FANG, Yang ZHANG, Chaoyue WANG, Huan HE, Jinqi NI, Yun SHI, Qin LI, Jianding YU. Co Incorporation on Structure, Conductivity and Magnetism of GaFeO3[J]. Journal of Inorganic Materials, 2021, 36(3): 319 Copy Citation Text show less

    Abstract

    GaFeO3 is one of the most promising ferromagnetic materials due to its magnetoelectric coupling effect. GaFe1-xCoxO3 (x=0, 0.02, 0.05, 0.07, 0.10) ceramics were prepared by the conventional solid-state method, and the effect of Co substitution on the microstructure, electrical leakage and magnetic properties was investigated. The XRD patterns and Rietveld refinement using the FullProf package showed that the secondary phase with a Fd3¯m space group was present in addition to the main GFO phase with a Pc21n space group, and with an increase of Co doping, the proportion of the secondary phase and the lattice distortion increased. The leakage current density of the GFCO-x samples decreased by approximately 7 orders of magnitude for Co=2at%. The improved magnetization in GFCO ceramics was attributed to the secondary phase and enhanced lattice distortion. This work suggests that the magnetism was improved by doping Co and the leakage current would be decreased sharply without prominent fluctuation of TC in the meantime by the incorporation of trace amounts of Co.
    $\text{O}_{\text{O}}^{\times }\to {{\text{{V}''}}_{\text{O}}}+\frac{1}{2}{{\text{O}}_{2}}+2{{\text{e}}^{-}},$

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    $\text{Fe}_{\text{Fe}}^{\times }+{{\text{e}}^{-}}\to \text{F{e}'}_{\text{Fe}}^{{}}. $

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    $\text{CoO}\to \text{C{o}'}_{\text{Fe}}^{{}}+{{h}^{\centerdot }}+\frac{1}{2}{{\text{O}}_{2}}$

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    ${{h}^{\centerdot }}+{{\text{e}}^{-}}\to 0$

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    Zhaoyang XIA, Hui WANG, Jinghong FANG, Yang ZHANG, Chaoyue WANG, Huan HE, Jinqi NI, Yun SHI, Qin LI, Jianding YU. Co Incorporation on Structure, Conductivity and Magnetism of GaFeO3[J]. Journal of Inorganic Materials, 2021, 36(3): 319
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