Giant chiro-optical responses in multipolar-resonances-based single-layer dielectric metasurfaces

Hafiz Saad Khaliq; Inki Kim; Aima Zahid; Joohoon Kim; Taejun Lee; Trevon Badloe; Yeseul Kim; Muhammad Zubair; Kashif Riaz; Muhammad Qasim Mehmood; Junsuk Rho

doi:10.1364/PRJ.424477

[1] V. A. Fedotov, A. S. Schwanecke, N. I. Zheludev, V. V. Khardikov, S. L. Prosvirnin. Asymmetric transmission of light and enantiomerically sensitive plasmon resonance in planar chiral nanostructures. Nano Lett., 7, 1996-1999(2007).

[2] J. K. Gansel, M. Thiel, M. S. Rill, M. Decker, K. Bade, V. Saile, G. Von Freymann, S. Linden, M. Wegener. Gold helix photonic metamaterial as broadband circular polarizer. Science, 325, 1513-1515(2009).

[3] M. Hentschel, M. Schäferling, T. Weiss, N. Liu, H. Giessen. Three-dimensional chiral plasmonic oligomers. Nano Lett., 12, 2542-2547(2012).

[4] Y. Zhao, A. N. Askarpour, L. Sun, J. Shi, X. Li, A. Alù. Chirality detection of enantiomers using twisted optical metamaterials. Nat. Commun., 8, 14180(2017).

[5] S. Fasold, S. Linß, T. Kawde, M. Falkner, M. Decker, T. Pertsch, I. Staude. Disorder-enabled pure chirality in bilayer plasmonic metasurfaces. ACS Photon., 5, 1773-1778(2018).

[6] M. Decker, M. Ruther, C. E. Kriegler, J. Zhou, C. M. Soukoulis, S. Linden, M. Wegener. Strong optical activity from twisted-cross photonic metamaterials. Opt. Lett., 34, 2501-2503(2009).

[7] A. F. Koenderink, A. Polman. Nanophotonics: shrinking light-based technology. Science, 348, 516-521(2015).

[8] V. K. Valev, J. J. Baumberg, C. Sibilia, T. Verbiest. Chirality and chiroptical effects in plasmonic nanostructures: fundamentals, recent progress, and outlook. Adv. Mater., 25, 2517-2534(2013).

[9] A. B. Khanikaev, N. Arju, Z. Fan, D. Purtseladze, F. Lu, J. Lee, P. Sarriugarte, M. Schnell, R. Hillenbrand, M. A. Belkin, G. Shvets. Experimental demonstration of the microscopic origin of circular dichroism in two-dimensional metamaterials. Nat. Commun., 7, 12045(2016).

[10] Z. Wang, F. Cheng, T. Winsor, Y. Liu. Optical chiral metamaterials: a review of the fundamentals, fabrication methods and applications. Nanotechnology, 27, 412001(2016).

[11] Z. Wang, H. Jia, K. Yao, W. Cai, H. Chen, Y. Liu. Circular dichroism metamirrors with near-perfect extinction. ACS Photon., 3, 2096-2101(2016).

[12] L. Kang, S. Rodrigues, M. Taghinejad, S. Lan, K. Lee, Y. Liu, D. H. Werner, A. Urbas, W. Cai. Preserving spin states upon reflection: linear and nonlinear responses of a chiral meta-mirror. Nano Lett., 17, 7102-7109(2017).

[13] M. Thiel, M. Decker, M. Deubel, M. Wegener, S. Linden, G. Von Freymann. Polarization stop bands in chiral polymeric three-dimensional photonic crystals. Adv. Mater., 19, 207-210(2007).

[14] M. Thiel, M. S. Rill, G. Von Freymann, M. Wegener. Three-dimensional bi-chiral photonic crystals. Adv. Mater., 21, 4680-4682(2009).

[15] B. Frank, X. Yin, M. Schäferling, J. Zhao, S. M. Hein, P. V. Braun, H. Giessen. Large-area 3D chiral plasmonic structures. ACS Nano, 7, 6321-6329(2013).

[16] A. V. Rogacheva, V. A. Fedotov, A. S. Schwanecke, N. I. Zheludev. Giant gyrotropy due to electromagnetic-field coupling in a bilayered chiral structure. Phys. Rev. Lett., 97, 177401(2006).

[17] C. Menzel, C. Helgert, C. Rockstuhl, E. B. Kley, A. Tünnermann, T. Pertsch, F. Lederer. Asymmetric transmission of linearly polarized light at optical metamaterials. Phys. Rev. Lett., 104, 253902(2010).

[18] C. Pfeiffer, C. Zhang, V. Ray, L. J. Guo, A. Grbic. High performance bianisotropic metasurfaces: asymmetric transmission of light. Phys. Rev. Lett., 113, 023902(2014).

