Fig. 1. Sampling sites of wine grape
Fig. 2. The absorbance spectra of grape berries
Fig. 3. The absorbance spectra of canopy leaves of grape
Fig. 4. PCA score plot of Chardonnay grape
Fig. 5. Results of calibration and validation of SSC prediction model for Chardonnay grape
Fig. 6. Results of calibration and validation of SSC prediction model for Petit Manseng grape
Fig. 7. Results of calibration and validation of SSC prediction model for Merlot grape
Fig. 8. Results of calibration and validation of SSC prediction model for Cabernet Sauvignon grape
Fig. 9. Results of calibration and validation of SSC prediction model for Cabernet Franc grape
Fig. 10. Results of calibration and validation of SSC prediction model for Chardonnay leaves
Fig. 11. Results of calibration and validation of SSC prediction model for Petit Manseng leaves
Fig. 12. Results of calibration and validation of SSC prediction model for Merlot leaves
Fig. 13. Results of calibration and validation of SSC prediction model for Cabernet Sauvignon leaves
Fig. 14. Results of calibration and validation of SSC prediction model for Cabernet Franc leaves
样品 名称 | 类别 | 样品 子集 | 样本 数量 | 范围/% | 均值 /% | 标准误 差/% |
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霞多丽 | 浆果 | 校正集 | 64 | 17.0~22.9 | 19.76 | 0.78 | 验证集 | 21 | 18.4~20.8 | 19.72 | 0.66 | 小芒森 | 浆果 | 校正集 | 64 | 19.9~23.4 | 21.67 | 0.72 | 验证集 | 20 | 20.5~22.6 | 21.55 | 0.63 | 梅洛 | 浆果 | 校正集 | 66 | 17.0~22.9 | 20.22 | 1.03 | 验证集 | 22 | 18.3~22.2 | 20.50 | 1.00 | 赤霞珠 | 浆果 | 校正集 | 60 | 19.1~20.9 | 20.17 | 0.46 | 验证集 | 20 | 18.8~21.3 | 20.05 | 0.64 | 品丽珠 | 浆果 | 校正集 | 66 | 17.2~21.3 | 19.67 | 0.80 | 验证集 | 22 | 18.0~21.2 | 19.53 | 0.78 | 霞多丽 | 叶片 | 校正集 | 50 | 18.0~21.4 | 19.54 | 0.72 | 验证集 | 16 | 18.5~21.3 | 19.71 | 0.56 | 小芒森 | 叶片 | 校正集 | 50 | 19.9~23.6 | 21.87 | 1.03 | 验证集 | 17 | 20.8~23.0 | 21.81 | 0.56 | 梅洛 | 叶片 | 校正集 | 53 | 17.2~23.7 | 20.47 | 1.54 | 验证集 | 16 | 19.5~22.8 | 20.56 | 0.91 | 赤霞珠 | 叶片 | 校正集 | 49 | 18.1~23.2 | 20.12 | 1.03 | 验证集 | 15 | 18.6~21.4 | 19.83 | 0.79 | 品丽珠 | 叶片 | 校正集 | 53 | 18.1~21.2 | 19.61 | 0.73 | 验证集 | 17 | 18.8~20.7 | 19.85 | 0.55 |
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Table 1. Statistics results of SSC of sample sets
样品 种类 | 预处理方法 | PCS | 校正集 | 验证集 |
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RC | RMSEC | RV | RMSEV |
