• Journal of Inorganic Materials
  • Vol. 36, Issue 7, 711 (2021)
Fangfang LIU1, Xiuyun CHUAN1、*, Yang YANG1, and Aijun LI1、2
Author Affiliations
  • 11. The Key Laboratory of Orogenic Belts and Crustal Evolution (MOE), School of Earth and Space Sciences, Peking University, Beijing 100871, China
  • 22. Golden Feature Science and Technology Ltd, Beijing 100095, China
  • show less
    DOI: 10.15541/jim20200033 Cite this Article
    Fangfang LIU, Xiuyun CHUAN, Yang YANG, Aijun LI. Influence of N/S Co-doping on Electrochemical Property of Brucite Template Carbon Nanotubes[J]. Journal of Inorganic Materials, 2021, 36(7): 711 Copy Citation Text show less
    XRD patterns of fibrous brucite templated carbon nanotube CNT, CNT-N and CNT-N/S
    1. XRD patterns of fibrous brucite templated carbon nanotube CNT, CNT-N and CNT-N/S
    Raman spectra of the fibrous brucite templated carbon nanotube CNT, CNT-N and CNT-N/S
    2. Raman spectra of the fibrous brucite templated carbon nanotube CNT, CNT-N and CNT-N/S
    (a-d) SEM and (e-h) TEM images of (a, e) fibrous brucite, fibrous brucite templated carbon nanotube (b, f) CNT, (c, g) CNT-N, (d, h) CNT-N/S
    3. (a-d) SEM and (e-h) TEM images of (a, e) fibrous brucite, fibrous brucite templated carbon nanotube (b, f) CNT, (c, g) CNT-N, (d, h) CNT-N/S
    (a) Nitrogen adsorption-desorption isotherms and corresponding (b) BJH pore size distribution curves of the Fibrous Brucite templated carbon nanotube CNT, CNT-N and CNT-N/S
    4. (a) Nitrogen adsorption-desorption isotherms and corresponding (b) BJH pore size distribution curves of the Fibrous Brucite templated carbon nanotube CNT, CNT-N and CNT-N/S
    Fitting curves of (a) C1s, (b) N1s and (c) S2p for CNT-N/S
    5. Fitting curves of (a) C1s, (b) N1s and (c) S2p for CNT-N/S
    (a) CV curves at 100 mV·s-1, (b) GCD curves at 1 A·g-1, (c) cycling performance at 1 A·g-1 of CNT, CNT-N and CNT-N/S
    6. (a) CV curves at 100 mV·s-1, (b) GCD curves at 1 A·g-1, (c) cycling performance at 1 A·g-1 of CNT, CNT-N and CNT-N/S
    (a) Specific capacitance versus current density, (b) cycling performance at 2 A·g-1 and (c) Nyquist plots of CNT//CNT, CNT-N//CNT-N and CNT-N/S//CNT-N/S with insert in (c) showing the corresponding enlarged view of the high frequency
    7. (a) Specific capacitance versus current density, (b) cycling performance at 2 A·g-1 and (c) Nyquist plots of CNT//CNT, CNT-N//CNT-N and CNT-N/S//CNT-N/S with insert in (c) showing the corresponding enlarged view of the high frequency
    Schematic of preparation process for CNT-N/S
    S1. Schematic of preparation process for CNT-N/S
    XRD patterns of raw and dispersed Fibrous Brucite
    S2. XRD patterns of raw and dispersed Fibrous Brucite
    XPS spectra with the enlarged view of N1s peaks in the insert of Fibrous Brucite templated carbon nanotube CNT, CNT-N and CNT-N/S
    S3. XPS spectra with the enlarged view of N1s peaks in the insert of Fibrous Brucite templated carbon nanotube CNT, CNT-N and CNT-N/S
    (a-c) CV curves at different scan rates and (d-f) GCD curves at different current densities of (a, d) CNT, (b, e) CNT-N and (c, f) CNT-N/S; (g) Nyquist plots of CNT, CNT-N and CNT-N/S with insert showing the corresponding equivalent circuit
    S4. (a-c) CV curves at different scan rates and (d-f) GCD curves at different current densities of (a, d) CNT, (b, e) CNT-N and (c, f) CNT-N/S; (g) Nyquist plots of CNT, CNT-N and CNT-N/S with insert showing the corresponding equivalent circuit
    (a) Schematic structure of symmetric capacitor; (b-d) CV curves at different scan rates and (e-g) GCD curves at different current densities of (b, e) CNT//CNT, (c, f) CNT-N//CNT-N and (d, g) CNT-N/S//CNT-N/S
    S5. (a) Schematic structure of symmetric capacitor; (b-d) CV curves at different scan rates and (e-g) GCD curves at different current densities of (b, e) CNT//CNT, (c, f) CNT-N//CNT-N and (d, g) CNT-N/S//CNT-N/S
    SampleC/at%O/at%N/at%S/at%
    CNT87.3412.66--
    CNT-N84.9313.621.45-
    CNT-N/S89.688.150.741.43
    Table 1. Elemental composition of Fibrous Brucite templated carbon nanotube CNT, CNT-N and CNT-N/S
    SampleSBET/(m2∙g-1)Smicropore/(m2∙g-1)Vtotal/(cm3∙g-1)Vmircropore/(cm3∙g-1)Dap/nm
    CNT505.5273.50.3810.1253.02
    CNT-N245.1131.30.2130.0603.48
    CNT-N/S224.863.80.2670.0284.75
    Table 1. Specific surface areas and pore structure parameters of fibrous brucite templated carbon nanotube CNT, CNT-N and CNT-N/S
    Fangfang LIU, Xiuyun CHUAN, Yang YANG, Aijun LI. Influence of N/S Co-doping on Electrochemical Property of Brucite Template Carbon Nanotubes[J]. Journal of Inorganic Materials, 2021, 36(7): 711
    Download Citation