1. Classification of non-noble metal/nitrogen-doped carbon composite materials
2. Synthesis schemes of (a) Co@CNT/NC composites
[23], (b) Co-MOF//NF and Co-NCNTFs//NF
[25]; (c) OER polarization curves with 85% iR compensation in a 1 mol·L
-1 KOH solution at a scan rate of 1 mV·s
-1 and (d) related Tafel plots of Co-MOF//NF, Co-NCNTFs//NF, bare Ni foam, and RuO
2[25]; (e) Stability tests of Co-NCNTFs//NF for OER and HER at a current density of 10 mA·cm
-2[25]; (f) Illustration of the Co@NC/CC composite fabrication
[27] 3. (a) “Confined recrystallization” self-template synthesis strategy for Fe-NC SAC
[28]; (b) Schematic illustration of the synthetic procedure of the SCoNC catalysts
[32]; (c) Schematic description of the synthetic process, (d, e) FESEM and (f) TEM images of the HCM@Ni-N
[35]; (g, h) FESEM and (i) TEM images for HCM@Ni-N after continuous operation for 10 h
[35]; (j) LSV curves in 1.0 mol·L
-1 KOH and (k) the related Tafel plots of HCM@Ni-N, HCM@Ni, HCM@N, and HCM
[35] 4. Schematic synthesis process of (a) FeCo@MNC
[42], (b) Ni
1.5Co
0.5 @ N-C NT/NFs
[44] and (c) FeNi@NC-
x[46]; (d) SEM image of FeNi@NC-2
[46]; (e) LSV curves and (f)Tafel plots of RuO
2, and FeNi@NC-
x[46]; (g) Illustration of the preparation of Ni
3Fe-GA
s[47]; (h,i) SEM images and (j) TEM image for Ni
3Fe-GA
1[47]; (k) OER polarization curves and (l) corresponding Tafel plots for Ni
3Fe-GA
s[47]; (m) Chronopotentiometric curves of Ni
3Fe-GA
1 and IrO
2 catalysts
[47] 5. (a) Illustration of the synthesis process of N-Co
3O
4 and N-CoO/C
[59]; SEM images of (b, c) CoO and (d, e) N-CoO nanowire arrays
[60]; (f) Illustration of the synthesis process of CoO/Co@N-C
[61]; SEM images of (g) Co
3O
4 and (h) Co
3O
4@Glu microspheres, and (i) CoO/Co@N-C electrocatalyst
[61]; (j) LSV curves and (k) Tafel plots of CoO@N-C, CoO/Co@N-C, CoO/Co@N-C-
x samples that etched in HCl with
x representing etching time, Ir/C and Pt/C in 0.1 mol·L
-1 KOH solution; (l) LSV curves for the CoO/Co@N-C electrocatalyst before and after 2000 CV cycles in 0.1 mol·L
-1 KOH solution
[61] Sample | Electrolyte | η10/mV
| Tafel slope/(mV·dec-1)
| Mass loading/(mg·cm-2)
| Ref. |
---|
Co@CNT/NC-1000 | 1.0 mol·L-1 KOH
| 282 | 82 | ~12.73 | [23] | Co-NCNTFs//NF | 1.0 mol·L-1 KOH
| 230 | 94 | 4.1(Nickel foam) | [25] | Co@NC/CC | 1.0 mol·L-1 KOH
| 290 | 73 | - | [27] |
|
Table 1. OER electrocatalytic performances of non-noble metal/nitrogen-doped carbon composites
Sample | Electrolyte | η10/mV
| Tafel slope/(mV·dec-1)
| Mass loading/(mg·cm-2)
| Ref. |
---|
Fe-NC SAC | 0.1 mol·L-1 KOH
| 450 | 114 | 0.2 | [28] | SCoNC | 0.1 mol·L-1 KOH
| 310 | 74 | 0.25 | [32] | HCM@Ni-N | 1.0 mol·L-1 KOH
| 304 | 76 | 1.524(Carbon fiber paper) | [35] |
|
Table 2. OER electrocatalytic performances of non-noble metal single atom/nitrogen-doped carbon composites
Sample | Electrolyte | η10/mV
| Tafel slope/(mV∙dec-1)
| Mass loading/(mg∙cm-2)
| Ref. |
---|
NiFe@NC/RGO-240 | 1.0 mol·L-1 KOH
0.1 mol·L-1 KOH
| 223
303
| 48.7
70
| 0.31 | [41] | FeCo@MNC | 1.0 mol·L-1 KOH
| 240 | 60 | 0.36 | [42] | Ni1.5Co0.5 @NCNT/NF
| 0.1 mol·L-1 KOH
| 243 | 103 | ~0.56 | [44] | FeNi3@NC
| 1.0 mol·L-1 KOH
| 273 | 77 | - | [45] | FeNi@NC-2 | 1.0 mol·L-1KOH
| 298 | 48.4 | 0.337 | [46] | Ni3Fe-GA1
| 1.0 mol·L-1KOH
| 239 | 44.8 | 0.25 | [47] | NiFe/N-CNT | 0.1 mol·L-1 KOH
| 290 | 79 | 0.4 | [48] | Co-FeCo/N-G | 1.0 mol·L-1 KOH
| 258 | 34 | - | [49] |
|
Table 3. OER electrocatalytic performances of non-noble alloy/nitrogen-doped carbon composites
Sample | Electrolyte | η10/mV
| Tafel slope/(mV∙dec-1)
| Mass loading/(mg∙cm-2)
| Ref. |
---|
CoOx@CN
| 1.0 mol·L-1 KOH
| 260 | - | 2.1(Nickel foam) | [58] | N-Co3O4(500 ℃)
| 1.0 mol·L-1 KOH
0.1 mol·L-1 KOH
| 190
300
| 29.8
36.3
| ~3.467 | [59] | N-CoO | 1.0 mol·L-1 KOH
| 319 | 74.0 | - | [60] | CoO/Co@N-C | 0.1 mol·L-1 KOH
| 442 | 78.0 | 0.170 | [61] |
|
Table 4. OER electrocatalytic performance of non-noble metal oxide/nitrogen-doped carbon composites