• Journal of Inorganic Materials
  • Vol. 36, Issue 12, 1283 (2021)
Wenwen LIU*, Yuxin MIAO, Yifei ZHANG, Xinyu WANG, Yuting LAN, and Zhen ZHAO
DOI: 10.15541/jim20210100 Cite this Article
Wenwen LIU, Yuxin MIAO, Yifei ZHANG, Xinyu WANG, Yuting LAN, Zhen ZHAO. Preparation of MgAl LDH with Various Morphologies and Catalytic Hydrogenation Performance of Pt/LDH Catalysts[J]. Journal of Inorganic Materials, 2021, 36(12): 1283 Copy Citation Text show less
FT-IR spectra of LDH-1 and LDH-AS samples
. FT-IR spectra of LDH-1 and LDH-AS samples
XRD patterns of different morphologies LDH (a), SEM images of LDH-1 (b) and LDH-AS (c, d), TEM images of Pt/LDH-1 (e) and Pt/LDH-AS (f)
. XRD patterns of different morphologies LDH (a), SEM images of LDH-1 (b) and LDH-AS (c, d), TEM images of Pt/LDH-1 (e) and Pt/LDH-AS (f)
XPS spectra of the as-prepared catalysts
. XPS spectra of the as-prepared catalysts
CO2-TPD profiles of the as-prepared catalysts
. CO2-TPD profiles of the as-prepared catalysts
TEM images of the used Pt/LDH-1 (a, b) catalyst
. TEM images of the used Pt/LDH-1 (a, b) catalyst
Effect of temperature (a), pressure (b), reaction time (c), and recycling stability (d) on catalytic performances of Pt/LDH-1 catalysts
. Effect of temperature (a), pressure (b), reaction time (c), and recycling stability (d) on catalytic performances of Pt/LDH-1 catalysts
Summary of the selective hydrogenation mechanism of Pt/LDH-1 catalyst
. Summary of the selective hydrogenation mechanism of Pt/LDH-1 catalyst
CatalystConversion/%Selectivity/%
CMOHCMAHCMO
Pt/LDH-179.882.112.65.3
Pt/LDH-AS42.389.48.52.1
Table 1. Effects of Pt catalysts with various morphologies on the hydrogenation properties of cinnamaldehyde
CatalystPt content/ at% Ptδ+/Pt0Oads/(Oads+Olat) Mg/Al atomic ratio
Pt/LDH-10.352.510.351.19
Pt/LDH-AS0.282.300.210.98
Table 2. Surface elemental compositions of Pt/LDH-1 and Pt/LDH-AS catalysts determined by XPS
Wenwen LIU, Yuxin MIAO, Yifei ZHANG, Xinyu WANG, Yuting LAN, Zhen ZHAO. Preparation of MgAl LDH with Various Morphologies and Catalytic Hydrogenation Performance of Pt/LDH Catalysts[J]. Journal of Inorganic Materials, 2021, 36(12): 1283
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