Author Affiliations
1Key Laboratory for Colloid and Interface Chemistry Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China2College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China3State Key Laboratory of Crystal Materials, School of Physics, Shandong University, Jinan 250100, China4Hefei National Laboratory for Physical Science at Microscale, University of Science and Technology of China, Hefei 230026, Chinashow less
1. Schematic illustration for the fabrication of CuO@Cu Mesh
2. (a) XRD pattern, (b) XPS spectrum, high-resolution XPS spectra of (c) Cu2p and (d) O1s for CuO@Cu Mesh
3. Structure characterizaton of (a-c) SEM, (d) TEM, (e)βHRTEM images, and (f) elements mappings of CuO@Cu Mesh
4. (a) Cycling performances, (b) first cyclic charge curves, (c) first cyclic EIS plots for half cells with Cu foil, Cu Mesh, CuO@Cu Mesh as current collectors
5. (a) Cycling performances, (b) rate performances and(c)first cyclic EIS plots of LFP full cells with CuO@Cu Mesh, Cu mesh and Cu foil as current collectors (1C=0.17 mA•mg-1)
6. (a) Cycling performances, (b) rate performances and (c) first cyclic EIS plots for LiNi0.6Co0.2Mn0.2O2 full cells with CuO@Cu Mesh, Cu mesh and Cu foil as current collectors (1C=0.18 mA•mg-1)
7. Current density distribution simulation for Comsol with CuO@Cu Mesh, Cu mesh and Cu foil as current collectors in presence of lithium dendrite (a,b) 3D model diagram; (c,d) 2D simplified simulation
S1. Photographs of (a) Cu mesh, (b) CuOx mesh, (c) CuO@Cu Mesh
S2. Magnified XRD pattern of CuO@Cu Mesh
S3. SEM images of Cu foil, Cu mesh and CuO@Cu Mesh in half cells after different cycles at 3 mA∙cm-2 & 1 mAh∙cm-2
S4. Magnified first cyclic charge curves for half cells with Cu foil, Cu Mesh, CuO@Cu Mesh as current collectors
S5. (a) Voltage profiles of CuO@Cu Mesh half-cell at the first cycle, (b) XRD patterns of CuO@Cu Mesh current collector at corresponding potentials