Preparation and High Temperature Inorganic Transformation of Flexible Silicone Aerogels

Yi LUO; Shuhai XIA; Bo NIU; Yayun ZHANG; Donghui LONG

doi:10.15541/jim20220129

[1] J W SONG, C J CHEN, Z YANG et al. Highly compressible, anisotropic aerogel with aligned cellulose nanofibers. ACS Nano, 140(2018).

[2] X HAN, K T HASSAN, A HARVEY et al. Bioinspired synthesis of monolithic and layered aerogels. Advanced Materials, 1706294(2018). https://onlinelibrary.wiley.com/doi/10.1002/adma.201706294

[3] H H OU, P J YANG, L H LIN et al. Carbon nitride aerogels for the photoredox conversion of water. Angewandte Chemie International Edition, 10905-10910(2017). https://onlinelibrary.wiley.com/doi/10.1002/anie.201705926

[4] B CAI, V SAYEVICH, N GAPONIK et al. Emerging hierarchical aerogels: self-assembly of metal and semiconductor nanocrystals. Advanced Materials, 1707518(2018). https://onlinelibrary.wiley.com/doi/10.1002/adma.201707518

[5] M A KHALILY, H EREN, S AKBAYRAK et al. Facile synthesis of three-dimensional Pt-TiO2 nano-networks: a highly active catalyst for the hydrolytic dehydrogenation of ammonia-borane. Angewandte Chemie International Edition, 12257-12261(2016). https://onlinelibrary.wiley.com/doi/10.1002/anie.201605577

[6] K HAGEDORN, W LI, Q J LIANG et al. Catalytically doped semiconductors for chemical gas sensing: aerogel-like aluminum- containing zinc oxide materials prepared in the gas phase. Advanced Functional Materials, 3424-3437(2016). https://onlinelibrary.wiley.com/doi/10.1002/adfm.201505355

[7] H NICOLA, S ULRICH. Aerogels-airy materials: chemistry, structure, and properties. Angewandte Chemie International Edition, 22-45(1998). https://onlinelibrary.wiley.com/doi/10.1002/(SICI)1521-3773(19980202)37:1/2<22::AID-ANIE22>3.0.CO;2-I

[8] J BEAMISH, T HERMAN. Adsorption and desorption of helium in aerogels. Physica B Condensed Matter, 340-341(2003).

[9] T BELLUNATO, A BRAEM, A R BUZYKAEV et al. Aerogel as cherenkov radiator for rich detectors. Nuclear Inst & Methods in Physics Research A, 227-230(2003).

[10] S S KISTLER. Coherent expanded aerogel jellies. Nature, 741(1931).

[11] A DU, B ZHOU, Z ZHANG et al. A special material or new state of matter: a review and reconsideration of the aerogel. Materials, 941-968(2013). http://www.mdpi.com/1996-1944/6/3/941

[12] F HE, W J YU, M H FANG et al. An overview on silica aerogels synthesized by siloxane co-precursors. Journal of Inorganic Materials, 1243-1253(2015).

[13] D Y NADARGI, S S LATTHE, H HIRASHIMA et al. Studies on rheological properties of methyltriethoxysilane (MTES) based flexible superhydrophobic silica aerogels. Microporous & Mesoporous Materials, 617-626(2009).

[14] K KANAMORI, M AIZAWA, K NAKANISHI et al. New transparent methylsilsesquioxane aerogels and xerogels with improved mechanical properties. Advanced Materials, 1589-1593(2007). https://onlinelibrary.wiley.com/doi/10.1002/adma.200602457

[15] A V RAO, S D BHAGAT, H HIRASHIMA et al. Synthesis of flexible silica aerogels using methyltrimethoxysilane (MTMS) precursor. Journal of Colloid & Interface Science, 279-285(2006).

[16] G Q ZU, T SHIMIZU, K KANAMORI et al. Transparent, superflexible doubly cross-linked polyvinylpolymethylsiloxane aerogel superinsulators via ambient pressure drying. ACS Nano, 521-532(2018). https://pubs.acs.org/doi/10.1021/acsnano.7b07117

[17] G Q ZU, J SHEN, L P ZOU et al. Preparation, mechanical properties and thermal properties of elastic aerogels. Journal of Inorganic Materials, 417-422(2014).

[18] J Y HONG, B M BAK, J J WIE et al. Reversibly compressible, highly elastic, and durable graphene aerogels for energy storage devices under limiting conditions. Advanced Functional Materials, 1053-1062(2015). https://onlinelibrary.wiley.com/doi/10.1002/adfm.201403273

[19] G HAYASE, K KANAMORI, G HASEGAWA et al. A superamphiphobic macroporous silicone monolith with marshmallow- like flexibility. Angewandte Chemie International Edition, 10788-10791(2013). https://onlinelibrary.wiley.com/doi/10.1002/anie.201304169

[20] F X QIU, Y M ZHOU, J Z LIU et al. Study of 29Si MAS NMR spectroscopy and electro-optic property based on polyimide/SiO2. Photographic Science and Photochemistry, 55-60(2006).

[21] T SHIMIZU, K KANAMORI, A MAENO et al. Transparent ethylene-bridged polymethylsiloxane aerogels and xerogels with improved bending flexibility. Langmuir, 13427-13434(2016).

[22] Z ZHANG, X D WANG, J SHEN. Effect of organic-inorganic crosslinking degree on the mechanical and thermal properties of aerogels. Journal of Inorganic Materials, 454-460(2020).

[23] G Q ZU, K KANAMORI, X D WANG et al. Superelastic triple-network polyorganosiloxane-based aerogels as transparent thermal superinsulators and efficient separators. Chemistry of Materials, 1595-1604(2020). https://pubs.acs.org/doi/10.1021/acs.chemmater.9b04877

[24] N NAZERAN, J MOGHADDAS. Synthesis and characterization of silica aerogel reinforced rigid polyurethane foam for thermal insulation application. Journal of Non-Crystalline Solids, 1-11(2017). https://linkinghub.elsevier.com/retrieve/pii/S0022309317300510

[25] Z ZHANG, X D WANG, G Q ZU et al. Resilient, fire-retardant and mechanically strong polyimide-polyvinylpolymethylsiloxane composite aerogel prepared via stepwise chemical liquid deposition. Materials & Design, 108096(2019).

[26] Z Q CHEN, Y F CHEN, H B LIU. Pyrolysis of phenolic resin by TG-MS and FTIR analysis. Advanced Materials Research, 104-109(2013). https://www.scientific.net/AMR.631-632.104

[28] D M HUANG, C N GUO, M Z ZHANG et al. Characteristics of nanoporous silica aerogel under high temperature from 950 ℃ to 1200 ℃. Materials & Design, 82-90(2017).

[29] G X YANG, P BISWAS. Computer simulation of the aggregation and sintering restructuring of fractal-like clusters containing limited numbers of primary particles. Journal of Colloid & Interface Science, 142-150(1999).

[30] X K LI, L LIU, Y X ZHANG et al. Synthesis of nanometre silicon carbide whiskers from binary carbonaceous silica aerogels. Carbon, 159-165(2001). https://linkinghub.elsevier.com/retrieve/pii/S0008622300000208

[31] J MA, F YE, S J LIN et al. Large size and low density SiOC aerogel monolith prepared from triethoxyvinylsilane/tetraethoxysilane. Ceramics International, 5774-5780(2017). https://linkinghub.elsevier.com/retrieve/pii/S0272884217301487