• Laser & Optoelectronics Progress
  • Vol. 57, Issue 9, 091601 (2020)
Caiyan Lu1, Yongping Li1, Yufeng Yuan2、**, and Junxian Liu1、*
Author Affiliations
  • 1College of Physical Science and Technology, Guangxi Normal University, Guilin, Guangxi 541004, China
  • 2College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen, Guangdong 518061, China
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    DOI: 10.3788/LOP57.091601 Cite this Article Set citation alerts
    Caiyan Lu, Yongping Li, Yufeng Yuan, Junxian Liu. Ultrasensitive Biochemical Detection by Employing Two-Dimensional Ti3C2Tx MXene Nanosheets[J]. Laser & Optoelectronics Progress, 2020, 57(9): 091601 Copy Citation Text show less
    Schematic of SPR sensor enhanced by two-dimensional Ti3C2Tx MXene nanosheet
    Fig. 1. Schematic of SPR sensor enhanced by two-dimensional Ti3C2Tx MXene nanosheet
    For the BAK1 prism/35 nm silver film/Ti3C2Tx MXene/monolayer graphene hybrid configuration, the calculated sensing performance by changing the number of Ti3C2Tx MXene layers when the excitation wavelength is 632.8 nm and the sensing medium is deionized water with the refractive index of 1.333. (a) Reflectivity; (b) phase
    Fig. 2. For the BAK1 prism/35 nm silver film/Ti3C2Tx MXene/monolayer graphene hybrid configuration, the calculated sensing performance by changing the number of Ti3C2Tx MXene layers when the excitation wavelength is 632.8 nm and the sensing medium is deionized water with the refractive index of 1.333. (a) Reflectivity; (b) phase
    SPR phase and reflectivity curves generated by the coupling BAK1 prism/35 nm silver film/3-layer Ti3C2Tx MXene/monolayer graphene when the excitation wavelength is 632.8 nm, and the sensing medium is deionized water with the refractive index of 1.333
    Fig. 3. SPR phase and reflectivity curves generated by the coupling BAK1 prism/35 nm silver film/3-layer Ti3C2Tx MXene/monolayer graphene when the excitation wavelength is 632.8 nm, and the sensing medium is deionized water with the refractive index of 1.333
    For the coupling BAK1 prism/silver film/Ti3C2Tx MXene/monolayer graphene SPR configuration, sensing performance changed with thicknesses of silver film and number of Ti3C2Tx MXene layers at Δnbio=0.0012 RIU when the excitation wavelength is 632.8 nm. (a) Phase difference; (b) angle deflection
    Fig. 4. For the coupling BAK1 prism/silver film/Ti3C2Tx MXene/monolayer graphene SPR configuration, sensing performance changed with thicknesses of silver film and number of Ti3C2Tx MXene layers at Δnbio=0.0012 RIU when the excitation wavelength is 632.8 nm. (a) Phase difference; (b) angle deflection
    Curves of phase difference changed with refractive index of medium by varying different thicknesses of silver film in the coupling BAK1 prism/silver film/Ti3C2Tx MXene/monolayer graphene SPR configuration when the excitation wavelength is 632.8 nm. (a) 30 nm; (b) 35 nm; (c) 40 nm; (d) 45 nm; (e) 50 nm; (f) 55 nm
    Fig. 5. Curves of phase difference changed with refractive index of medium by varying different thicknesses of silver film in the coupling BAK1 prism/silver film/Ti3C2Tx MXene/monolayer graphene SPR configuration when the excitation wavelength is 632.8 nm. (a) 30 nm; (b) 35 nm; (c) 40 nm; (d) 45 nm; (e) 50 nm; (f) 55 nm
    Simulated results at the sensing interface between Ti3C2Tx MXene and graphene. (a) Distribution of electric field intensity; (b) evanescent decay curve of electric field
    Fig. 6. Simulated results at the sensing interface between Ti3C2Tx MXene and graphene. (a) Distribution of electric field intensity; (b) evanescent decay curve of electric field
    Comparison of the SPR sensing performances for different structures when the excitation wavelength is 632.8 nm
    Fig. 7. Comparison of the SPR sensing performances for different structures when the excitation wavelength is 632.8 nm
    λ /nmRefractive index
    AuAgSF11BAF10BAK1BK7
    5320.5438+2.2309i0.0540+3.4290i1.79481.67471.57581.5195
    632.81.7231+4.7557i0.0563+4.2760i1.77861.66711.57041.5151
    7850.1489+4.7830i0.0345+5.4581i1.76551.66051.56571.5111
    9800.2178+6.3201i0.0400+6.9264i1.75661.65551.56201.5078
    15500.0344+5.4581i0.1445+11.3660i1.74341.64691.55521.5007
    Table 1. Refractive indexes of SF11, BAF10, BAK1, BK7, gold film, and silver film
    λ /nmMetalPrismdmetal /nmNumberof MXenelayersθSPR /(°)ΔθSPR /(°)nbio=0.001)Δφd /(°)Sp /[(°)/RIU]FWTM /(°)Rmin
    Δnbio=10-6Δnbio=0.0012
    1550AuBK730264.000.2680.0001106.168.85×1040.09744.51×10-7
    980AuSF1133452.010.0610.443380.687.17×1040.41154.08×10-5
    785AuSF1133553.890.0240.509688.017.33×1040.29094.74×10-5
    632.8AuBAK140237.000.0271.80543.923.27×1030.43804.77×10-7
    532AuSF1130559.460.0052.6198108.359.03×1040.08202.65×10-7
    1550AgBAF1036254.800.6360.105012.641.05×1040.09905.22×10-5
    980AgBAK131561.600.0882.655599.228.27×1040.09841.73×10-6
    785AgBAF1030557.840.0420.903889.217.43×1040.09793.95×10-6
    632.8AgBAK135365.270.12135.0396110.559.21×1040.09693.48×10-9
    532AgBAK150066.840.1202.1918100.298.36×1040.09666.81×10-6
    Table 2. Results of optimized SPR sensing performance
    Caiyan Lu, Yongping Li, Yufeng Yuan, Junxian Liu. Ultrasensitive Biochemical Detection by Employing Two-Dimensional Ti3C2Tx MXene Nanosheets[J]. Laser & Optoelectronics Progress, 2020, 57(9): 091601
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