Author Affiliations
11. The Key Laboratory of Orogenic Belts and Crustal Evolution (MOE), School of Earth and Space Sciences, Peking University, Beijing 100871, China22. Golden Feature Science and Technology Ltd, Beijing 100095, Chinashow less
1. XRD patterns of fibrous brucite templated carbon nanotube CNT, CNT-N and CNT-N/S
2. Raman spectra of the fibrous brucite templated carbon nanotube CNT, CNT-N and CNT-N/S
3. (a-d) SEM and (e-h) TEM images of (a, e) fibrous brucite, fibrous brucite templated carbon nanotube (b, f) CNT, (c, g) CNT-N, (d, h) CNT-N/S
4. (a) Nitrogen adsorption-desorption isotherms and corresponding (b) BJH pore size distribution curves of the Fibrous Brucite templated carbon nanotube CNT, CNT-N and CNT-N/S
5. Fitting curves of (a) C1s, (b) N1s and (c) S2p for CNT-N/S
6. (a) CV curves at 100 mV·s-1, (b) GCD curves at 1 A·g-1, (c) cycling performance at 1 A·g-1 of CNT, CNT-N and CNT-N/S
7. (a) Specific capacitance versus current density, (b) cycling performance at 2 A·g-1 and (c) Nyquist plots of CNT//CNT, CNT-N//CNT-N and CNT-N/S//CNT-N/S with insert in (c) showing the corresponding enlarged view of the high frequency
S1. Schematic of preparation process for CNT-N/S
S2. XRD patterns of raw and dispersed Fibrous Brucite
S3. XPS spectra with the enlarged view of N1s peaks in the insert of Fibrous Brucite templated carbon nanotube CNT, CNT-N and CNT-N/S
S4. (a-c) CV curves at different scan rates and (d-f) GCD curves at different current densities of (a, d) CNT, (b, e) CNT-N and (c, f) CNT-N/S; (g) Nyquist plots of CNT, CNT-N and CNT-N/S with insert showing the corresponding equivalent circuit
S5. (a) Schematic structure of symmetric capacitor; (b-d) CV curves at different scan rates and (e-g) GCD curves at different current densities of (b, e) CNT//CNT, (c, f) CNT-N//CNT-N and (d, g) CNT-N/S//CNT-N/S
Sample | C/at% | O/at% | N/at% | S/at% |
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CNT | 87.34 | 12.66 | - | - | CNT-N | 84.93 | 13.62 | 1.45 | - | CNT-N/S | 89.68 | 8.15 | 0.74 | 1.43 |
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Table 1. Elemental composition of Fibrous Brucite templated carbon nanotube CNT, CNT-N and CNT-N/S
Sample | SBET/(m2∙g-1) | Smicropore/(m2∙g-1) | Vtotal/(cm3∙g-1) | Vmircropore/(cm3∙g-1) | Dap/nm |
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CNT | 505.5 | 273.5 | 0.381 | 0.125 | 3.02 | CNT-N | 245.1 | 131.3 | 0.213 | 0.060 | 3.48 | CNT-N/S | 224.8 | 63.8 | 0.267 | 0.028 | 4.75 |
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Table 1. Specific surface areas and pore structure parameters of fibrous brucite templated carbon nanotube CNT, CNT-N and CNT-N/S