• Journal of Inorganic Materials
  • Vol. 34, Issue 2, 137 (2019)
Ying YANG1、2、3, De-Qun PAN1、2、3, Zheng ZHANG1、2、3, Tian CHEN1、2、3, Xiao-Min HAN1, Li-Song ZHANG1, Xue-Yi GUO1、2、3, [in Chinese]1、2、3, [in Chinese]1、2、3, [in Chinese]1、2、3, [in Chinese]1、2、3, [in Chinese]1, [in Chinese]1, and [in Chinese]1、2、3
Author Affiliations
  • 11. School of Metallurgy and Environment, Central South University, Changsha 410083, China
  • 22. Hunan Key Laboratory of Nonferrous Metal Resources Recycling, Changsha 410083, China
  • 33. Hunan Engineering Research Center of Nonferrous Metal Resources Recycling, Changsha 410083, China
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    DOI: 10.15541/jim20180233 Cite this Article
    Ying YANG, De-Qun PAN, Zheng ZHANG, Tian CHEN, Xiao-Min HAN, Li-Song ZHANG, Xue-Yi GUO, [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese]. Photovoltaic Performance of Ag2Se Quantum Dots Co-sensitized Solid-state Dye-sensitized Solar Cells[J]. Journal of Inorganic Materials, 2019, 34(2): 137 Copy Citation Text show less
    (a)Transmission electron microscope (TEM) image, (b) size distribution histogram, (c) HRTEM image, and (d) zoom-in HRTEM image of the Ag2Se quantum dots
    . (a)Transmission electron microscope (TEM) image, (b) size distribution histogram, (c) HRTEM image, and (d) zoom-in HRTEM image of the Ag2Se quantum dots
    (a) Absorption spectrum and (b) corresponding Tauc plot of the Ag2Se quantum dots in ethanol solution
    . (a) Absorption spectrum and (b) corresponding Tauc plot of the Ag2Se quantum dots in ethanol solution
    (a) UV-Vis spectra of photoanodes with different Ag2Se QDs sensitization methods with inset showing photographs of photoandes, and (b) J-V curve of DSSCs with different sensitization methods
    . (a) UV-Vis spectra of photoanodes with different Ag2Se QDs sensitization methods with inset showing photographs of photoandes, and (b) J-V curve of DSSCs with different sensitization methods
    IPCE spectra of DSSCs with different sensitization methods
    . IPCE spectra of DSSCs with different sensitization methods
    (a) Device structure and (b) energy level diagram of solid-state Ag2Se QDs and dye co-sensitized solar cell
    . (a) Device structure and (b) energy level diagram of solid-state Ag2Se QDs and dye co-sensitized solar cell
    (a) UV-Vis absorption spectra of Ag2Se QDs sensitized, N719 sensitized and Ag2Se QDs/N719 co-sensitized photoanodes, and (b) UV-Vis absorption spectra of photoanodes with different sensitization time of Ag2Se QDs
    . (a) UV-Vis absorption spectra of Ag2Se QDs sensitized, N719 sensitized and Ag2Se QDs/N719 co-sensitized photoanodes, and (b) UV-Vis absorption spectra of photoanodes with different sensitization time of Ag2Se QDs
    J-V curves of pure Ag2Se quantum dot sensitized solar cell and co-sensitized solar cells with different Ag2Se QDs sensitization time
    . J-V curves of pure Ag2Se quantum dot sensitized solar cell and co-sensitized solar cells with different Ag2Se QDs sensitization time
    (a) Electrochemical impedance plots of co-sensitized solar cells with different Ag2Se QDs sensitization time with inset showing the equivalent circuit, and (b) the recombination resistance R2 of DSSCs as a function of different Ag2Se QDs sensitization time
    . (a) Electrochemical impedance plots of co-sensitized solar cells with different Ag2Se QDs sensitization time with inset showing the equivalent circuit, and (b) the recombination resistance R2 of DSSCs as a function of different Ag2Se QDs sensitization time
    (a) IMPS and (b) IMVS plots of co-sensitized solar cells with different Ag2Se QDs sensitization time
    . (a) IMPS and (b) IMVS plots of co-sensitized solar cells with different Ag2Se QDs sensitization time
    SampleJsc/(mA∙cm-2)Voc/VFFƞ/%
    TiO2/dye8.780.690.502.96
    TiO2/dye/QDs8.080.710.482.74
    TiO2/QDs/dye9.180.740.533.59
    Table 1. Photovoltaic parameters of DSSCs with different sensitized methods
    SampleJsc/(mA∙cm-2)Voc/VFFƞ /%
    TiO2/QDs(2 h)0.440.410.550.10
    TiO2/dye8.780.690.502.96
    TiO2/QDs(1 h)/dye9.180.740.533.59
    TiO2/QDs(2 h)/dye9.530.750.553.97
    TiO2/QDs(3 h)/dye9.460.730.553.82
    TiO2/QDs(4 h)/dye8.690.750.563.68
    TiO2/QDs(5 h)/dye7.690.740.553.10
    Table 2. Photovoltaic parameters of co-sensitized solar cells with different Ag2Se QDs sensitization time
    Sampleτd/msτc/msDn/
    (cm2·s-1)
    Ln/μmηcc
    TiO2/dye31.778.457.2515.180.73
    TiO2/QDs(1 h)/dye33.658.457.2515.620.75
    TiO2/QDs(2 h)/dye42.377.987.6818.040.81
    TiO2/QDs(3 h)/dye42.378.457.2517.520.80
    TiO2/QDs(4 h)/dye31.777.538.1416.070.76
    TiO2/QDs(5 h)/dye23.838.457.2513.140.65
    Table 3. IMPS/VS kinetic parameters of co-sensitized solar cells with different Ag2Se QDs sensitization time
    Ying YANG, De-Qun PAN, Zheng ZHANG, Tian CHEN, Xiao-Min HAN, Li-Song ZHANG, Xue-Yi GUO, [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese]. Photovoltaic Performance of Ag2Se Quantum Dots Co-sensitized Solid-state Dye-sensitized Solar Cells[J]. Journal of Inorganic Materials, 2019, 34(2): 137
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