• Journal of Inorganic Materials
  • Vol. 35, Issue 8, 902 (2020)
Yuehong PENG1、2, Weizhou REN1, Jianbei QIU1, Jin HAN1, Zhengwen YANG1, and Zhiguo SONG1、*
Author Affiliations
  • 1School of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China
  • 2School of Physics and Electronical Science, Chuxiong Normal University, Chuxiong 675000, China
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    DOI: 10.15541/jim20190462 Cite this Article
    Yuehong PENG, Weizhou REN, Jianbei QIU, Jin HAN, Zhengwen YANG, Zhiguo SONG. Upconversion Luminescence and Temperature Sensing Properties of Layered BiOCl: Er3+ under 1550 nm Excitation [J]. Journal of Inorganic Materials, 2020, 35(8): 902 Copy Citation Text show less
    XRD patternsof BiOCl with different Er3+ concentrations (a), effect of Er3+ concentration on the main diffraction peak near 2θ = 32º-34.5º (b), SEM image of BiOCl:Er3+(c), and the structure modelof BiOCl crystal (d)
    1. XRD patternsof BiOCl with different Er3+ concentrations (a), effect of Er3+ concentration on the main diffraction peak near 2θ = 32º-34.5º (b), SEM image of BiOCl:Er3+(c), and the structure modelof BiOCl crystal (d)
    UC spectra (a) of BiOCl with different Er3+ concentrations (from 1mol% to 5mol%) under 1550 nm excitation and the dependence of Ired/Igreen on Er3+ concentrations (b)
    2. UC spectra (a) of BiOCl with different Er3+ concentrations (from 1mol% to 5mol%) under 1550 nm excitation and the dependence of Ired/Igreen on Er3+ concentrations (b)
    Dependence of the UC emission on power (a), energy-level diagram of Er3+ and possible up-conversion mechanism of BiOCl:Er3+ under 1550 nm excitation (b)
    3. Dependence of the UC emission on power (a), energy-level diagram of Er3+ and possible up-conversion mechanism of BiOCl:Er3+ under 1550 nm excitation (b)
    Normalized up-conversion emission spectra of BiOCl:4mol%Er3+ under 1550 nm excitation at various temperatures (300-560 K) (a), relative intensities of 525, 542 and 670 nm emissions as a function of temperature (b), and the dependence of Ired/Igreen on temperature (c)
    4. Normalized up-conversion emission spectra of BiOCl:4mol%Er3+ under 1550 nm excitation at various temperatures (300-560 K) (a), relative intensities of 525, 542 and 670 nm emissions as a function of temperature (b), and the dependence of Ired/Igreen on temperature (c)
    Dependence of the fluorescence intensity ratio, the absolute sensitivity (SA) and the relative sensitivity (SR) on temperature
    5. Dependence of the fluorescence intensity ratio, the absolute sensitivity (SA) and the relative sensitivity (SR) on temperature
    FT-IR (a) and EPR (b) spectra for BiOCl:Er3+ powders
    6. FT-IR (a) and EPR (b) spectra for BiOCl:Er3+ powders
    UC materialsRTemperature range/KSA/(×10-3, K-1)SR/(%, K-1)Reference
    NaYF4:Er3+/Yb3+/Li+I523/I547300-4535.91.46[11]
    KMnF3:Yb3+/Er3+Ired/Igreen303-39011.35.7[2]
    YWO6:0.1Yb3+/0.02Er3+I524/I675303-5632.21.2[8]
    Ba2In2O5:Yb3+/Er3+I658/I549303-563480[10]
    BiOCl:Er3+I525/I542300-5604.231.15This work
    BiOCl:Er3+I670/I542300-56095.31.19This work
    Table 1. Maximum temperature sensitivity for several Er3+ doped UC materials
    Er3+ concentrationRSA/(×10-3, K-1)SR/(%, K-1)
    4mol%I670/I542=188.52exp(-1070.58/T)95.31.19
    5mol%I670/I542=231.85exp(-994.74/T)126.21.11
    Table 2. Maximum temperature sensitivity for BiOCl with different Er3+ concentrations
    Yuehong PENG, Weizhou REN, Jianbei QIU, Jin HAN, Zhengwen YANG, Zhiguo SONG. Upconversion Luminescence and Temperature Sensing Properties of Layered BiOCl: Er3+ under 1550 nm Excitation [J]. Journal of Inorganic Materials, 2020, 35(8): 902
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