• Journal of Inorganic Materials
  • Vol. 37, Issue 2, 117 (2021)
Fengjuan ZHANG1、2, Boning HAN2、3, and Haibo ZENG2、*
Author Affiliations
  • 11. Key Laboratory for Special Functional Materials, Henan University, Kaifeng 475004, China
  • 22. MIIT Key Laboratory of Advanced Display Materials and Devices, School of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
  • 33. Tianjin Key Lab for Photoelectric Materials & Devices, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China
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    DOI: 10.15541/jim20210441 Cite this Article
    Fengjuan ZHANG, Boning HAN, Haibo ZENG. Perovskite Quantum Dot Photovoltaic and Luminescent Concentrator Cells: Current Status and Challenges[J]. Journal of Inorganic Materials, 2021, 37(2): 117 Copy Citation Text show less
    Schematic diagram of perovskite quantum dot solar cells with (a) mesoporous structure and (b) planar heterojunction structure, and (c) schematic diagram of energy levels and electron transfer processes of perovskite solar cells[23]
    1. Schematic diagram of perovskite quantum dot solar cells with (a) mesoporous structure and (b) planar heterojunction structure, and (c) schematic diagram of energy levels and electron transfer processes of perovskite solar cells[23]
    (a) Crystal structure diagram and composition regulation of PQDs (1 Å=0.1 nm); (b) Illustration of the A site cation exchange process and the corresponding photoluminescence (PL) spectra of PQDs[26]; (c) Illustration of the electronic band structure of typical defect intolerant semiconductors and defect tolerant perovskites[36]; (d) Schematic of Pb2+ at B site partially substituted by various metal ions to improve stability[41]
    2. (a) Crystal structure diagram and composition regulation of PQDs (1 Å=0.1 nm); (b) Illustration of the A site cation exchange process and the corresponding photoluminescence (PL) spectra of PQDs[26]; (c) Illustration of the electronic band structure of typical defect intolerant semiconductors and defect tolerant perovskites[36]; (d) Schematic of Pb2+ at B site partially substituted by various metal ions to improve stability[41]
    (a) Theoretical model and adsorption energy for various ligands with different chain length adsorbed on the surface of α-CsPbI3 QDs; (b) Schematic of the stabilization mechanism of CsPbI3 QDs in C8 and C8/C18 ligand systems[46]; (c) Schematic of layer-by-layer assembly of PQDs[12]; (d) Schematic of anion and cation ligand exchange reaction of PQD films[53]; (e) AX salt post-treatment process of the PQD films[55]; (f) Illustration of enhanced electrical coupling between the GA-capped PQDs as a result of reduced interdot distance[57]
    3. (a) Theoretical model and adsorption energy for various ligands with different chain length adsorbed on the surface of α-CsPbI3 QDs; (b) Schematic of the stabilization mechanism of CsPbI3 QDs in C8 and C8/C18 ligand systems[46]; (c) Schematic of layer-by-layer assembly of PQDs[12]; (d) Schematic of anion and cation ligand exchange reaction of PQD films[53]; (e) AX salt post-treatment process of the PQD films[55]; (f) Illustration of enhanced electrical coupling between the GA-capped PQDs as a result of reduced interdot distance[57]
    (a) Energy band structures for SC based on PQDs with different compositions[12] with horizontal dotted line indicating the Fermi level positions; (b) Schemati of FAPbI3 QD/ITIC film fabrication[60]; (c) Schematic of the charge transport process and stabilization mechanism for SC based on µ-graphene crosslinked PQDs[64]; (d) Schematic of Cs-treatment on mesoporous TiO2, and schematic view and J-V curve of corresponding SC with mesoporous structure[65]; (e) P3HT modified PQD film[71]; (f) Energy band structures of SC with different polymeric HTM[72]
    4. (a) Energy band structures for SC based on PQDs with different compositions[12] with horizontal dotted line indicating the Fermi level positions; (b) Schemati of FAPbI3 QD/ITIC film fabrication[60]; (c) Schematic of the charge transport process and stabilization mechanism for SC based on µ-graphene crosslinked PQDs[64]; (d) Schematic of Cs-treatment on mesoporous TiO2, and schematic view and J-V curve of corresponding SC with mesoporous structure[65]; (e) P3HT modified PQD film[71]; (f) Energy band structures of SC with different polymeric HTM[72]
    (a) Operating principle of a luminescent concentrator cell[76]; (b) Photos of Yb3+ doped PQDs luminescent solar concentrator (LSC) under sunlight and ultraviolet radiation and its light conversion diagram[8]; (c) Schematic illustration and energy transfer (ET) process of Mn2+/Yb3+ co-doped CsPbCl3 quantum dots[9]; (d) Top: near-infrared LSC using triphenylphosphine treatment strategy, below: optical efficiency of the luminescent concentrator cell coupled with LSC and silicon cell as a function of G-factor[82]
    5. (a) Operating principle of a luminescent concentrator cell[76]; (b) Photos of Yb3+ doped PQDs luminescent solar concentrator (LSC) under sunlight and ultraviolet radiation and its light conversion diagram[8]; (c) Schematic illustration and energy transfer (ET) process of Mn2+/Yb3+ co-doped CsPbCl3 quantum dots[9]; (d) Top: near-infrared LSC using triphenylphosphine treatment strategy, below: optical efficiency of the luminescent concentrator cell coupled with LSC and silicon cell as a function of G-factor[82]
    Fengjuan ZHANG, Boning HAN, Haibo ZENG. Perovskite Quantum Dot Photovoltaic and Luminescent Concentrator Cells: Current Status and Challenges[J]. Journal of Inorganic Materials, 2021, 37(2): 117
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