• Journal of Inorganic Materials
  • Vol. 38, Issue 11, 1271 (2023)
Jia CAI1、2, Fangxia ZHAO1、*, Dong FAN1、2, Liping HUANG2, Yaran NIU2、*, Xuebin ZHENG2, and Zhenzhong ZHANG1
Author Affiliations
  • 11. College of Materials Science and Engineering, Nanjing Tech University, Nanjing 211816, China
  • 22. Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
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    DOI: 10.15541/jim20230143 Cite this Article
    Jia CAI, Fangxia ZHAO, Dong FAN, Liping HUANG, Yaran NIU, Xuebin ZHENG, Zhenzhong ZHANG. Pyrolysis Behavior and Laser Ablation Resistance of PCS in Polycarbosilane Composite Coatings[J]. Journal of Inorganic Materials, 2023, 38(11): 1271 Copy Citation Text show less
    Schematic of 10.6 μm CO2 laser examination device
    1. Schematic of 10.6 μm CO2 laser examination device
    XRD patterns of PT (a) and PY (b) coatings
    2. XRD patterns of PT (a) and PY (b) coatings
    Infrared spectra of products pyrolyzed from PT (a) and PY (b) coatings at different temperatures
    3. Infrared spectra of products pyrolyzed from PT (a) and PY (b) coatings at different temperatures
    TG (a) and DSC (b) curves of PT, PY and PCS
    4. TG (a) and DSC (b) curves of PT, PY and PCS
    XRD patterns of PT (a) and PY (b) coatings after heat-treated at different temperatures in air for 2 h
    5. XRD patterns of PT (a) and PY (b) coatings after heat-treated at different temperatures in air for 2 h
    Morphologies of YPT and YPY coatings ablated by 425 W/cm2 laser for different periods
    6. Morphologies of YPT and YPY coatings ablated by 425 W/cm2 laser for different periods
    Temperature curves of YPT (a) and YPY (b) coatings ablated by 425 W/cm2 laser for different periods
    7. Temperature curves of YPT (a) and YPY (b) coatings ablated by 425 W/cm2 laser for different periods
    XRD patterns of YPT (a) and YPY (b) coatings after 425 W/cm2 laser ablation for different periods
    8. XRD patterns of YPT (a) and YPY (b) coatings after 425 W/cm2 laser ablation for different periods
    Surface SEM morphologies of YPT and YPY coatings after 425 W/cm2, 5 s laser ablation
    9. Surface SEM morphologies of YPT and YPY coatings after 425 W/cm2, 5 s laser ablation
    Cross-sectional original SEM morphologies (a, d), cross-sectional morphologies (b, c, e, f) and EDS results (g, h) of YPT and YPY coatings after 425 W/cm2, 5 s laser ablation
    10. Cross-sectional original SEM morphologies (a, d), cross-sectional morphologies (b, c, e, f) and EDS results (g, h) of YPT and YPY coatings after 425 W/cm2, 5 s laser ablation
    Surface morphologies (a) and back surface morphologies (b) of YSZ, YPT and YPY coatings ablated by 2123 and 4246 W/cm2 laser for 5 and 10 s, respectively
    11. Surface morphologies (a) and back surface morphologies (b) of YSZ, YPT and YPY coatings ablated by 2123 and 4246 W/cm2 laser for 5 and 10 s, respectively
    XRD patterns of YPT (a) and YPY (b) coatings after 4246 W/cm2, 10 s laser ablation
    12. XRD patterns of YPT (a) and YPY (b) coatings after 4246 W/cm2, 10 s laser ablation
    SEM surface morphologies and EDS analyses of YSZ, YPT and YPY coatingsafter 4246 W/cm2, 10 s laser ablation
    13. SEM surface morphologies and EDS analyses of YSZ, YPT and YPY coatingsafter 4246 W/cm2, 10 s laser ablation
    Cross-sectional SEM morphologies and corresponding elements mapping of the central ablation area of YSZ (a), YPT (b) and YPY (c) coatings after 4246 W/cm2, 10 s laser ablation
    14. Cross-sectional SEM morphologies and corresponding elements mapping of the central ablation area of YSZ (a), YPT (b) and YPY (c) coatings after 4246 W/cm2, 10 s laser ablation
    CoatingsYSZNiCrAlY
    Ar/slpm30−4030−40
    H2/slpm5−155−15
    Spray distance/mm90−130200−300
    Feed rate/(r·min-1)15−3015−30
    Power/kW38−4830−40
    Table 1. Spray parameters of YSZ and NiCrAlY coatings[18]
    Jia CAI, Fangxia ZHAO, Dong FAN, Liping HUANG, Yaran NIU, Xuebin ZHENG, Zhenzhong ZHANG. Pyrolysis Behavior and Laser Ablation Resistance of PCS in Polycarbosilane Composite Coatings[J]. Journal of Inorganic Materials, 2023, 38(11): 1271
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