This paper presents a novel approach to counterbalance free-carrier-absorption (FCA) in electro-optic (E-O) Mach–Zehnder interferometer (MZI) cells by harnessing the self-heating effect. We show insights on crosstalk limitations in MZIs with direct carrier-injection and provide a detailed design methodology on a differential phase shifter pair. Leveraging both free-carrier dispersion (FCD) and self-heating effects, our design enables arbitrary phase tuning with balanced FCA loss in the pair of arms, eliminating the need for additional phase corrections and creating ultralow crosstalk MZI elements. This neat design disengages from the commonly used nested structure, thus providing an opportunity of embedding tunable couplers for correcting imperfect splitting ratios given that only two are needed. We show that with the use of tunable directional couplers, a standard $\pm 10\mathrm{nm}$ process variation is tolerated, while achieving a crosstalk ratio below $-40\mathrm{dB}$. By direct carrier injection in both arms, the proposed device operates at nanosecond scales and can bring about a breakthrough in the scalability of E-O switch fabrics, as well as other silicon integrated circuits that have stringent requirements for crosstalk leakage.