[19] M. Mutlu, E. Ozbay. A transparent 90 polarization rotator by combining chirality and electromagnetic wave tunneling. Appl. Phys. Lett., 100, 051909(2012).

[20] K. Tanaka, D. Arslan, S. Fasold, M. Steinert, J. Sautter, M. Falkner, T. Pertsch, M. Decker, I. Staude. Chiral bilayer all-dielectric metasurfaces. ACS Nano, 14, 15926-15935(2020).

[21] S. S. Bukhari, J. Vardaxoglou, W. Whittow. A metasurfaces review: definitions and applications. Appl. Sci., 9, 2727(2019).

[22] T. Kelvin. The Molecular Tactics of a Crystal(1894).

[23] W. T. B. Kelvin. Baltimore Lectures on Molecular Dynamics and the Wave Theory of Light(1904).

[24] S. Vignolini, E. Moyroud, B. J. Glover, U. Steiner. Analysing photonic structures in plants. J. R. Soc. Interface, 10, 20130394(2013).

[25] V. Sharma, M. Crne, J. O. Park, M. Srinivasarao. Structural origin of circularly polarized iridescence in jeweled beetles. Science, 325, 449-451(2009).

[26] V. Saranathan, C. O. Osuji, S. G. J. Mochrie, H. Noh, S. Narayanan, A. Sandy, E. R. Dufresne, R. O. Prum. Structure, function, and self-assembly of single network gyroid (I4₁32) photonic crystals in butterfly wing scales. Proc. Natl. Acad. Sci. USA, 107, 11676-11681(2010).

[27] R. M. Hazen, D. S. Sholl. Chiral selection on inorganic crystalline surfaces. Nat. Mater., 2, 367-374(2003).

[28] I. Čorić, B. List. Asymmetric spiroacetalization catalysed by confined brønsted acids. Nature, 483, 315-319(2012).

[29] F. Kamarei, A. Tarafder, F. Gritti, P. Vajda, G. Guiochon. Determination of the adsorption isotherm of the naproxen enantiomers on (S,S)-Whelk-O1 in supercritical fluid chromatography. J. Chromatogr. A, 1314, 276-287(2013).

[30] B. S. Sekhon. Exploiting the power of stereochemistry in drugs: an overview of racemic and enantiopure drugs. J. Mod. Med. Chem., 1, 10-36(2013).

[31] D. J. Cordato, L. E. Mather, G. K. Herkes. Stereochemistry in clinical medicine: a neurological perspective. J. Clin. Neurosci., 10, 649-654(2003).

[32] M. E. Franks, G. R. Macpherson, W. D. Figg. Thalidomide. Lancet, 363, 1802-1811(2004).

[33] J. Hu, M. Lawrence, J. A. Dionne. High quality factor dielectric metasurfaces for ultraviolet circular dichroism spectroscopy. ACS Photon., 7, 36-42(2020).

[34] T. Naeem, A. S. Rana, M. Zubair, T. Tauqeer, M. Q. Mehmood. Breaking planar symmetries by a single layered metasurface for realizing unique on-chip chiroptical effects. Opt. Mater. Express, 10, 3342-3352(2020).

[35] M. L. Solomon, J. Hu, M. Lawrence, A. García-Etxarri, J. A. Dionne. Enantiospecific optical enhancement of chiral sensing and separation with dielectric metasurfaces. ACS Photon., 6, 43-49(2019).

[36] S. Sun, Z. Zhou, C. Zhang, W. Yang, Q. Song, S. Xiao. All-dielectric meta-reflect array for efficient control of visible light. Ann. Phys., 530, 1700418(2018).

[37] M. A. Ansari, T. Tauqeer, M. Zubair, M. Q. Mehmood. Breaking polarisation-bandwidth trade-off in dielectric metasurface for unpolarised white light. Nanophotonics, 9, 963-971(2020).

[38] M. R. Akram, M. Q. Mehmood, T. Tauqeer, A. S. Rana, I. D. Rukhlenko, W. Zhu. Highly efficient generation of Bessel beams with polarization insensitive metasurfaces. Opt. Express, 27, 9467-9480(2019).

[39] M. A. Ansari, I. Kim, D. Lee, M. H. Waseem, M. Zubair, N. Mahmood, T. Badloe, S. Yerci, T. Tauqeer, M. Q. Mehmood, J. Rho. A spin-encoded all-dielectric metahologram for visible light. Laser Photon. Rev., 13, 1900065(2019).

[40] H. S. Khaliq, I. Kim, K. Riaz, T. Naeem, M. Zubair, J. Rho, M. Q. Mehmood. Chiroptical effect induced by achiral structures for full-dimensional manipulation of optical waves. Proc. SPIE, 11695, 116951M(2021).

