• Photonics Research
  • Vol. 9, Issue 9, 1767 (2021)
Chenjing Quan1、2、†, Xiao Xing2、†, Sihao Huang2, Mengfeifei Jin3, Tongchao Shi2, Zeyu Zhang2、4、5, Weidong Xiang3、6、*, Zhanshan Wang1、7、*, and Yuxin Leng2、4、8、*
Author Affiliations
  • 1School of Physics Science and Engineering, Tongji University, Shanghai 200092, China
  • 2State Key Laboratory of High Field Laser Physics and CAS Center for Excellence in Ultra-intense Laser Science, Shanghai Institute of Optics and Fine Mechanics (SIOM), Chinese Academy of Sciences (CAS), Shanghai 201800, China
  • 3College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China
  • 4Hangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, Hangzhou 310024, China
  • 5School of Physics and Electronics, Shandong Normal University, Jinan 250014, China
  • 6e-mail: xiangweidong001@126.com
  • 7e-mail: wangzs@tongji.edu.cn
  • 8e-mail: lengyuxin@mail.siom.ac.cn
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    DOI: 10.1364/PRJ.427155 Cite this Article Set citation alerts
    Chenjing Quan, Xiao Xing, Sihao Huang, Mengfeifei Jin, Tongchao Shi, Zeyu Zhang, Weidong Xiang, Zhanshan Wang, Yuxin Leng. Nonlinear optical properties of CsPbClxBr3-x nanocrystals embedded glass[J]. Photonics Research, 2021, 9(9): 1767 Copy Citation Text show less

    Abstract

    All-inorganic perovskite has attracted significant attention due to its excellent nonlinear optical characteristics. Stable and low-toxic perovskite materials have great application prospects in optoelectronic devices. Here, we study the nonlinear optical properties of CsPbClxBr3-x (x=1, 1.5, 2) nanocrystals (NCs) glass by open-aperture Z-scan. It is found that the two- (2PA) and three-photon absorption (3PA) intensity can be adjusted by the treatment temperature and the ratio of halide anions. The perovskite NCs glass treated at a high temperature has better crystallinity, resulting in stronger nonlinear absorption performance. In addition, the value of the 2PA parameter of CsPbCl1.5Br1.5 NCs glasses decreases when the incident pump intensity increases, which is ascribed to the saturation of 2PA and population inversion. Finally, the research results show that the 2PA coefficient (0.127 cm GW-1) and 3PA coefficient (1.21×10-5 cm3 GW-2) of CsPbCl1Br2 NCs glass with high Br anion content are larger than those of CsPbCl2Br1 and CsPbCl1.5Br1.5 NCs glasses. This is mainly due to the greater influence of Br anions on the symmetry of the perovskite structure, which leads to the redistribution of delocalized electrons. The revealed adjustable nonlinear optical properties of perovskite NCs glass are essential for developing stable and high-performance nonlinear optical devices.
    TOA(nPA)=1{1+(n1)αNLLeff{I0/[1+(z/z0)2]}n1}1/n1(n=1,2,3),

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    Imχ(3)=c2ε0n02βω,

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    Chenjing Quan, Xiao Xing, Sihao Huang, Mengfeifei Jin, Tongchao Shi, Zeyu Zhang, Weidong Xiang, Zhanshan Wang, Yuxin Leng. Nonlinear optical properties of CsPbClxBr3-x nanocrystals embedded glass[J]. Photonics Research, 2021, 9(9): 1767
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