• Acta Photonica Sinica
  • Vol. 50, Issue 7, 230 (2021)
Yang YANG1, Gang LI1, Kewu JING1, Tianqi WANG1, Saiao PENG1, Tingting YAO1, and Shuyong CHEN2
Author Affiliations
  • 1State Key Laboratory of Advanced Technology for Float Glass, Institute of Coating-film Technology, Bengbu, Anhui233000, China
  • 2CNBM Bengbu Design & Research Institute for Glass Industry Co. Ltd, Bengbu, Anhui33018, China
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    DOI: 10.3788/gzxb20215007.0731002 Cite this Article
    Yang YANG, Gang LI, Kewu JING, Tianqi WANG, Saiao PENG, Tingting YAO, Shuyong CHEN. Studies on the Preparation and Properties of Nanocrystalline ZnSX Thin Films by RF Magnetron Sputtering Technique at Room Temperature[J]. Acta Photonica Sinica, 2021, 50(7): 230 Copy Citation Text show less

    Abstract

    In order to obtain high-performance transparent dielectric thin films, nanocrystalline zinc-rich ZnS films were prepared on glass substrates by radio frequency magnetron sputtering with a ZnS ceramic target at room temperature, and the effect of the radio frequency power on the structural, surface morphology and optical properties of the films were studied using X-ray diffraction, field emission scanning electron microscopy, micro-Raman spectroscopy, ultraviolet-visible spectroscopy and spectroscopic ellipsometry. It is found that the radio frequency power has an important impact on the phase formation and crystallinity of the ZnSX films. With the increase in the radio frequency power, the atomic ratio of zinc to sulfur, intensity of the characteristic Raman peak and refraction index first increase and then decrease, the optical band gap of the film deceases from 3.86 eV to 3.76 eV systematically. Among the various radio frequency power values investigated, 150 W is optimal for the growth of highly crystalline ZnSX films with the cubic phase, the ratio of Zn/S of film is 1.23 close to the standard stoichiometric ratio, the average transmittance is more than 80% at visible light, and the optical refractive index of ZnSX film is 2.03 at 550 nm.
    d111=λ2sinθ(1)

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    acubic=d111(h2+k2+l21/2

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    D111=0.9λβcosθ(3)

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    ε=βcosθ4(4)

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    (αhν)2 = A(hν -Eg

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    α=1dln 1T(6)

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    △E=Eg(NC)-Eg(B)

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    E=h28μeffR2-1.8e24πε0εrR-0.248 e2μeff2(ε0εr)2h2(8)

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    FP=j=1Mk=1Cji=1Njmikj-tikjPwkj2NjCjvjj=1Mvj(9)

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    MSEP=FP(10)

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    Yang YANG, Gang LI, Kewu JING, Tianqi WANG, Saiao PENG, Tingting YAO, Shuyong CHEN. Studies on the Preparation and Properties of Nanocrystalline ZnSX Thin Films by RF Magnetron Sputtering Technique at Room Temperature[J]. Acta Photonica Sinica, 2021, 50(7): 230
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