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EDITORIAL|58 Article(s)
Dongfeng XUE, Liangbi SU, and Jun XU
Journal of Inorganic Materials
- Publication Date: Mar. 20, 2023
- Vol. 38, Issue 3, 225 (2023)
Prussian Blue Modified Biochar: Preparation and Adsorption of Ammonia Nitrogen from Sewage
Yefan YU, Ling XU, Zhongbing NI, Dongjian SHI, and Mingqing CHEN
Eutrophication caused by nitrogen, phosphorus and organic pollutants is a common problem which has attracted much attention in China. Ammonia nitrogen, as a main pollutant, should be removed efficiently to avoid the extension of eutrophication. In this research, Prussian Blue (PB), which can not only capture ammonia nitrogen by vacancy in crystal cell but also degrade organic pollutants by Fenton oxidation, was combined with modified biochar to increase efficiency of ammonia nitrogen removal. Several characterization methods were used to investigate the structure and morphologies of the biochar composite. Adsorption capacity of biochar composite material (BC700-PB) was tested by NH4Cl solution. The results show that the maximum adsorption capacity to ammonia nitrogen is 24.4 mg/g and the removal efficiency is over 95% within 60 min under the condition of pH 8, which is 101.3% higher than that of the unmodified biochar. The adsorption mechanism of BC700-PB was investigated with Langmuir model and pseudo-second-order kinetic equation which reveal that the adsorption including physical adsorption by biochar and coordination adsorption by PB. Meanwhile, Fenton oxidation process is conducted by PB nanoparticles in the biochar composite material with existence of H2O2. The biochar composite material could catalyze H2O2 to generate ?OH, and achieve degradation of organic pollutants and adsorption of ammonia nitrogen. The PB/biochar composite material can be recycled easily by NaCl solution for several times. In conclusion, the PB/biochar composite is a promising material for eliminating multi-component eutrophication wastewater. Eutrophication caused by nitrogen, phosphorus and organic pollutants is a common problem which has attracted much attention in China. Ammonia nitrogen, as a main pollutant, should be removed efficiently to avoid the extension of eutrophication. In this research, Prussian Blue (PB), which can not only capture ammonia nitrogen by vacancy in crystal cell but also degrade organic pollutants by Fenton oxidation, was combined with modified biochar to increase efficiency of ammonia nitrogen removal. Several characterization methods were used to investigate the structure and morphologies of the biochar composite. Adsorption capacity of biochar composite material (BC700-PB) was tested by NH4Cl solution. The results show that the maximum adsorption capacity to ammonia nitrogen is 24.4 mg/g and the removal efficiency is over 95% within 60 min under the condition of pH 8, which is 101.3% higher than that of the unmodified biochar. The adsorption mechanism of BC700-PB was investigated with Langmuir model and pseudo-second-order kinetic equation which reveal that the adsorption including physical adsorption by biochar and coordination adsorption by PB. Meanwhile, Fenton oxidation process is conducted by PB nanoparticles in the biochar composite material with existence of H2O2. The biochar composite material could catalyze H2O2 to generate ?OH, and achieve degradation of organic pollutants and adsorption of ammonia nitrogen. The PB/biochar composite material can be recycled easily by NaCl solution for several times. In conclusion, the PB/biochar composite is a promising material for eliminating multi-component eutrophication wastewater.
Journal of Inorganic Materials
- Publication Date: Feb. 20, 2023
- Vol. 38, Issue 2, 205 (2023)
YBa2Cu3O7-δ Thin Film: Preparation by BaCl2/BaF2-MOD Method and Superconducting Property
Mingyue CHEN, Zhichao YAN, Jing CHEN, Minjuan LI, Zhiyong LIU, and Chuanbing CAI
Conventional trifluoroacetic acid metal organic chemical solution deposition (TFA-MOD) method for the preparation of YBa2Cu3O7-δ (YBCO) superconducting layers follows the BaF2 growth mechanism. In this work, a novel chemical solution method based on BaCl2/BaF2 pathway for the growth of YBCO superconducting thin films was carried out. The effects of Cl addition on grain orientation, microstructure and superconductivity of YBCO thin films were investigated, and mechanism of the phase transition of YBCO thin films in the BaCl2 pathway was explored by thermochemical calculations of the growth reaction. The results show that the Cl addition inhibits a-axis grain orientation and promotes nucleation of c-axis grains. Onset transition temperature (Tc-onset) of the YBCO 2-layer film is about 89.6 K without significant change after Cl addition. But its critical current density (Jc) is significantly increased to 2.07 MA/cm2 (77 K, self-field). Meanwhile, the phase transition of the growth reaction process shows that Cl is preferentially combined with Ba to form BaCl2 as much as possible, effectively avoiding the formation of BaCO3. All results of this study indicate that Cl addition facilitates preparation of YBCO superconducting thick films, and provides a new idea for the preparation of YBCO by MOD method. Conventional trifluoroacetic acid metal organic chemical solution deposition (TFA-MOD) method for the preparation of YBa2Cu3O7-δ (YBCO) superconducting layers follows the BaF2 growth mechanism. In this work, a novel chemical solution method based on BaCl2/BaF2 pathway for the growth of YBCO superconducting thin films was carried out. The effects of Cl addition on grain orientation, microstructure and superconductivity of YBCO thin films were investigated, and mechanism of the phase transition of YBCO thin films in the BaCl2 pathway was explored by thermochemical calculations of the growth reaction. The results show that the Cl addition inhibits a-axis grain orientation and promotes nucleation of c-axis grains. Onset transition temperature (Tc-onset) of the YBCO 2-layer film is about 89.6 K without significant change after Cl addition. But its critical current density (Jc) is significantly increased to 2.07 MA/cm2 (77 K, self-field). Meanwhile, the phase transition of the growth reaction process shows that Cl is preferentially combined with Ba to form BaCl2 as much as possible, effectively avoiding the formation of BaCO3. All results of this study indicate that Cl addition facilitates preparation of YBCO superconducting thick films, and provides a new idea for the preparation of YBCO by MOD method.
