• Journal of Inorganic Materials
  • Vol. 37, Issue 2, 163 (2021)
Yongsheng FU, Min BI, Chun LI, Jingwen SUN, Xin WANG, and Junwu ZHU*
Author Affiliations
  • Key Laboratory for Soft Chemistry and Functional Materials of Ministry of Education, Nanjing University of Science and Technology, Nanjing 210094, China
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    DOI: 10.15541/jim20210015 Cite this Article
    Yongsheng FU, Min BI, Chun LI, Jingwen SUN, Xin WANG, Junwu ZHU. Research Progress on Non-noble Metal/Nitrogen-doped Carbon Composite Materials in Electrocatalytic Oxygen Evolution Reaction[J]. Journal of Inorganic Materials, 2021, 37(2): 163 Copy Citation Text show less
    Classification of non-noble metal/nitrogen-doped carbon composite materials
    1. Classification of non-noble metal/nitrogen-doped carbon composite materials
    Synthesis schemes of (a) Co@CNT/NC composites[23], (b) Co-MOF//NF and Co-NCNTFs//NF[25]; (c) OER polarization curves with 85% iR compensation in a 1 mol·L-1 KOH solution at a scan rate of 1 mV·s-1 and (d) related Tafel plots of Co-MOF//NF, Co-NCNTFs//NF, bare Ni foam, and RuO2[25]; (e) Stability tests of Co-NCNTFs//NF for OER and HER at a current density of 10 mA·cm-2[25]; (f) Illustration of the Co@NC/CC composite fabrication[27]
    2. Synthesis schemes of (a) Co@CNT/NC composites[23], (b) Co-MOF//NF and Co-NCNTFs//NF[25]; (c) OER polarization curves with 85% iR compensation in a 1 mol·L-1 KOH solution at a scan rate of 1 mV·s-1 and (d) related Tafel plots of Co-MOF//NF, Co-NCNTFs//NF, bare Ni foam, and RuO2[25]; (e) Stability tests of Co-NCNTFs//NF for OER and HER at a current density of 10 mA·cm-2[25]; (f) Illustration of the Co@NC/CC composite fabrication[27]
    (a) “Confined recrystallization” self-template synthesis strategy for Fe-NC SAC[28]; (b) Schematic illustration of the synthetic procedure of the SCoNC catalysts[32]; (c) Schematic description of the synthetic process, (d, e) FESEM and (f) TEM images of the HCM@Ni-N[35]; (g, h) FESEM and (i) TEM images for HCM@Ni-N after continuous operation for 10 h[35]; (j) LSV curves in 1.0 mol·L-1 KOH and (k) the related Tafel plots of HCM@Ni-N, HCM@Ni, HCM@N, and HCM[35]
    3. (a) “Confined recrystallization” self-template synthesis strategy for Fe-NC SAC[28]; (b) Schematic illustration of the synthetic procedure of the SCoNC catalysts[32]; (c) Schematic description of the synthetic process, (d, e) FESEM and (f) TEM images of the HCM@Ni-N[35]; (g, h) FESEM and (i) TEM images for HCM@Ni-N after continuous operation for 10 h[35]; (j) LSV curves in 1.0 mol·L-1 KOH and (k) the related Tafel plots of HCM@Ni-N, HCM@Ni, HCM@N, and HCM[35]
    Schematic synthesis process of (a) FeCo@MNC[42], (b) Ni1.5Co0.5 @ N-C NT/NFs[44] and (c) FeNi@NC-x[46]; (d) SEM image of FeNi@NC-2[46]; (e) LSV curves and (f)Tafel plots of RuO2, and FeNi@NC-x[46]; (g) Illustration of the preparation of Ni3Fe-GAs[47]; (h,i) SEM images and (j) TEM image for Ni3Fe-GA1[47]; (k) OER polarization curves and (l) corresponding Tafel plots for Ni3Fe-GAs[47]; (m) Chronopotentiometric curves of Ni3Fe-GA1 and IrO2 catalysts[47]
