• Infrared and Laser Engineering
  • Vol. 51, Issue 1, 20210772 (2022)
Shuangyi Zhao, Qionghua Mo, Baiqian Wang, and Zhigang Zang*
Author Affiliations
  • College of Optoelectronic Engineering, Chongqing University, Chongqing 400044, China
  • show less
    DOI: 10.3788/IRLA20210772 Cite this Article
    Shuangyi Zhao, Qionghua Mo, Baiqian Wang, Zhigang Zang. Research progress in inorganic perovskites white LEDs and visible light communication (Invited)[J]. Infrared and Laser Engineering, 2022, 51(1): 20210772 Copy Citation Text show less
    Morphologies of CsPbBr3 NCs synthesized at (a) 80 ℃, (b) 120 ℃ and (c) 140 ℃[22]; (d) Variations of the PLQYs depending on the added amounts of ZnX2 of CsPbBr3 NCs[24]; (e) Spectra of white LED and (f) CIE color coordinates and color triangle based on CsPbBr3 and CsPbBr1.5I1.5[25]
    Fig. 1. Morphologies of CsPbBr3 NCs synthesized at (a) 80 ℃, (b) 120 ℃ and (c) 140 ℃[22]; (d) Variations of the PLQYs depending on the added amounts of ZnX2 of CsPbBr3 NCs[24]; (e) Spectra of white LED and (f) CIE color coordinates and color triangle based on CsPbBr3 and CsPbBr1.5I1.5[25]
    (a) TEM image of SiO2-coating CsPbBr3 NCs[27]; (b) TEM image of SiO2/CsPbBr3 NCs with Janus structure; (c) Schematic of the whole formation process of CsPbBr3/SiO2 NCs with Janus structure[29]; (d) Schematic of the two-step synthesis of CsPbX3-zeolite-Y composites; Spectra change of white LEDs composed of (e) CsPb(Br,I)3 perovskite QDs and (f) CsPb(Br,I)3-zeolite-Y composites with increase of currents[31]; (g) CIE color coordinate and color triangle of white LEDs based on mesoporous silica CsPbBr3 NCs[32]
    Fig. 2. (a) TEM image of SiO2-coating CsPbBr3 NCs[27]; (b) TEM image of SiO2/CsPbBr3 NCs with Janus structure; (c) Schematic of the whole formation process of CsPbBr3/SiO2 NCs with Janus structure[29]; (d) Schematic of the two-step synthesis of CsPbX3-zeolite-Y composites; Spectra change of white LEDs composed of (e) CsPb(Br,I)3 perovskite QDs and (f) CsPb(Br,I)3-zeolite-Y composites with increase of currents[31]; (g) CIE color coordinate and color triangle of white LEDs based on mesoporous silica CsPbBr3 NCs[32]
    (a) Schematics showing the Al3+ doping in dimer form[34]; Variety of (b) PL spectra and (c) PLQY of NCs with increase of doping ratio of Sn2+[36]; Evolution of (d) EL spectra and (e) CIE color coordinates of white LEDs based on Mn2+-doping CsPb(Br/Cl)3[37]
    Fig. 3. (a) Schematics showing the Al3+ doping in dimer form[34]; Variety of (b) PL spectra and (c) PLQY of NCs with increase of doping ratio of Sn2+[36]; Evolution of (d) EL spectra and (e) CIE color coordinates of white LEDs based on Mn2+-doping CsPb(Br/Cl)3[37]
    (a) Crystal structure, (b) PL and PLE spectra, (c) schematic configuration coordinate for the excited-state reorganization of Cs3Cu2I5[46]; (d) PL spectra of Cs3Cu2Cl5 and CsCu2Cl3 synthesized at different temperatures[39]; (e) Power-dependent PL spectra of Cs4MnBi2Cl12; (f) Spectra of white LEDs based on Cs4MnBi2Cl12[40]
    Fig. 4. (a) Crystal structure, (b) PL and PLE spectra, (c) schematic configuration coordinate for the excited-state reorganization of Cs3Cu2I5[46]; (d) PL spectra of Cs3Cu2Cl5 and CsCu2Cl3 synthesized at different temperatures[39]; (e) Power-dependent PL spectra of Cs4MnBi2Cl12; (f) Spectra of white LEDs based on Cs4MnBi2Cl12[40]
    (a) Crystal structure and (b) PL spectra excited under 310 nm of Pb2+-doped Cs3Cu2Br5[41]; (c) White-light PL spectra in Sb3+/Bi3+-codoped Cs2NaInCl6[42]; (d) Optical absorption and PL spectra of Cs2AgInCl6 and Cs2Ag0.6Na0.4InCl6[43]; (e) PL spectra of Cs2AgIn0.6B0.15La0.25Cl6 and Cs2AgIn0.8Bi0.2Cl6[47]; (f) CIE color coordinates of Li+/K+ alloyed Cs2AgBi0.01In0.99Cl6[48]
    Fig. 5. (a) Crystal structure and (b) PL spectra excited under 310 nm of Pb2+-doped Cs3Cu2Br5[41]; (c) White-light PL spectra in Sb3+/Bi3+-codoped Cs2NaInCl6[42]; (d) Optical absorption and PL spectra of Cs2AgInCl6 and Cs2Ag0.6Na0.4InCl6[43]; (e) PL spectra of Cs2AgIn0.6B0.15La0.25Cl6 and Cs2AgIn0.8Bi0.2Cl6[47]; (f) CIE color coordinates of Li+/K+ alloyed Cs2AgBi0.01In0.99Cl6[48]
