• Journal of Infrared and Millimeter Waves
  • Vol. 39, Issue 6, 742 (2020)
Ying HE1, Yu-Jun ZHANG1,2,*, Kun YOU1, Bo-Qiang FAN1,2..., Meng-Qi LI1,2, Dong-Qi YU1,2, Hao XIE1,2, Bo-En LEI1,2, Wei JIA3, Jun-Sen JING3 and Wen-Qing LIU1,2|Show fewer author(s)
Author Affiliations
  • 1Key Laboratory of Environmental Optics & Technology, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei230031, China
  • 2University of Science and Technology of China, Hefei230026, China
  • 3College of Mechanical and Electrical Engineering, Anhui Jianzhu University, Hefei230601, China
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    DOI: 10.11972/j.issn.1001-9014.2020.06.012 Cite this Article
    Ying HE, Yu-Jun ZHANG, Kun YOU, Bo-Qiang FAN, Meng-Qi LI, Dong-Qi YU, Hao XIE, Bo-En LEI, Wei JIA, Jun-Sen JING, Wen-Qing LIU. Precise measurements the broadening characteristics and parameters of methane near-infrared absorption spectrum at high pressure[J]. Journal of Infrared and Millimeter Waves, 2020, 39(6): 742 Copy Citation Text show less
    (a) Spectrum measurement experimental platform, (b) gas path connection of experimental device
    Fig. 1. (a) Spectrum measurement experimental platform, (b) gas path connection of experimental device
    (a) Absorbance signal before and after filtering, (b) line-type fitting and residual result
    Fig. 2. (a) Absorbance signal before and after filtering, (b) line-type fitting and residual result
    Absorbance spectral signals after Lorentz line-type fitting
    Fig. 3. Absorbance spectral signals after Lorentz line-type fitting
    Nitrogen broadening coefficient at 6 046.96 cm-1
    Fig. 4. Nitrogen broadening coefficient at 6 046.96 cm-1
    Center frequency drift phenomenon
    Fig. 5. Center frequency drift phenomenon
    Calculated the pressure shift coefficient of nitrogen-induced
    Fig. 6. Calculated the pressure shift coefficient of nitrogen-induced
    Absorbance signals of different concentration at high pressure
    Fig. 7. Absorbance signals of different concentration at high pressure
    Specific parametersValue
    spectral line intensity S(cm mol-11.34E-21
    air-broadened half width at half maximum γair@296 K/ (cm -1 atm -10.062 1
    self-broadened half width at half maximumγself@296 K/ (cm -1 atm -10.082
    temperature dependence coefficient of the air-broadened n0.85
    pressure shift of the air-broadened δair@296 K/ (cm -1 atm -10
    Table 1. Specific parameters of methane absorption line at 6046.9647 cm-1(Hitran2008 database)
    TimeTure concentration/(%)Inverted concentration/(%)

    Relative error

    /(%)

    10.5000.5122.40
    20.4000.3902.50
    30.3000.3113.67
    40.2000.2084.00
    Table 2. Methane standard gas concentration and inverted concentration
    Ying HE, Yu-Jun ZHANG, Kun YOU, Bo-Qiang FAN, Meng-Qi LI, Dong-Qi YU, Hao XIE, Bo-En LEI, Wei JIA, Jun-Sen JING, Wen-Qing LIU. Precise measurements the broadening characteristics and parameters of methane near-infrared absorption spectrum at high pressure[J]. Journal of Infrared and Millimeter Waves, 2020, 39(6): 742
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