Fig. 1. Morphologies of CsPbBr
3 NCs synthesized at (a) 80 ℃, (b) 120 ℃ and (c) 140 ℃
[22]; (d) Variations of the PLQYs depending on the added amounts of ZnX
2 of CsPbBr3 NCs
[24]; (e) Spectra of white LED and (f) CIE color coordinates and color triangle based on CsPbBr
3 and CsPbBr
1.5I
1.5[25] Fig. 2. (a) TEM image of SiO
2-coating CsPbBr
3 NCs
[27]; (b) TEM image of SiO
2/CsPbBr
3 NCs with Janus structure; (c) Schematic of the whole formation process of CsPbBr
3/SiO
2 NCs with Janus structure
[29]; (d) Schematic of the two-step synthesis of CsPbX
3-zeolite-Y composites; Spectra change of white LEDs composed of (e) CsPb(Br,I)
3 perovskite QDs and (f) CsPb(Br,I)
3-zeolite-Y composites with increase of currents
[31]; (g) CIE color coordinate and color triangle of white LEDs based on mesoporous silica CsPbBr
3 NCs
[32] Fig. 3. (a) Schematics showing the Al
3+ doping in dimer form
[34]; Variety of (b) PL spectra and (c) PLQY of NCs with increase of doping ratio of Sn
2+[36]; Evolution of (d) EL spectra and (e) CIE color coordinates of white LEDs based on Mn
2+-doping CsPb(Br/Cl)
3[37] Fig. 4. (a) Crystal structure, (b) PL and PLE spectra, (c) schematic configuration coordinate for the excited-state reorganization of Cs
3Cu
2I
5[46]; (d) PL spectra of Cs
3Cu
2Cl
5 and CsCu
2Cl
3 synthesized at different temperatures
[39]; (e) Power-dependent PL spectra of Cs
4MnBi
2Cl
12; (f) Spectra of white LEDs based on Cs
4MnBi
2Cl
12[40] Fig. 5. (a) Crystal structure and (b) PL spectra excited under 310 nm of Pb
2+-doped Cs
3Cu
2Br
5[41]; (c) White-light PL spectra in Sb
3+/B
i3+-codoped Cs
2NaInCl
6[42]; (d) Optical absorption and PL spectra of Cs
2AgInCl
6 and Cs
2Ag
0.6Na
0.4InCl
6[43]; (e) PL spectra of Cs
2AgIn
0.6B
0.15La
0.25Cl
6 and Cs
2AgIn
0.8Bi
0.2Cl
6[47]; (f) CIE color coordinates of Li
+/K
+ alloyed Cs
2AgBi
0.01In
0.99Cl
6[48] Fig. 6. (a) Schematic of band structure and (b) variety of EL spectra with the changes of blend ratio of white LED in CsPbBr
xCl
3−x/MEH:PPV as luminous layer
[50]; (c) Device structure, (d) EL spectrum, (e) current density-voltage and luminance-voltage curves, (f) EQE-current density and current efficiency-current density curves of white LEDs mixed with
α/
δ-CsPbI
3 emitting layers
[53] Fig. 7. (a) Schematic diagram of the preparation process of CsCu
2I
3@Cs
3Cu
2I
5 composites; (b) Absorption and PL spectra of the CsCu
2I
3@Cs
3Cu
2I
5 composites with varied CsI/CuI molar ratios precursor
[54]; Time-resolved GIWAXS profiles of CsCu
2I
3/Cs
3Cu
2I
5 composites (c) without Tween and (d) with Tween; (e) EL spectra of the device under different voltages and (f) curve of EQE versus current density
[55] of white LED after CsCu
2I
3/Cs
3Cu
2I
5processed by Tween
Fig. 8. (a) Bit-error rates(BERs) at different data rates
[56]; (b) Typical schematic diagrams of VLC test system
[58]; (c) Electrical-optical-electrical frequency response and (d) received signal-to-noise ratio of white LEDs signal in VLC system based on ZrO
2/CsPbBr
3[28]; (e) Frequency response of white LEDs at different current densities
[59]; (f) Constellation diagrams for white LEDs in VCL based on Cs
3Cu
2Cl
5 NCs
[60] Emitting materials | CIE coordinates | CCT
/K
| CRI | Luminous efficiency
/lm·W−1 | Gamut
NTSC
| Ref. | Photoluminescent WLEDs based on inorganic lead halide perovskites | CsPbBr3/CsPbBr1.2I1.8 | (0.33, 0.30) | | | | 120% | [20]
| CsPbBr3/CsPbBrxI3−x | (0.31, 0.34) | | | | | [21]
| CsPbBr3/red phosphors
| (0.334, 0.362) | 5447 | 93.2 | | | [22]
| CsPbBr3/red phosphors
| (0.33, 0.33) | 5569 | | 18.9 | 126% | [23]
| CsPbBr3/red phosphors
| (0.32, 0.30) | | | 98 | 130% | [24]
| CsPbBr3 nanocrystal and nanosheet/CsPbBr1.5I1.5 | (0.33, 0.34) | | | | 123% | [25]
| CsPbBr3/CsPb(Br/I)3 | (0.33, 0.33) | | | 61.2 | | [26]
| CsPbBr3/Ag-In-Zn-S
| (0.404, 0.411) | 3689 | 91 | 40.6 | | [27]
| CsPbBr3/red phosphors
| (0.351, 0.346) | 4743 | | 64 | | [28]
| CsPbBr3/CdSe
| (0.30, 0.32) | | 63 | | 138% | [29]
| CsPb(BrCl)3/CsPbBr3/CsPb(BrI)3 | (0.31, 0.38) | | | | | [30]
| CsPbBr3/CsPb(Br0.4,I0.6)3 | (0.38, 0.37) | 3876 | | | 114% | [31]
| CsPbBr3/CsPb(Br0.4I0.6)3 | (0.24, 0.28) | | | 30 | 113% | [32]
| Zn:CsPbCl3/CsPbBr3/CsPbI3 | (0.321, 0.296) | 6285 | 86.3 | 67.5 | 118% | [33]
| Al:CsPbBr3/CsPbBr3/CdSe@ZnS
| (0.32, 0.34) | | | 21.6 | 116% | [34]
| Nd:CsPbBr3/CsPbBr3/CsPbI3 | (0.34, 0.33) | 5310 | | | 122% | [35]
| Sn:CsPbBr3/CsPbBr3/Ag-In-Zn-S
| (0.41, 0.48) | 3954 | 89 | 43.2 | | [36]
| Mn:CsPb(Br/Cl)3/CsPbBr3 | | 3857 | 91 | 68.4 | | [37]
| Ce3+/Mn2+: CsPbClxBr3−x | (0.32, 0.29) | | 89 | 51 | | [38]
| Photoluminescent WLEDs based on inorganic lead-free perovskites | CsCu2Cl3/Cs3Cu2Cl5/red phosphors
| (0.37, 0.338) | 5285 | 94 | | | [39]
| Cs4MnBi2Cl12/green and blue phosphors
| (0.32, 0.30) | | | | | [40]
| Pb: Cs3Cu2Br5 | (0.333, 0.341) | 5469 | 98 | | | [41]
| Sb3+/Bi3+: Cs2NaInCl6 | | | | | | [42]
| Cs2(Ag0.6Na0.4)InCl6 | (0.396, 0.448) | 4054 | | | | [43]
|
|
Table 1. Optimized technologies and device parameters of typical inorganic perovskite white LEDs