    (a) Schematic of band structure and (b) variety of EL spectra with the changes of blend ratio of white LED in CsPbBrxCl3−x/MEH:PPV as luminous layer[50]; (c) Device structure, (d) EL spectrum, (e) current density-voltage and luminance-voltage curves, (f) EQE-current density and current efficiency-current density curves of white LEDs mixed with α/δ-CsPbI3 emitting layers[53]
    Fig. 6. (a) Schematic of band structure and (b) variety of EL spectra with the changes of blend ratio of white LED in CsPbBrxCl3−x/MEH:PPV as luminous layer[50]; (c) Device structure, (d) EL spectrum, (e) current density-voltage and luminance-voltage curves, (f) EQE-current density and current efficiency-current density curves of white LEDs mixed with α/δ-CsPbI3 emitting layers[53]
    (a) Schematic diagram of the preparation process of CsCu2I3@Cs3Cu2I5 composites; (b) Absorption and PL spectra of the CsCu2I3@Cs3Cu2I5 composites with varied CsI/CuI molar ratios precursor[54]; Time-resolved GIWAXS profiles of CsCu2I3/Cs3Cu2I5 composites (c) without Tween and (d) with Tween; (e) EL spectra of the device under different voltages and (f) curve of EQE versus current density[55] of white LED after CsCu2I3/Cs3Cu2I5processed by Tween
    Fig. 7. (a) Schematic diagram of the preparation process of CsCu2I3@Cs3Cu2I5 composites; (b) Absorption and PL spectra of the CsCu2I3@Cs3Cu2I5 composites with varied CsI/CuI molar ratios precursor[54]; Time-resolved GIWAXS profiles of CsCu2I3/Cs3Cu2I5 composites (c) without Tween and (d) with Tween; (e) EL spectra of the device under different voltages and (f) curve of EQE versus current density[55] of white LED after CsCu2I3/Cs3Cu2I5processed by Tween
    (a) Bit-error rates(BERs) at different data rates[56]; (b) Typical schematic diagrams of VLC test system[58]; (c) Electrical-optical-electrical frequency response and (d) received signal-to-noise ratio of white LEDs signal in VLC system based on ZrO2/CsPbBr3[28]; (e) Frequency response of white LEDs at different current densities[59]; (f) Constellation diagrams for white LEDs in VCL based on Cs3Cu2Cl5 NCs[60]
    Fig. 8. (a) Bit-error rates(BERs) at different data rates[56]; (b) Typical schematic diagrams of VLC test system[58]; (c) Electrical-optical-electrical frequency response and (d) received signal-to-noise ratio of white LEDs signal in VLC system based on ZrO2/CsPbBr3[28]; (e) Frequency response of white LEDs at different current densities[59]; (f) Constellation diagrams for white LEDs in VCL based on Cs3Cu2Cl5 NCs[60]
    Emitting materialsCIE coordinatesCCT /K CRILuminous efficiency /lm·W−1Gamut NTSC Ref.
    Photoluminescent WLEDs based on inorganic lead halide perovskites
    CsPbBr3/CsPbBr1.2I1.8(0.33, 0.30)120%[20]
    CsPbBr3/CsPbBrxI3−x(0.31, 0.34)[21]
    CsPbBr3/red phosphors (0.334, 0.362)544793.2[22]
    CsPbBr3/red phosphors (0.33, 0.33)556918.9126%[23]
    CsPbBr3/red phosphors (0.32, 0.30)98130%[24]
    CsPbBr3 nanocrystal and nanosheet/CsPbBr1.5I1.5(0.33, 0.34)123%[25]
    CsPbBr3/CsPb(Br/I)3(0.33, 0.33)61.2[26]
    CsPbBr3/Ag-In-Zn-S (0.404, 0.411)36899140.6[27]
    CsPbBr3/red phosphors (0.351, 0.346)474364[28]
    CsPbBr3/CdSe (0.30, 0.32)63138%[29]
    CsPb(BrCl)3/CsPbBr3/CsPb(BrI)3(0.31, 0.38)[30]
    CsPbBr3/CsPb(Br0.4,I0.6)3(0.38, 0.37)3876114%[31]
    CsPbBr3/CsPb(Br0.4I0.6)3(0.24, 0.28)30113%[32]
    Zn:CsPbCl3/CsPbBr3/CsPbI3(0.321, 0.296)628586.367.5118%[33]
    Al:CsPbBr3/CsPbBr3/CdSe@ZnS (0.32, 0.34)21.6116%[34]
    Nd:CsPbBr3/CsPbBr3/CsPbI3(0.34, 0.33)5310122%[35]
    Sn:CsPbBr3/CsPbBr3/Ag-In-Zn-S (0.41, 0.48)39548943.2[36]
    Mn:CsPb(Br/Cl)3/CsPbBr338579168.4[37]
    Ce3+/Mn2+: CsPbClxBr3−x(0.32, 0.29)8951[38]
    Photoluminescent WLEDs based on inorganic lead-free perovskites
    CsCu2Cl3/Cs3Cu2Cl5/red phosphors (0.37, 0.338)528594[39]
    Cs4MnBi2Cl12/green and blue phosphors (0.32, 0.30)[40]
    Pb: Cs3Cu2Br5(0.333, 0.341)546998[41]
    Sb3+/Bi3+: Cs2NaInCl6[42]
    Cs2(Ag0.6Na0.4)InCl6(0.396, 0.448)4054[43]
    Table 1. Optimized technologies and device parameters of typical inorganic perovskite white LEDs
    Shuangyi Zhao, Qionghua Mo, Baiqian Wang, Zhigang Zang. Research progress in inorganic perovskites white LEDs and visible light communication (Invited)[J]. Infrared and Laser Engineering, 2022, 51(1): 20210772
    Download Citation