• Laser & Optoelectronics Progress
  • Vol. 56, Issue 17, 170606 (2019)
Haitao Guo1、*, Jian Cui1、2, Yantao Xu1、2, and Xusheng Xiao1
Author Affiliations
  • 1 State Key Laboratory of Transient Optics and Photonics, Xi'an Institute of Optics and Precision Mechanics, Chinese Academy of Sciences, Xi'an, Shaanxi 710119, China
  • 2 University of Chinese Academy of Sciences, Beijing 100045, China
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    DOI: 10.3788/LOP56.170606 Cite this Article Set citation alerts
    Haitao Guo, Jian Cui, Yantao Xu, Xusheng Xiao. Progress in Preparation and Applications of Low-Loss Chalcogenide Infrared Fibers[J]. Laser & Optoelectronics Progress, 2019, 56(17): 170606 Copy Citation Text show less
    Typical loss spectra of chalcogenide glass fibers manufactured by CorActive[5]. (a) IRT-SE; (b) IRT-SU
    Fig. 1. Typical loss spectra of chalcogenide glass fibers manufactured by CorActive[5]. (a) IRT-SE; (b) IRT-SU
    Loss spectra of (a) As39S61 and (b) As39Se61 fibers[11-12]
    Fig. 2. Loss spectra of (a) As39S61 and (b) As39Se61 fibers[11-12]
    Open-type distilled process flow chart for fabrication of Ge-Sb-Se glass[15]
    Fig. 3. Open-type distilled process flow chart for fabrication of Ge-Sb-Se glass[15]
    Loss spectrum of prepared As2S3 multi-mode fiber[16]
    Fig. 4. Loss spectrum of prepared As2S3 multi-mode fiber[16]
    Absorption coefficients of Ge-S-I glass synthesized by different methods[22]
    Fig. 5. Absorption coefficients of Ge-S-I glass synthesized by different methods[22]
    Schematics of drawing of chalcogenide glass fibers. (a) Double-crucible method; (b) rod in tube method; (c) extrusion method; (d) rotary tube method; (e) drawing fiber from preform
    Fig. 6. Schematics of drawing of chalcogenide glass fibers. (a) Double-crucible method; (b) rod in tube method; (c) extrusion method; (d) rotary tube method; (e) drawing fiber from preform
    As2S3 prepared by rod in tube method[14]. (a) As2S3 chalcogenide glass fiber preforms and As2S3 multimode fiber; (b) loss spectrum of As2S3 fiber
    Fig. 7. As2S3 prepared by rod in tube method[14]. (a) As2S3 chalcogenide glass fiber preforms and As2S3 multimode fiber; (b) loss spectrum of As2S3 fiber
    Extrusion equipment, chalcogenide glass fiber preforms, and loss spectrum of As2Se3 glass fiber prepared by Ningbo University[41-42]. (a) Extrusion equipment for glass fiber preforms; (b) chalcogenide glass fiber preforms with multi-mode and single-mode; (c) loss spectrum of single-mode As2Se3 fiber
    Fig. 8. Extrusion equipment, chalcogenide glass fiber preforms, and loss spectrum of As2Se3 glass fiber prepared by Ningbo University[41-42]. (a) Extrusion equipment for glass fiber preforms; (b) chalcogenide glass fiber preforms with multi-mode and single-mode; (c) loss spectrum of single-mode As2Se3 fiber
    Picture of chalcogenide multi-mode fiber-based combiner (7×1)[46]
    Fig. 9. Picture of chalcogenide multi-mode fiber-based combiner (7×1)[46]
    Line-plane-switching chalcogenide fiber array, infrared push-broom experimental system, and obtained infrared images of target[52]
    Fig. 10. Line-plane-switching chalcogenide fiber array, infrared push-broom experimental system, and obtained infrared images of target[52]
    Schematics of fabrication process for plane-plane fiber image bundles using stack-and-draw, and micrographs of cross sections of bundles[37]. (a) Process flow chart; (b) micrographs of cross sections of bundles
    Fig. 11. Schematics of fabrication process for plane-plane fiber image bundles using stack-and-draw, and micrographs of cross sections of bundles[37]. (a) Process flow chart; (b) micrographs of cross sections of bundles
    Developemnt of chalocogenide galss fiber based FBG
