• Journal of Inorganic Materials
  • Vol. 37, Issue 1, 22 (2022)
Xiao WANG*, Zhijie ZHU, Zhiyi WU, Chengcheng ZHANG, Zhijie CHEN, Mengqi XIAO, Chaoran LI, and Le HE
Author Affiliations
  • Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Institute of Functional Nano and Soft Materials (FUNSOM), Soochow University, Suzhou 215000, China
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    DOI: 10.15541/jim20210458 Cite this Article
    Xiao WANG, Zhijie ZHU, Zhiyi WU, Chengcheng ZHANG, Zhijie CHEN, Mengqi XIAO, Chaoran LI, Le HE. Preparation and Photothermal Catalytic Application of Powder-form Cobalt Plasmonic Superstructures[J]. Journal of Inorganic Materials, 2022, 37(1): 22 Copy Citation Text show less
    Preparation and characterization of Co-SiO2
    . Preparation and characterization of Co-SiO2
    XRD patterns of (a) ZIF-67, ZIF-67-SiO2, and (b) Co and Co-SiO2
    . XRD patterns of (a) ZIF-67, ZIF-67-SiO2, and (b) Co and Co-SiO2
    (a) Diffuse reflectance spectra of Co-SiO2 and Co (insets showing photographs of two catalysts), (b) dependence of calculated normalized extinction cross-section of Co nanostructures on the number of Co nanoparticles (n) in the chain, and surface temperature of (c) Co catalyst and (d) Co-SiO2 catalyst
    . (a) Diffuse reflectance spectra of Co-SiO2 and Co (insets showing photographs of two catalysts), (b) dependence of calculated normalized extinction cross-section of Co nanostructures on the number of Co nanoparticles (n) in the chain, and surface temperature of (c) Co catalyst and (d) Co-SiO2 catalyst
    Catalytic activity and CO selectivity of Co-SiO2 under different light intensities
    . Catalytic activity and CO selectivity of Co-SiO2 under different light intensities
    Stability of Co-SiO2 and Co in thermocatalytic CO2 hydrogenation at 300 ℃
    . Stability of Co-SiO2 and Co in thermocatalytic CO2 hydrogenation at 300 ℃
    (a) TEM image and (b) particle size distribution of spent Co-SiO2
    . (a) TEM image and (b) particle size distribution of spent Co-SiO2
    SampleMetal mass per unit area /(mg·cm-2) Size of Co/nmCO2 conversion /% CO selectivity /%
    Co-SiO2-1 0.412711.961.0
    Co-SiO2-2 0.862717.634.9
    Co-SiO2-3 1.42726.229.7
    Co-SiO2-4 1.72724.827.2
    Co-PS@SiO20.32250.970.4
    Table 1. CO2 conversion efficiencies of different catalysts in photothermal hydrogenation of carbon dioxide
    Xiao WANG, Zhijie ZHU, Zhiyi WU, Chengcheng ZHANG, Zhijie CHEN, Mengqi XIAO, Chaoran LI, Le HE. Preparation and Photothermal Catalytic Application of Powder-form Cobalt Plasmonic Superstructures[J]. Journal of Inorganic Materials, 2022, 37(1): 22
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