Journal of Inorganic Materials
- Publication Date: Feb. 20, 2023
- Vol. 38, Issue 2, 199 (2023)
Fabrication of Transparent AlON by Gel Casting and Pressureless Sintering
Xihai JIN, Manjiang DONG, Yanmei KAN, Bo LIANG, and Shaoming DONG
Transparent AlON possesses good mechanical and optical properties, which shows great potential for application. However, high fabrication cost seriously restricts its wide usage. To solve this problem, gel-casting and pressureless sintering of transparent AlON was tentatively studied here, with emphasis on low temperature synthesis and anti-hydrolysis treatment of AlON powder. It was found that fine AlON powder could be readily synthesized at a low temperature of 1700 ℃ by a novel carbothermal nitridation technique, using polymer coated AlN/Al2O3 mixture as the starting materials. The powder obtained was submicron in size and its hydrolysis resistance could be significantly improved after surface coating with a polyurethane layer. On the basis of these findings, transparent AlON ceramics was successfully prepared through gel-casting and pressureless sintering. The material sintered at 1850 ℃ showed good optical and mechanical properties, with a high in-line transmittance of 83.1%-86.2% from ultraviolet to mid-infrared and three-point bending strength of 310 MPa. Transparent AlON possesses good mechanical and optical properties, which shows great potential for application. However, high fabrication cost seriously restricts its wide usage. To solve this problem, gel-casting and pressureless sintering of transparent AlON was tentatively studied here, with emphasis on low temperature synthesis and anti-hydrolysis treatment of AlON powder. It was found that fine AlON powder could be readily synthesized at a low temperature of 1700 ℃ by a novel carbothermal nitridation technique, using polymer coated AlN/Al2O3 mixture as the starting materials. The powder obtained was submicron in size and its hydrolysis resistance could be significantly improved after surface coating with a polyurethane layer. On the basis of these findings, transparent AlON ceramics was successfully prepared through gel-casting and pressureless sintering. The material sintered at 1850 ℃ showed good optical and mechanical properties, with a high in-line transmittance of 83.1%-86.2% from ultraviolet to mid-infrared and three-point bending strength of 310 MPa.