[41] T. Naeem, A. S. Rana, H. S. Khaliq, T. Tauqeer, M. Zubair, M. Q. Mehmood. C2 symmetric single-layered meta-atoms for asymmetric holography. Proc. SPIE, 11710, 1171007(2021).

[42] T. Naeem, H. S. Khaliq, M. Zubair, T. Tauqeer, M. Q. Mehmood. Engineering tunability through electro-optic effects to manifest a multifunctional metadevice. RSC Adv., 11, 13220-13228(2021).

[43] H. S. Khaliq, M. R. Akram, K. Riaz, M. A. Ansari, J. Akbar, J. Zhang, W. Zhu, D. Zhang, X. Wang, M. Zubair, M. Q. Mehmood. Single-layered meta-reflectarray for polarization retention and spin-encrypted phase-encoding. Opt. Express, 29, 3230-3242(2021).

[44] H. S. Khaliq, K. Riaz, M. Zubair, M. A. Ansari, M. R. Akram, T. Naeem, J. Zhang, W. Zhu, D. Zhang, X. Wang, M. Q. Mehmood. Highly efficient metamirror with circular dichroism and wavefront engineering. Proc. SPIE, 11344, 113441N(2020).

[45] A. S. Rana, M. Q. Mehmood, H. Jeong, I. Kim, J. Rho. Tungsten-based ultrathin absorber for visible regime. Sci. Rep., 8, 2443(2018).

[46] M. Q. Mehmood, S. Mei, S. Hussain, K. Huang, S. Y. Siew, L. Zhang, T. Zhang, X. Ling, H. Liu, J. Teng, A. Danner, S. Zhang, C. W. Qiu. Visible-frequency metasurface for structuring and spatially multiplexing optical vortices. Adv. Mater., 28, 2533-2539(2016).

[47] N. Mahmood, I. Kim, M. Q. Mehmood, H. Jeong, A. Akbar, D. Lee, M. Saleem, M. Zubair, M. S. Anwar, F. A. Tahir, J. Rho. Polarisation insensitive multifunctional metasurfaces based on all-dielectric nanowaveguides. Nanoscale, 10, 18323-18330(2018).

[48] K. Huang, H. Liu, S. Restuccia, M. Q. Mehmood, S. T. Mei, D. Giovannini, A. Danner, M. J. Padgett, J. H. Teng, C. W. Qiu. Spiniform phase-encoded metagratings entangling arbitrary rational-order orbital angular momentum. Light Sci. Appl., 7, 17156(2018).

[49] S. Mei, M. Q. Mehmood, S. Hussain, K. Huang, X. Ling, S. Y. Siew, H. Liu, J. Teng, A. Danner, C. W. Qiu. Flat helical nanosieves. Adv. Funct. Mater., 26, 5255-5262(2016).

[50] Y. Chen, J. Gao, X. Yang. Direction-controlled bifunctional metasurface polarizers. Laser Photon. Rev., 12, 1800198(2018).

[51] E. Plum, V. A. Fedotov, N. I. Zheludev. Asymmetric transmission: a generic property of two-dimensional periodic patterns. J. Opt., 13, 024006(2011).

[52] S. Yang, Z. Liu, S. Hu, A. Z. Jin, H. Yang, S. Zhang, J. Li, C. Gu. Spin-selective transmission in chiral folded metasurfaces. Nano Lett., 19, 3432-3439(2019).

[53] Z. Li, W. Liu, H. Cheng, D. Y. Choi, S. Chen, J. Tian. Spin-selective full-dimensional manipulation of optical waves with chiral mirror. Adv. Mater., 32, 1907983(2020).

[54] L. Zhang, P. Zhou, H. Chen, H. Lu, H. Xie, L. Zheng, E. Li, J. Xie, L. Deng. Ultrabroadband design for linear polarization conversion and asymmetric transmission crossing X- and K-band. Sci. Rep., 6, 33826(2016).

[55] W. Li, Z. J. Coppens, L. V. Besteiro, W. Wang, A. O. Govorov, J. Valentine. Circularly polarized light detection with hot electrons in chiral plasmonic metamaterials. Nat. Commun., 6, 8379(2015).

[56] W. Ma, F. Cheng, Y. Liu. Deep-learning-enabled on-demand design of chiral metamaterials. ACS Nano, 12, 6326-6334(2018).

[57] K. Tanaka, D. Arslan, S. Fasold, M. Steinert, J. Sautter, M. Falkner. Chiral bilayer all-dielectric metasurfaces. ACS Nano, 14, 15926-15935(2020).