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霞多丽 | S-G | 2 | 0.72 | 0.76 | 0.73 | 0.64 | S-G+FD | 2 | 0.78 | 0.49 | 0.83 | 0.40 | S-G+SNV+FD | 2 | 0.83 | 0.44 | 0.85 | 0.36 | S-G+MSC+FD | 3 | 0.93 | 0.30 | 0.86 | 0.36 | 小芒森 | S-G | 4 | 0.61 | 0.58 | 0.41 | 0.63 | S-G+FD | 3 | 0.95 | 0.22 | 0.86 | 0.33 | S-G+SNV+FD | 3 | 0.95 | 0.22 | 0.86 | 0.33 | S-G+MSC+FD | 3 | 0.95 | 0.22 | 0.86 | 0.30 | 梅洛 | S-G | 7 | 0.73 | 0.70 | 0.76 | 0.70 | S-G+FD | 7 | 1.00 | 0.09 | 0.83 | 0.54 | S-G+SNV+FD | 4 | 0.96 | 0.30 | 0.88 | 0.48 | S-G+MSC+FD | 5 | 0.96 | 0.29 | 0.88 | 0.48 | 赤霞珠 | S-G | 4 | 0.91 | 0.19 | 0.87 | 0.35 | S-G+FD | 1 | 0.93 | 0.18 | 0.85 | 0.37 | S-G+SNV+FD | 2 | 0.97 | 0.12 | 0.88 | 0.31 | S-G+MSC+FD | 7 | 0.98 | 0.02 | 0.82 | 0.40 | 品丽珠 | S-G | 6 | 0.71 | 0.56 | 0.67 | 0.33 | S-G+FD | 3 | 0.81 | 0.37 | 0.71 | 0.66 | S-G+SNV+FD | 4 | 0.93 | 0.27 | 0.81 | 0.37 | S-G+MSC+FD | 4 | 0.96 | 0.22 | 0.86 | 0.44 |
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Table 2. Comparison of PLS prediction models with four different pretreatment methods
样品 种类 | 预处理方法 | PCS | 校正集 | 验证集 |
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RC | RMSEC | RV | RMSEV |
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霞多丽 | S-G | 1 | 0.69 | 0.65 | 0.36 | 0.79 | S-G+FD | 1 | 0.70 | 0.52 | 0.55 | 0.68 | S-G+SNV+FD | 1 | 0.71 | 0.66 | 0.61 | 0.55 | S-G+MSC+FD | 1 | 0.76 | 0.46 | 0.67 | 0.44 | 小芒森 | S-G | 2 | 0.61 | 0.96 | 0.41 | 0.75 | S-G+FD | 3 | 0.66 | 0.83 | 0.59 | 0.70 | S-G+SNV+FD | 2 | 0.75 | 0.79 | 0.60 | 0.58 | S-G+MSC+FD | 2 | 0.80 | 0.61 | 0.66 | 0.48 | 梅洛 | S-G | 1 | 0.62 | 0.70 | 0.52 | 0.97 | S-G+FD | 2 | 0.72 | 0.69 | 0.61 | 0.86 | S-G+SNV+FD | 2 | 0.72 | 0.90 | 0.61 | 0.80 | S-G+MSC+FD | 2 | 0.78 | 0.96 | 0.66 | 0.75 | 赤霞珠 | S-G | 1 | 0.47 | 1.26 | 0.51 | 1.27 | S-G+FD | 2 | 0.61 | 0.99 | 0.61 | 0.99 | S-G+SNV+FD | 1 | 0.70 | 0.86 | 0.62 | 0.77 | S-G+MSC+FD | 1 | 0.73 | 0.71 | 0.69 | 0.70 | 品丽珠 | S-G | 3 | 0.60 | 0.90 | 0.41 | 1.65 | S-G+FD | 2 | 0.69 | 0.77 | 0.59 | 0.99 | S-G+SNV+FD | 2 | 0.71 | 0.59 | 0.60 | 0.75 | S-G+MSC+FD | 2 | 0.78 | 0.46 | 0.65 | 0.44 |
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Table 3. Comparison of PLS prediction models with four different pretreatment methods
样品 名称 | 样品 类别 | 数量 | 范围/% | 绝对误 差/% | 相对误 差/% |
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霞多丽 | 浆果 | 20 | 18.4~20.8 | 0.08 | -0.44 | 小芒森 | 浆果 | 20 | 20.5~22.6 | -0.02 | -0.06 | 梅洛 | 浆果 | 20 | 19.1~22.2 | -0.09 | -0.35 | 赤霞珠 | 浆果 | 20 | 18.8~20.9 | -0.01 | -0.05 | 品丽珠 | 浆果 | 20 | 18.0~21.2 | 0.07 | 0.43 |
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Table 4. External validation results of samples of berry and canopy leaves