Author Affiliations
1School of Materials Science and Engineering, Heilongjiang University of Science and Technology, Harbin , Heilongjiang 150022, China2School of Materials Engineering, Shanghai University of Engineering Science, Shanghai 201620, Chinashow less
Fig. 1. Macro morphology of laser cladding coating. (a) Free graphene; (b) 1% graphene; (c) 2% graphene; (d) 3% graphene
Fig. 2. X-ray diffraction pattern of the coating
Fig. 3. Position of energy spectrum analysis for coating. (a) Position 1; (b) position 2; (c) position 3
Fig. 4. BSE morphology of coating interface. (a) Free graphene; (b) 1% graphene; (c) 2% graphene; (d) 3% graphene
Fig. 5. Cross-sectional line scanning of coating
Fig. 6. BSE photo of Ti-C-Nb coating cross section. (a) Bottom part of coating; (b) middle part of coating; (c) top part of coating
Fig. 7. BSE ptoto of Ti-C-Nb graphene at bottom of Ti-C-Nb-graphene coating cross section. (a) 1% graphene;
Fig. 8. BSE photo of Ti-C-Nb-graphene at middle of coating cross section. (a) 1% graphene; (b) 2% graphene; (c) 3% graphene
Fig. 9. BSE photo of Ti-C-Nb-graphene at top of coating cross section. (a) 1% graphene; (b) 2% graphene; (c) 3% graphene
Fig. 10. TEM and electron diffraction pattern of white granular phase in 2% graphene cladding coating. (a) TEM morphology; (b) electron diffraction pattern
Fig. 11. Microhardness curve of Ti-C-Nb-graphene coating
Element | Cr | B | Si | Fe | C | Ni |
---|
Mass fraction /% | 16 | 3.5 | 4.5 | ≤15 | 0.8 | Balance |
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Table 1. Chemical composition of Ni60A alloy powder
Number | Ni60A | C | Ti | Nb | Graphene |
---|
G1 | 80 | 4 | 12 | 4 | 0 | G2 | 80 | 4 | 11 | 4 | 1 | G3 | 80 | 4 | 10 | 4 | 2 | G4 | 80 | 4 | 9 | 4 | 3 |
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Table 2. Composition ratio of alloy powder (mass fraction)
Position | C | Si | Nb | Ti | Cr | Fe | Ni |
---|
P1 | 6.02 | 2.29 | 0.19 | 0.65 | 5.37 | 55.89 | 29.58 | P2 | 7.02 | 1.4 | 0 | 0.89 | 10.04 | 58.25 | 22.41 | P3 | 25.14 | 0.92 | 16.03 | 41.14 | 4.62 | 8.39 | 3.75 |
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Table 3. Chemical composition of different phases (mass fraction)
Position | C | Si | Nb | Ti | Cr | Fe | Ni |
---|
P1 | 22.73 | 3.70 | 0.09 | 0.62 | 4.68 | 45.35 | 22.83 | P2 | 25.74 | 2.20 | 0 | 0.81 | 8.50 | 45.94 | 16.81 | P3 | 60.49 | 0.95 | 4.99 | 24.82 | 2.57 | 4.34 | 1.85 |
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Table 4. Chemical composition of different phases (atomic fraction)
| | Coating | | Fusion line | | Substrate |
---|
XH1 | 687.28 | 642.25 | 674.77 | 640.36 | 431.41 | 199.63 | 195.95 | 189.65 | XH2 | 696.62 | 699.14 | 703.63 | 685.25 | 431.56 | 196.35 | 189.25 | 198.65 | XH3 | 828.55 | 782.17 | 773.74 | 705.63 | 487.90 | 213.02 | 207.95 | 209.54 | XH4 | 753.37 | 769.59 | 694.37 | 690.36 | 451.47 | 196.25 | 205.21 | 198.69 |
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Table 5. Microhardness test of Ti-C-Nb- graphene coating