• Journal of Semiconductors
  • Vol. 40, Issue 2, 022101 (2019)
Qi Lei1, Hairong Li1、2、3, Huan Zhang1, Jianan Wang1, Wenhao Fan1, and Lina Cai1
Author Affiliations
  • 1School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, China
  • 2Key Laboratory of Special Function Materials and Structure Design, Ministry of Education, Lanzhou University, Lanzhou 730000, China
  • 3Institute of Sensor Technology, Gansu Academy of Sciences, Lanzhou 730000, China
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    DOI: 10.1088/1674-4926/40/2/022101 Cite this Article
    Qi Lei, Hairong Li, Huan Zhang, Jianan Wang, Wenhao Fan, Lina Cai. Three-dimensional hierarchical CuO gas sensor modified by Au nanoparticles[J]. Journal of Semiconductors, 2019, 40(2): 022101 Copy Citation Text show less
    (Color online) XRD patterns of (a) the Au samples, and (b) the Au–CuO and pure CuO samples.
    Fig. 1. (Color online) XRD patterns of (a) the Au samples, and (b) the Au–CuO and pure CuO samples.
    SEM micrographs of (a,b) the CuO nanomaterial, (c) the Au nanoparticles, and (d) the Au-loaded CuO nanomaterial.
    Fig. 2. SEM micrographs of (a,b) the CuO nanomaterial, (c) the Au nanoparticles, and (d) the Au-loaded CuO nanomaterial.
    (Color online) (a) Relation of the gas response with operating temperature for the pure CuO, and 0.5‰, 1.0‰, and 2.0‰ Au-loaded CuO gas sensors to 500 ppm of ethanol. (b) The response of the sensors based on pure CuO and Au-loaded CuO to different concentrations of ethanol at 160 ºC.
    Fig. 3. (Color online) (a) Relation of the gas response with operating temperature for the pure CuO, and 0.5‰, 1.0‰, and 2.0‰ Au-loaded CuO gas sensors to 500 ppm of ethanol. (b) The response of the sensors based on pure CuO and Au-loaded CuO to different concentrations of ethanol at 160 ºC.
    (Color online) (a, b) Response and recovery behavior of the gas sensors based on pure CuO and 1.0‰ Au-loaded CuO to different concentrations of ethanol at 160 ºC. (c, d) The response time (Tres) and the recovery time (Trec) of the gas sensors based on pure CuO and 1.0‰ Au-loaded CuO to 400 ppm of ethanol at 160 ºC.
    Fig. 4. (Color online) (a, b) Response and recovery behavior of the gas sensors based on pure CuO and 1.0‰ Au-loaded CuO to different concentrations of ethanol at 160 ºC. (c, d) The response time (Tres) and the recovery time (Trec) of the gas sensors based on pure CuO and 1.0‰ Au-loaded CuO to 400 ppm of ethanol at 160 ºC.
    (Color online) Equivalent diagram of the resistance of the Au-loaded CuO nanosheet.
    Fig. 5. (Color online) Equivalent diagram of the resistance of the Au-loaded CuO nanosheet.
    (Color online) Response of the gas sensors based on the pure CuO and 0.5‰, 1.0‰, and 2.0‰ Au-loaded CuO to 400 ppm of various test gases at 160 ºC.
    Fig. 6. (Color online) Response of the gas sensors based on the pure CuO and 0.5‰, 1.0‰, and 2.0‰ Au-loaded CuO to 400 ppm of various test gases at 160 ºC.
    (Color online) Response of the gas sensors based on the pure CuO and 0.5‰, 1.0‰, and 2.0‰ Au-loaded CuO to different concentrations of formaldehyde at 160 ºC.
    Fig. 7. (Color online) Response of the gas sensors based on the pure CuO and 0.5‰, 1.0‰, and 2.0‰ Au-loaded CuO to different concentrations of formaldehyde at 160 ºC.
    (Color online) Seven cycles of response-recovery to 300 ppm of ethanol of the 2.0‰ Au-loaded CuO gas sensor at 160 ºC.
    Fig. 8. (Color online) Seven cycles of response-recovery to 300 ppm of ethanol of the 2.0‰ Au-loaded CuO gas sensor at 160 ºC.
    Sensing materialT (°С) Ethanol (ppm)ResponseReference
    3D hierarchical porous structure Pt-NiO2005005.0[43]
    Co3O4 hollow nanospheres 10010006.3[44]
    MnO2 nanorods 1803001.6[45]
    Comb-like Cu2O 3206003.0[46]
    CuO/MWNT thin film4005004.5[47]
    CuO flowers26010004.0[20]
    3D hierarchical structure Au-CuO1605008.6This work
    Table 1. Comparison of gas-sensing properties of other metal oxide nanostructures toward ethanol gas.
    Qi Lei, Hairong Li, Huan Zhang, Jianan Wang, Wenhao Fan, Lina Cai. Three-dimensional hierarchical CuO gas sensor modified by Au nanoparticles[J]. Journal of Semiconductors, 2019, 40(2): 022101
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