• Journal of Inorganic Materials
  • Vol. 35, Issue 8, 882 (2020)
Rui LI1, Hao WANG1, Qiang FU2, Ziyu TIAN1, Jianxu WANG3, Xiaojian MA1、*, Jian YANG1, and Yitai QIAN1、4
Author Affiliations
  • 1Key Laboratory for Colloid and Interface Chemistry Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China
  • 2College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
  • 3State Key Laboratory of Crystal Materials, School of Physics, Shandong University, Jinan 250100, China
  • 4Hefei National Laboratory for Physical Science at Microscale, University of Science and Technology of China, Hefei 230026, China
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    DOI: 10.15541/jim20190545 Cite this Article
    Rui LI, Hao WANG, Qiang FU, Ziyu TIAN, Jianxu WANG, Xiaojian MA, Jian YANG, Yitai QIAN. Stable Li-metal Depositon on Lithiophilic 3D CuO Nanosheet-decorated Cu Mesh[J]. Journal of Inorganic Materials, 2020, 35(8): 882 Copy Citation Text show less

    Abstract

    Lithium metal anode, due to its highest theoretical specific capacity (3860 mAh·g -1) and lowest electrochemical potential (-3.04 V (vs SHE)), has become the first choice of the next generation of electrochemical energy storage devices. It is known as the “holy grail” of the battery industry. However, the disadvantage of lithium metal battery is particularly obvious: during the charge and discharge process, lithium metal battery is easy to deposit unevenly on the anode electrode, resulting in lithium dendrite which causes the continuous rupture and formation of solid electrolyte interface (SEI) film. The unstable SEI film, intensifying the formation of lithium dendrites and then piercing the separator, causes a decline for the battery cycle performance and the safety hazard. Therefore, it is particularly important to take corresponding measures to make lithium metal uniformly deposited on the anode. In this study, the uniform lithiophilic copper oxide nanosheet array formed on the surface of commercial copper mesh through oxidation of alkaline solvent and calcination of air. The 3D structure of copper mesh can effectively reduce the current density, and the lithiophilic nanosheet array can effectively reduce the overpotential of lithium deposition simultaneously. This lithiophilic 3D copper-based current collector makes lithium deposited uniformly and effectively, and inhibits the formation of lithium dendrites. In the half-cell test at a current density of 3 mA·cm -2 the battery circulated stably for 230 cycles with Coulombic efficiency remaining above 99%. The lithium iron phosphate (LFP) full battery with the as-prepared material as current collector worked stably for more than 300 cycles at 1C(0.17 mA·mg -1) and present a capacity retention of ~95%. This study provides a new design strategy of 3D current collector for stable lithium metal batteries.
    Rui LI, Hao WANG, Qiang FU, Ziyu TIAN, Jianxu WANG, Xiaojian MA, Jian YANG, Yitai QIAN. Stable Li-metal Depositon on Lithiophilic 3D CuO Nanosheet-decorated Cu Mesh[J]. Journal of Inorganic Materials, 2020, 35(8): 882
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