    Fig. 12. Developemnt of chalocogenide galss fiber based FBG
    Transmission spectra of FBG[55]
    Fig. 13. Transmission spectra of FBG[55]
    Development of chalcogenide Raman fiber lasers
    Fig. 14. Development of chalcogenide Raman fiber lasers
    A 3.34-μm cascaded Raman laser based on As2S3 fiber[60]. (a) Diagram; (b) relationship between average output power of 3.34 μm laser and pumping power
    Fig. 15. A 3.34-μm cascaded Raman laser based on As2S3 fiber[60]. (a) Diagram; (b) relationship between average output power of 3.34 μm laser and pumping power
    Structural diagram of Brillouin fiber laser[63]
    Fig. 16. Structural diagram of Brillouin fiber laser[63]
    Theoretical model of cascaded mid-infrared laser at 4.3 μm and 3.1 μm based on Dy3+ ions doped Ge20Ga5Sb10S65 fiber[67]. (a) Theoretical model of cascaded mid-infrared laser at 4.3 μm; (b) laser self-terminating mechanism
    Fig. 17. Theoretical model of cascaded mid-infrared laser at 4.3 μm and 3.1 μm based on Dy3+ ions doped Ge20Ga5Sb10S65 fiber[67]. (a) Theoretical model of cascaded mid-infrared laser at 4.3 μm; (b) laser self-terminating mechanism
    Optical photographs of surfaces of fiber preforms[85]. (a) Ge16.5As9Ga10Se64.5 glass doped with 0.2% DyCl3; (b) Ge16.5As9Ga10Se64.5 doped with 0.2% Dy foil
    Fig. 18. Optical photographs of surfaces of fiber preforms[85]. (a) Ge16.5As9Ga10Se64.5 glass doped with 0.2% DyCl3; (b) Ge16.5As9Ga10Se64.5 doped with 0.2% Dy foil
    Supercontinuum source based on all-fiber structure[87]
    Fig. 19. Supercontinuum source based on all-fiber structure[87]
    2-16 μm mid- and far-infrared supercontinuum spectra based on (Ge10Te43)90(AgI)10 fiber using 7 μm OPA laser as pump source[90]
    Fig. 20. 2-16 μm mid- and far-infrared supercontinuum spectra based on (Ge10Te43)90(AgI)10 fiber using 7 μm OPA laser as pump source[90]
    Infrared spectra of hepatic tissue of hungry and normal mice[91]
    Fig. 21. Infrared spectra of hepatic tissue of hungry and normal mice[91]
    CO2 gas detector based on Pr3+/Dy3+ co-doped Ga5Ge20Sb10S65 fiber[100]
    Fig. 22. CO2 gas detector based on Pr3+/Dy3+ co-doped Ga5Ge20Sb10S65 fiber[100]
    Detected CO2 signal using gas detector based on Pr3+/Dy3+co-doped Ga5Ge20Sb10S65 fiber[100]
    Fig. 23. Detected CO2 signal using gas detector based on Pr3+/Dy3+co-doped Ga5Ge20Sb10S65 fiber[100]
    IndexCorActiveIRFlexArt Photonics
    P/NIRT-SUIRT-SEIRF-SIRF-SeIRF-SeGCIR
    Core/cladAs2S3As2Se3As2S3As2Se3As2Se3/GeAs2S5As2S3
    Transmission range /μm2-62-91.5-6.51.5-101.5-9.31.1-6.5
    Core refractive index2.42.72.42.72.72.42
    Numerical aperture0.250.260.28-0.300.275-0.3500.760.25-0.30
    Typical loss /(dB·m-1)0.15@2.7 μm0.70@4.0 μm0.20@6 μm0.50@4.55 μm0.05@2.8 μm0.21@2.59 μm0.32@2 μm0.20@2.5-4 μm
    Core roundness /%< 1< 1<1<1--
    Concentricity deviation /μm< 5< 5<3<3--
    Tensile strength /kpsi> 15> 15>15>15->70
    Coatingmonolayer acrylatestainless steel/monolayer or multilayer polymersbilayer polymer
    Table 1. Performance parameters of typical commercial chalcogenide optical fibers[5-7]
    ComponentMass fraction /10-4ComponentMass fraction /10-4
    C≤0.600V<0.005
    O≤460.000Cr<0.005
    Na<0.005Mn<0.010
    Mg0.020Fe<0.050
    Al0.170Co<0.005
    Si4.000Ni<0.050
    SMatrixCu<0.050
    Cl65.000Zn<0.050
    K<0.050Ga<0.050
    Ca<0.050GeMatrix
    Ti<0.005Ce<0.005
    Table 2. Composition analysis results of Ge-S bulk glass prepared using chemical vapor deposition method[28](mass fraction, %)
    Haitao Guo, Jian Cui, Yantao Xu, Xusheng Xiao. Progress in Preparation and Applications of Low-Loss Chalcogenide Infrared Fibers[J]. Laser & Optoelectronics Progress, 2019, 56(17): 170606
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