Experimental study on reaction of H3O+(H2O)n(n = O～4) with methanol and ethanol

[in Chinese]; [in Chinese]; [in Chinese]; [in Chinese]; [in Chinese]; [in Chinese]

Journals >Chinese Journal of Quantum Electronics >Volume 21 >Issue 3 >Page 302 > Article

Chinese Journal of Quantum Electronics
Vol. 21, Issue 3, 302 (2004)

Experimental study on reaction of H₃O⁺(H₂O)_n(n = O～4) with methanol and ethanol

[in Chinese]^*, [in Chinese], [in Chinese], [in Chinese], [in Chinese], and [in Chinese]

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[in Chinese]

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DOI: Cite this Article

[in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese]. Experimental study on reaction of H₃O⁺(H₂O)_n(n = O～4) with methanol and ethanol[J]. Chinese Journal of Quantum Electronics, 2004, 21(3): 302 Copy Citation Text

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Abstract

By the reaction of water vapor with He+ and He* which were generated by hollow cathode discharge of helium, H3O+(H2O)n(n= 0-4) was produced. We studied the reactions of H₃O⁺(H₂O)_n(n= 0-4) with methanol and ethanol in a flowing afterglow mass spectrometer. Various ionic products were identified. They were formed by proton-transfer, ligand switching . association and condensation reactions.

Keywords

ethanol methanol flowing afterglow mass spectrometer spectroscopy

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