Author Affiliations
1School of Physical science and Technology, Tianjin Polytechnic University, Tianjin 300387, China2Institute of Advanced Wear & Corrosion Resistance and Functional Materials, Jinan University, Guangzhou, Guangdong 510632, China;3Institute of Laser Engineering, Beijing University of Technology, Beijing 100124, Chinashow less
Fig. 1. XRD results of Al2O3/CoNiCrAlY coating at different energy densities
Fig. 2. Microstructures of coating before oxidation. (a) Bottom of E1 coating; (b) top of E1 coating; (c) Al2O3 distribution in E1 coating; (d) bottom of E2 coating; (e) top of E2 coating; (f) Al2O3 distribution in E2 coating; (g) bottom of E3 coating; (h) top of E3 coating; (i) Al2O3 distribution in E3 coating
Fig. 3. Oxidation kinetics curves of Al2O3/CoNiCrAlY coating at different energy densities. (a) Isothermal oxidation weight gain curves; (b) relationship curves between ΔW2 and oxidation time
Fig. 4. XRD results of Al2O3/CoNiCrAlY coating at different energy densities after oxidation
Fig. 5. Microstructures of coating after oxidation. (a) Surface of E1 coating; (b) enlarged view of region I in Fig. (a); (c) enlarged view of region Ⅱ in Fig. (a); (d) surface of E2 coating; (e) enlarged view of region ix in Fig. (d); (f) enlarged view of region vi in Fig. (d); (g) surface of E3 coating; (h) enlarged view of region ii in Fig. (g); (i) enlarged view of region vii in Fig. (g)
Fig. 6. Microstructures of cross section of coating after oxidation. (a)(b) Coating of E1 sample; (c)(d) coating of E2 sample; (e)(f) coating of E3 sample
Fig. 7. Coating oxidation models. (a) Initial stage of oxidation; (b) after some time oxidation
Element | Ni | Cr | Al | Y | Co |
---|
Mass fraction /% | 32.0 | 21.0 | 8.0 | 0.5 | 38.5 |
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Table 1. Chemical compositions of cladding material CoNiCrAlY
Sample | Spotdiameter /mm | Powder feedrate /(g·min-1) | Scanningspeed /(mm·s-1) | Laserpower /W | Energydensity /(J·mm-3) |
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E1 | 3.5 | 0.5 | 4 | 2000 | 51.98 | E2 | 3.5 | 0.5 | 6 | 2000 | 34.65 | E3 | 3.5 | 0.5 | 4 | 2500 | 64.97 |
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Table 2. Process parameters of laser cladding
Element | Co | O | Al | Cr | Ni | Y |
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Massfraction /% | 5.80 | 52.33 | 26.04 | 5.20 | 7.76 | 2.87 |
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Table 3. EDS analysis results of white particles
Position | Mass fraction /% |
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O | Al | Ni | Cr | Co | Si | Ti | Fe |
---|
Ⅰ | 24.32 | 1.28 | 3.86 | 62.12 | 3.90 | 3.26 | 1.26 | | Ⅱ | 29.03 | 5.49 | 12.18 | 38.93 | 14.37 | | | | Ⅲ | 29.11 | 43.91 | 9.59 | 7.00 | 10.39 | | | | Ⅳ | 24.20 | 18.80 | 14.18 | 25.58 | 17.24 | | | | Ⅴ | 35.47 | 17.48 | 12.65 | 20.74 | 13.66 | | | | Ⅵ | 18.31 | 35.75 | 17.18 | 10.79 | 17.97 | | | | Ⅶ | 37.57 | 57.41 | 2.45 | 1.13 | 1.44 | | | | Ⅷ | | 4.71 | 34.80 | 22.15 | 37.03 | | | 1.31 | Ⅸ | 30.17 | 27.57 | 16.53 | 13.64 | 12.09 | | | | Ⅹ | 29.33 | 8.79 | 9.72 | 33.42 | 17.71 | | 1.03 | | Ⅺ | 25.31 | 12.11 | 12.79 | 31.78 | 17.49 | | 0.52 | | Ⅻ | 30.94 | 8.44 | 9.84 | 33.20 | 17.58 | | | | iv | 21.50 | 9.95 | 12.83 | 35.89 | 19.83 | | | |
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Table 4. EDS results of Al2O3/CoNiCrAlY coating shown in Fig. 5
Position | Mass fraction /% |
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O | Al | Ni | Cr | Co | Si | Ti | P | N |
---|
C | | | 88.59 | | | | | 11.41 | | D | 8.70 | 9.65 | 33.15 | 29.16 | 19.34 | | | | | E | 15.17 | 31.46 | 36.45 | 6.79 | 10.13 | | | | | F | | 51.53 | 5.18 | 3.99 | 5.19 | | 3.15 | | 30.96 | G | 36.93 | 42.98 | 20.09 | | | | | | | L | 31.35 | 23.37 | 18.32 | 14.55 | 12.41 | | | | | M | 44.34 | 55.66 | | | | | | | | B | | 68.27 | | | | | | | 31.73 | A | | | 40.85 | 17.55 | 40.60 | | | | | S | 57.28 | 42.72 | | | | | | | | T | 45.93 | 54.07 | | | | | | | | V | | 81.14 | | | | | | | 18.86 |
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Table 5. EDS results of Al2O3/CoNiCrAlY coating shown in Fig. 6