• Journal of Inorganic Materials
  • Vol. 37, Issue 2, 163 (2021)
Yongsheng FU, Min BI, Chun LI, Jingwen SUN, Xin WANG, and Junwu ZHU*
Author Affiliations
  • Key Laboratory for Soft Chemistry and Functional Materials of Ministry of Education, Nanjing University of Science and Technology, Nanjing 210094, China
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    DOI: 10.15541/jim20210015 Cite this Article
    Yongsheng FU, Min BI, Chun LI, Jingwen SUN, Xin WANG, Junwu ZHU. Research Progress on Non-noble Metal/Nitrogen-doped Carbon Composite Materials in Electrocatalytic Oxygen Evolution Reaction[J]. Journal of Inorganic Materials, 2021, 37(2): 163 Copy Citation Text show less

    Abstract

    Oxygen evolution reaction (OER) suffers from four-electron transfer, sluggish kinetics and high energy requirements, limiting the development of new energy technologies such as hydrogen production from water electrolysis. In recent years, non-noble metal composite catalysts have attracted increasing attention due to their advantages of excellent catalytic activity and cost compared with noble metal-based catalysts. This review summarizes the latest progress in this field. Firstly, the OER mechanism and the evaluation methods of catalytic performance are briefly introduced. Then the non-noble metal/nitrogen-doped carbon composites are further classified into metal/nitrogen-doped carbon composites, metal single atom/nitrogen-doped carbon composites, alloy/nitrogen-doped carbon composites, and metal oxide/nitrogen-doped carbon composites. The research progress of the electrocatalysts is summarized and analyzed based on the synthesis method and catalytic activity, aiming to explore the role of nitrogen-doped carbon materials in catalyst structure and catalyst performance. Finally, perspectives are given out for the current problems and future directions of non-noble metal/nitrogen-doped carbon composites.
    4OH-→ O2(g)+2H2O(l)+4e-

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    M+OH-→MOH+e-

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    MOH+OH-→ MO + H2O(l) + e-

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    2MO → 2M + O2(g)

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    MO + OH-→ MOOH + e-

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    MOOH + OH-→ M + O2(g) + H2O(l) + e-

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    $ \eta =a+b\text{lg}|j| $

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    Yongsheng FU, Min BI, Chun LI, Jingwen SUN, Xin WANG, Junwu ZHU. Research Progress on Non-noble Metal/Nitrogen-doped Carbon Composite Materials in Electrocatalytic Oxygen Evolution Reaction[J]. Journal of Inorganic Materials, 2021, 37(2): 163
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