    4. Schematic synthesis process of (a) FeCo@MNC[42], (b) Ni1.5Co0.5 @ N-C NT/NFs[44] and (c) FeNi@NC-x[46]; (d) SEM image of FeNi@NC-2[46]; (e) LSV curves and (f)Tafel plots of RuO2, and FeNi@NC-x[46]; (g) Illustration of the preparation of Ni3Fe-GAs[47]; (h,i) SEM images and (j) TEM image for Ni3Fe-GA1[47]; (k) OER polarization curves and (l) corresponding Tafel plots for Ni3Fe-GAs[47]; (m) Chronopotentiometric curves of Ni3Fe-GA1 and IrO2 catalysts[47]
    (a) Illustration of the synthesis process of N-Co3O4 and N-CoO/C[59]; SEM images of (b, c) CoO and (d, e) N-CoO nanowire arrays[60]; (f) Illustration of the synthesis process of CoO/Co@N-C[61]; SEM images of (g) Co3O4 and (h) Co3O4@Glu microspheres, and (i) CoO/Co@N-C electrocatalyst[61]; (j) LSV curves and (k) Tafel plots of CoO@N-C, CoO/Co@N-C, CoO/Co@N-C-x samples that etched in HCl with x representing etching time, Ir/C and Pt/C in 0.1 mol·L-1 KOH solution; (l) LSV curves for the CoO/Co@N-C electrocatalyst before and after 2000 CV cycles in 0.1 mol·L-1 KOH solution[61]
    5. (a) Illustration of the synthesis process of N-Co3O4 and N-CoO/C[59]; SEM images of (b, c) CoO and (d, e) N-CoO nanowire arrays[60]; (f) Illustration of the synthesis process of CoO/Co@N-C[61]; SEM images of (g) Co3O4 and (h) Co3O4@Glu microspheres, and (i) CoO/Co@N-C electrocatalyst[61]; (j) LSV curves and (k) Tafel plots of CoO@N-C, CoO/Co@N-C, CoO/Co@N-C-x samples that etched in HCl with x representing etching time, Ir/C and Pt/C in 0.1 mol·L-1 KOH solution; (l) LSV curves for the CoO/Co@N-C electrocatalyst before and after 2000 CV cycles in 0.1 mol·L-1 KOH solution[61]
    SampleElectrolyteη10/mV Tafel slope/(mV·dec-1) Mass loading/(mg·cm-2) Ref.
    Co@CNT/NC-10001.0 mol·L-1 KOH 28282~12.73[23]
    Co-NCNTFs//NF1.0 mol·L-1 KOH 230944.1(Nickel foam)[25]
    Co@NC/CC1.0 mol·L-1 KOH 29073-[27]
    Table 1. OER electrocatalytic performances of non-noble metal/nitrogen-doped carbon composites
    SampleElectrolyteη10/mV Tafel slope/(mV·dec-1) Mass loading/(mg·cm-2) Ref.
    Fe-NC SAC0.1 mol·L-1 KOH 4501140.2[28]
    SCoNC0.1 mol·L-1 KOH 310740.25[32]
    HCM@Ni-N1.0 mol·L-1 KOH 304761.524(Carbon fiber paper)[35]
    Table 2. OER electrocatalytic performances of non-noble metal single atom/nitrogen-doped carbon composites
    SampleElectrolyteη10/mV Tafel slope/(mV∙dec-1) Mass loading/(mg∙cm-2) Ref.
    NiFe@NC/RGO-2401.0  mol·L-1 KOH 0.1  mol·L-1 KOH 223 303 48.7 70 0.31[41]
    FeCo@MNC1.0 mol·L-1 KOH 240600.36[42]
    Ni1.5Co0.5 @NCNT/NF 0.1 mol·L-1 KOH 243103~0.56[44]
    FeNi3@NC 1.0 mol·L-1 KOH 27377-[45]
    FeNi@NC-21.0 mol·L-1KOH 29848.40.337[46]
    Ni3Fe-GA1 1.0 mol·L-1KOH 23944.80.25[47]
    NiFe/N-CNT0.1 mol·L-1 KOH 290790.4[48]
    Co-FeCo/N-G1.0 mol·L-1 KOH 25834-[49]
    Table 3. OER electrocatalytic performances of non-noble alloy/nitrogen-doped carbon composites
    SampleElectrolyteη10/mV Tafel slope/(mV∙dec-1) Mass loading/(mg∙cm-2) Ref.
    CoOx@CN 1.0  mol·L-1 KOH 260-2.1(Nickel foam)[58]
    N-Co3O4(500 ℃) 1.0 mol·L-1 KOH 0.1 mol·L-1 KOH 190 300 29.8 36.3 ~3.467[59]
    N-CoO1.0 mol·L-1 KOH 319 74.0-[60]
    CoO/Co@N-C0.1 mol·L-1 KOH 44278.00.170[61]
    Table 4. OER electrocatalytic performance of non-noble metal oxide/nitrogen-doped carbon composites
    Yongsheng FU, Min BI, Chun LI, Jingwen SUN, Xin WANG, Junwu ZHU. Research Progress on Non-noble Metal/Nitrogen-doped Carbon Composite Materials in Electrocatalytic Oxygen Evolution Reaction[J]. Journal of Inorganic Materials, 2021, 37(2): 163
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