[58] A. B. Evlyukhin, S. M. Novikov, U. Zywietz, R. L. Eriksen, C. Reinhardt, S. I. Bozhevolnyi, B. N. Chichkov. Demonstration of magnetic dipole resonances of dielectric nanospheres in the visible region. Nano Lett., 12, 3749-3755(2012).

[59] V. A. Zenin, C. E. Garcia-Ortiz, A. B. Evlyukhin, Y. Yang, R. Malureanu, S. M. Novikov, V. Coello, B. N. Chichkov, S. I. Bozhevolnyi, A. V. Lavrinenko, N. A. Mortensen. Engineering nanoparticles with pure high-order multipole scattering. ACS Photon., 7, 1067-1075(2020).

[60] M. Decker, I. Staude, M. Falkner, J. Dominguez, D. N. Neshev, I. Brener, T. Pertsch, Y. S. Kivshar. High-efficiency dielectric Huygens’ surfaces. Adv. Opt. Mater., 3, 813-820(2015).

[61] T. V. Raziman, R. H. Godiksen, M. A. Müller, A. G. Curto. Conditions for enhancing chiral nanophotonics near achiral nanoparticles. ACS Photon., 6, 2583-2589(2019).

[62] F. Zhang, M. Pu, X. Li, P. Gao, X. Ma, J. Luo, H. Yu, X. Luo. All-dielectric metasurfaces for simultaneous giant circular asymmetric transmission and wavefront shaping based on asymmetric photonic spin–orbit interactions. Adv. Funct. Mater., 27, 1704295(2017).

[63] A. Y. Zhu, W. T. Chen, A. Zaidi, Y. W. Huang, M. Khorasaninejad, V. Sanjeev, C. W. Qiu, F. Capasso. Giant intrinsic chiro-optical activity in planar dielectric nanostructures. Light Sci. Appl., 7, 17158(2018).

[64] K. Yao, Y. Liu. Enhancing circular dichroism by chiral hotspots in silicon nanocube dimers. Nanoscale, 10, 8779-8786(2018).

[65] K. Yao, Y. Zheng. Near-ultraviolet dielectric metasurfaces: from surface-enhanced circular dichroism spectroscopy to polarization-preserving mirrors. J. Phys. Chem. C, 123, 11814-11822(2019).

[66] A. S. Rana, I. Kim, M. A. Ansari, M. S. Anwar, M. Saleem, T. Tauqeer, A. Danner, M. Zubair, M. Q. Mehmood, J. Rho. Planar achiral metasurfaces-induced anomalous chiroptical effect of optical spin isolation. ACS Appl. Mater. Interfaces, 12, 48899-48909(2020).

[67] H. S. Khaliq, I. Kim, J. Kim, D. K. Oh, M. Zubair, K. Riaz, M. Q. Mehmood, J. Rho. Manifesting simultaneous optical spin conservation and spin isolation in diatomic metasurfaces. Adv. Opt. Mater., 9, 2002002(2021).

[68] J. P. Balthasar Mueller, N. A. Rubin, R. C. Devlin, B. Groever, F. Capasso. Metasurface polarization optics: independent phase control of arbitrary orthogonal states of polarization. Phys. Rev. Lett., 118, 113901(2017).

[69] Z. Ma, S. M. Hanham, Y. Gong, M. Hong. All-dielectric reflective half-wave plate metasurface based on the anisotropic excitation of electric and magnetic dipole resonances. Opt. Lett., 43, 911-914(2018).

[70] T. Kaelberer, V. A. Fedotov, N. Papasimakis, D. P. Tsai, N. I. Zheludev. Toroidal dipolar response in a metamaterial. Science, 330, 1510-1512(2010).

[71] M. Qiu, L. Zhang, Z. Tang, W. Jin, C. Qiu, D. Y. Lei. 3D metaphotonic nanostructures with intrinsic chirality. Adv. Funct. Mater., 28, 1803147(2018).

[72] J. Mun, M. Kim, Y. Yang, C. Qiu, J. Rho. Electromagnetic chirality: from fundamentals to nontraditional chiroptical phenomena. Light Sci. Appl., 9, 139(2020).

[73] H. Lee, H.-Y. Ahn, J. Mun, Y. Y. Lee, M. Kim, N. H. Cho, K. Chang Kim, S. W. J. Rho, K. T. Nam. Amino-acid- and peptide-directed synthesis of chiral plasmonic gold nanoparticles. Nature, 556, 360-365(2018).

[74] I. Kim, M. A. Ansari, M. Q. Mehmood, W.-S. Kim, J. Jang, M. Zubair, Y.-K. Kim, J. Rho. Stimuli-responsive dynamic metaholographic displays with designer liquid crystal modulators. Adv. Mater., 32, 2004664(2020).

CLP Journals