Fig. 1. The electrospray and electrospray as a tool for material processing.(a) A close-up view of the Taylor cone with a fine jet attached to the cone, and the jet diameter is typically 10 to 10
4 nm, and details of the break-up process
31.
(b) A typical arrangement of the electrospray.
(c) Several typical outcomes of using electrospray as a material processing tool.
Fig. 2. (a) Electrospray printing setup with three-electrode configuration (emitter, extractor, and ground).
(b) Effect of driving field on line width. Inset: electrospray profile images from (left) experiments, (middle) Lagrangian model simulation, and (right) analytical model (Equation (12))
21.
Fig. 3. The impact of a single droplet on the solid and smooth substrate for the inkjet printing17.
(a) Side-view of impact process of neutral and charged droplets on mirror-like ITO glass.
(b) Neutral droplet and
(c) droplet charged at 63 pC. Impacting velocity for both senarios: 0.6 m/s, droplet radius: 1.25 mm
48.
Fig. 4. Three typical configurations of multiplexed electrosrpay.(a) Linear array of 19 silica capillaries
49.
(b) Multi-jet mode with 24 jets stabilized on the grooved nozzle
50.
(c) The three-electrode design
51.
(d) Planar array of silicon nozzles
51.
(e) CNC micromachined linear array made of brass
42.
Fig. 5. AFM images of the electrosprayed P3HT/PCBM-blend films on the PEDOT/PSS-coated ITO/glass.(a) As-cast.
(b) Solvent vapor soaking (SVS).
(c) Thermal annealing (TA), and
(d) SVS followed by TA. The white line on the AFM images are the cross-section height. The cartoons are schematic illustrations of the P3HT/PCBM morphologies, depicting the nanoscale phase transition of P3HT (wires) and PCBM (balls) as well as the pancake boundary
44.
Fig. 6. AFM image of the P3HT: PCBM layer. Acetone concentrations45.
(a) 5,
(b) 10,
(c) 15, and
(d) 20 vol%.
(e) Reference device.
Fig. 7. Surface morphology of continuous thin films by electrospray at various flow rates and substrate temperatures (thickness of thin films is ~200 nm)22.
(a) Optical microscopy images.
(b) AFM images.
(c) Raman intensity distribution.
(d) Ratio images of Lorentzian components (
R) derived from the Raman spectra,
Rave: average
R value.
(e) Current density map by C-AFM and
(f) carrier mobility vs.
Da numbers.
Fig. 8. SEM images of electrosprayed P3HT films fabricated with different h.(a) Low deposition density at 15.9 mm.
(b) 19.6 mm and
(c) 23.2 mm.
(d) High deposition density at 23.2 mm.
(e) GIXRD plot of a spin-cast P3HT film.
(f) GIXRD of electrosprayed P3HT film for
h= 23.2 mm
35.
Fig. 9. Schematics of
(a) electrospray deposition setup, and
(b) the formation of perovskite films by electrospray deposition
71. The inset photographs show the cone-jet and perovskite film.
Fig. 10. Top-view SEM images of electrospray printed film when
(a)tf>
te and
(b) when
tf <
te; the scale bar is 1 micron.
(c) PCE of electrospray printed and spin-coated devices. Inset: top-view and cross-sectional SEM images of TiO
2 films electrospray printed at
h=4, 3, 2 mm and spin-coated. Scale bar: 600 nm.
(d) PCE of perovskite solar cells by 4 fabrication conditions for Spiro-MeOTAD: electrosprayed with CB or DCB, and spin-coating with CB or DCB. Inset is the corresponding top-view SEM images. Scale bar: 400 nm.
(e) Cross-section view SEM image of an all electrospray printed photovoltaic device.
(f)J-V curves of the champion cell of the all-printed, all spin-coated devices and the device with only perovskite layer electrospray printed. Inset: PCE histogram of all-electrospray printed devices
47.
Fig. 11. Schematic diagram of
(a) electrostatic spray and
(b) formation of hierarchically structured TiO
2 nanospheres
100.
Fig. 12. SEM images of
(a) crack-free photoelectrode of HS TiO
2 spheres,
(b) cross-sectional image of the HS-TiO
2 layer,
(c) the non-structured TiO
2 layer by electrospray.
(d) HS-TiO
2 with diameter of 640 nm.
(e) HS-TiO
2 with diameter of 260 nm.
(f) A HS-TiO
2 of nanoclusters of P25.
(g) After heat treatment at 120 ℃ (for 10 min), and
(h) post-treated HS-TiO
2 layer with TiCl4 aq. solution
100.
Fig. 13. SEM image of the ZnO nanoparticles fabricated by (a) doctor-blade method and (b) large scale ZnO film prepared by electrospray technique after heat treated at 460 ℃ for 1 h
104.
Fig. 14. Multiscale of porous structures fabricated by electrospraying dense P25 suspensions. SEM images of the electrosprayed film from dense P25 suspensions to the substrate heated at 150 ℃ and 250 ℃36.
(a) Side view of the film showing decent film uniformity.
(b) Top view of the electrosprayed film.
(c) Closeup of the electrosprayed film showing the multiscale nature of the photo electrode.
Fig. 15. Comparison of a hybrid electrospray and spin coated DSSC with bilayer structure with a purely spin coated one37.
(a) SEM image of hybrid structure with close up of the interface in
(b).
(c) SEM cross section of a spin coated (5×) DSSC.
(d)J–V characteristics comparing the two structures (with the spin coated cell having TiO
2 blocking layers and TiCl
4 treatment).
Active layer | Perovskite | Polymer | DSSC |
(DMSO: dimethyl sulfoxide; DMF: N, N-dimethylformamide; DCB: dichlorobenzene; CB: chlorobenzene; OXY: o-xylene; EG: ethylene glycol)
| Solution | Newtonian | Non-Newtonian | Non-Newtonian (suspension) | Solute | Salt | Polymer | TiO2 nanoparticles | Solvent | Polar (DMSO, DMF, …) | Nonpolar (CB, DCB, OXY, …) | Polar (Ethanol, EG, …) | Electric conductivities | High (~1 S/m) | Low (~10-5 S/m) | Medium (~10-4 S/m) | Typical flow rate per source | 40 μL/h | 1000 μL/h | 300 μL/h | Typical droplet size | < 1 μm | ~20 μm | ~10 μm | Typical evaporation time | 0.1 ms | 10 ms | 1 ms |
|
Table 1. Comparison of electrospray printed active layers of three different solar cells.
Scalable method | Special conditions* | Best PCE | References |
*Special conditions refer to: humidity control, environment control and temperature. The omission of a certain condition means it is not required during the preparation of PSCs.
| Infiltration | \ | 12.8% | [82] | Brush printing | \ | 9.1% | [83] | Slot-die | \ | 12.6% | [84] | Doctor blade | Humidity controlled (15%-25%) | 10.7% | [80] | Slot-die | \ | 12.0% | [79] | Slot-die | \ | 14.7% | [81] | Screen-printing | High-temperature (500 ℃) | 13.3% | [85] | Blow drying | High-temperature (450 ℃), glove box | 17% | [24] | Electrospray printing | \ | 15.0% | [47] |
|
Table 2. Overview of PCE of the reported PSCs with all three layers (ETL, perovskite, and HTL) fabricated using scalable method
47.