• Journal of Inorganic Materials
  • Vol. 36, Issue 2, 168 (2021)
Yanxiang WANG, Peiyang GAO, Xueyun FAN, Jiake LI, Pingchun GUO, Liqun HUANG, and Jian SUN
Author Affiliations
  • College of Materials Science and Engineering, Jingdezheng Ceramic Institute, Jingdezheng 333403, China
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    DOI: 10.15541/jim20190650 Cite this Article
    Yanxiang WANG, Peiyang GAO, Xueyun FAN, Jiake LI, Pingchun GUO, Liqun HUANG, Jian SUN. Effect of SnO2 Annealing Temperature on the Performance of Perovskite Solar Cells[J]. Journal of Inorganic Materials, 2021, 36(2): 168 Copy Citation Text show less
    FSEM images of FTO and SnO2 films annealed at different temperatures
    1. FSEM images of FTO and SnO2 films annealed at different temperatures
    XPS spectra of SnO2 film annealed at 180 ℃ with FTO as substrate
    2. XPS spectra of SnO2 film annealed at 180 ℃ with FTO as substrate
    UV-visible absorption spectra of SnO2 films annealed at different temperatures with FTO as substrate (Colourful curves are available on web)
    3. UV-visible absorption spectra of SnO2 films annealed at different temperatures with FTO as substrate (Colourful curves are available on web)
    Cross-sectional FSEM image of PSC with SnO2 ETL annealed at 180 ℃
    4. Cross-sectional FSEM image of PSC with SnO2 ETL annealed at 180 ℃
    (a) J-V curves, (b) PCE histograms, (c) IPCE spectra of PSCs prepared with SnO2 ETLs annealed at different temperatures; (d) IPCE and integral current curves of PSC with SnO2 ETL annealed at 180 ℃ (Colourful curves are available on web)
    5. (a) J-V curves, (b) PCE histograms, (c) IPCE spectra of PSCs prepared with SnO2 ETLs annealed at different temperatures; (d) IPCE and integral current curves of PSC with SnO2 ETL annealed at 180 ℃ (Colourful curves are available on web)
    PL spectra of perovskite films prepared with SnO2 ETL annealed at different temperatures
    6. PL spectra of perovskite films prepared with SnO2 ETL annealed at different temperatures
    Nyquist plots of PSCs prepared with SnO2 ETLs annealed at different temperatures
    7. Nyquist plots of PSCs prepared with SnO2 ETLs annealed at different temperatures
    AFM images of SnO2 films prepared at different annealing temperatures (20 μm×20 μm)
    S1. AFM images of SnO2 films prepared at different annealing temperatures (20 μm×20 μm)
    XRD patterns of SnO2 films prepared at different annealing temperatures
    S2. XRD patterns of SnO2 films prepared at different annealing temperatures
    TRPL spectra of perovskite films prepared with SnO2 ETLs annealed at 60 and 90 ℃
    S3. TRPL spectra of perovskite films prepared with SnO2 ETLs annealed at 60 and 90 ℃
    (a) Zoom-in high-frequency region of Nyquist plot and (b) equivalent circuit for PSCs with SnO2 ETLs annealed at different temperatures
    S4. (a) Zoom-in high-frequency region of Nyquist plot and (b) equivalent circuit for PSCs with SnO2 ETLs annealed at different temperatures
    Temperature/℃6090120150180210240
    Band gap/eV3.883.873.883.913.903.883.88
    Table 1. Bandgap of SnO2 films annealed at different temperatures
    Temperature/℃VOC/VJSC/(mA∙cm-2)FF/%PCE/%
    600.8718.8540.756.72
    900.9019.1555.709.60
    1200.9719.5671.6713.60
    1501.0619.6574.3615.48
    1801.0920.9175.9117.28
    2101.0619.2773.3214.91
    2400.9919.2370.7513.43
    Table 1. Photoelectric parameters of PSCs with SnO2 ETLs annealed at different temperatures
    Temperature/℃Resistivity/(×10-4, Ω∙cm)Carrier mobility/(cm2∙V-1·s-1)
    601.4023.11
    901.7425.60
    1201.8033.98
    1501.2445.26
    1801.4657.89
    2101.6439.81
    2401.3826.21
    Table 2. Electrical properties of SnO2 films annealed at different temperatures with FTO as substrate
    Yanxiang WANG, Peiyang GAO, Xueyun FAN, Jiake LI, Pingchun GUO, Liqun HUANG, Jian SUN. Effect of SnO2 Annealing Temperature on the Performance of Perovskite Solar Cells[J]. Journal of Inorganic Materials, 2021, 36(2): 168
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