Journal of Inorganic Materials
- Publication Date: Feb. 20, 2023
- Vol. 38, Issue 2, 193 (2023)
Effects of Carbon Sources on Structure and Properties of TaC Ceramic Powder Prepared by Polymer Derived Ceramics
Jingwei SUN, Honglei WANG, Chuhan SUN, Xingui ZHOU, and Xiaoyu JI
Polymer derived ceramic is one of the effective methods for producing ultra-high temperature ceramics and powders, but effect of source material type on precursor cross-linking degree and ceramic yield has rarely been reported. Here, TaC precursors were synthesized using two carbon sources and poly-tantalumoxane (PTO). Phase composition and microstructure of TaC ceramic powders from different carbon sources, tantalum/carbon mass ratios, and pyrolysis temperatures were characterized. It was found that PF-3 resin with C=C was effective in promoting the cross-linking of PTO and increasing the ceramic yield. When the mass ratio of PTO to PF-3 Resin was 1 : 0.25 and PTO to 2402 Resin was 1 : 0.4, TaC ceramic powders could be obtained at 1400 ℃ without residue Ta2O5. Ceramic yields of ceramic powders were 54.02% and 49.64%, and the crystal sizes were 47.2 and 60.9 nm, respectively. Therefore, PF-3 resin is able to reduce crystal size while increasing ceramic yield, but has less impact on the powder purity and particle size. The purity of TaC ceramic powders derived from different carbon sources are 96.50% and 97.36%, respectively, meanwhile the median diameters are 131 and 129 nm, respectively. Polymer derived ceramic is one of the effective methods for producing ultra-high temperature ceramics and powders, but effect of source material type on precursor cross-linking degree and ceramic yield has rarely been reported. Here, TaC precursors were synthesized using two carbon sources and poly-tantalumoxane (PTO). Phase composition and microstructure of TaC ceramic powders from different carbon sources, tantalum/carbon mass ratios, and pyrolysis temperatures were characterized. It was found that PF-3 resin with C=C was effective in promoting the cross-linking of PTO and increasing the ceramic yield. When the mass ratio of PTO to PF-3 Resin was 1 : 0.25 and PTO to 2402 Resin was 1 : 0.4, TaC ceramic powders could be obtained at 1400 ℃ without residue Ta2O5. Ceramic yields of ceramic powders were 54.02% and 49.64%, and the crystal sizes were 47.2 and 60.9 nm, respectively. Therefore, PF-3 resin is able to reduce crystal size while increasing ceramic yield, but has less impact on the powder purity and particle size. The purity of TaC ceramic powders derived from different carbon sources are 96.50% and 97.36%, respectively, meanwhile the median diameters are 131 and 129 nm, respectively.
Journal of Inorganic Materials
- Publication Date: Feb. 20, 2023
- Vol. 38, Issue 2, 184 (2023)
Tensile Creep Behavior of Cansas-II SiCf/SiC Composites at High Temperatures
Kaikai JING, Haoyang GUAN, Siyu ZHU, Chao ZHANG, Yongsheng LIU, Bo WANG, Jing WANG, Mei LI, and Chengyu ZHANG
Continuous silicon carbide fiber reinforced silicon carbide composite (SiCf/SiC) is a key material for the advanced aero-engines. It is required to possess excellent high-temperature creep resistance for SiCf/SiC to meet the long-term service lifetime of the aero-engines. Here, tensile creep behaviors of a plain woven Cansas-II SiCf/SiC (2D-SiCf/SiC) were investiged in the temperature of 1200-1400 ℃ with the stress levels of 80 to 140 MPa. Its microstructure and fracture morphology were observed, and composition was analyzed. Results show that creep-rupture time of 2D-SiCf/SiC is more than 500 h and steady-state creep rate is 1×10-10-5×10-10 /s at stresses lower than the proportional limit stress (σPLS). The creep behaviors are controlled by matrix and fibers. The creep-rupture time is significantly reduced, and the steady-state creep rate is increased by an order of magnitude when the stress is higher than the σPLS. The matrix, fibers and interfaces of the composite are greatly oxidized, and the creep behaviors are mainly controlled by the fibers. Continuous silicon carbide fiber reinforced silicon carbide composite (SiCf/SiC) is a key material for the advanced aero-engines. It is required to possess excellent high-temperature creep resistance for SiCf/SiC to meet the long-term service lifetime of the aero-engines. Here, tensile creep behaviors of a plain woven Cansas-II SiCf/SiC (2D-SiCf/SiC) were investiged in the temperature of 1200-1400 ℃ with the stress levels of 80 to 140 MPa. Its microstructure and fracture morphology were observed, and composition was analyzed. Results show that creep-rupture time of 2D-SiCf/SiC is more than 500 h and steady-state creep rate is 1×10-10-5×10-10 /s at stresses lower than the proportional limit stress (σPLS). The creep behaviors are controlled by matrix and fibers. The creep-rupture time is significantly reduced, and the steady-state creep rate is increased by an order of magnitude when the stress is higher than the σPLS. The matrix, fibers and interfaces of the composite are greatly oxidized, and the creep behaviors are mainly controlled by the fibers.
Journal of Inorganic Materials
- Publication Date: Feb. 20, 2023
- Vol. 38, Issue 2, 177 (2023)
Effect of Recombination Time on the Structure and Properties of P2O5-Al2O3 Heterogeneous Composite Glass
Qingong ZHU, Gaoling ZHAO, and Gaorong HAN
In recent years, phase separation glass has attracted extensive attention because of its unique structure and excellent properties. But its mechanism of phase separation on glass remains insufficient clear, especially, the influence of recombination time on structure and properties is unclear. Here, strengthened P2O5-Al2O3 glass with SiO2-Na2O high-silicate glass particles as the second phase was prepared by melting-quenching method combined with pneumatic atomization and mechanical stirring. The relationship between structure and mechanical properties of the glass was investigated by varying the recombination time. Experiment results showed that Young's modulus of the heterogeneous composite glass was higher than that of the P2O5-Al2O3 glass. Young's modulus of the sample firstly increased and then decreased with the recombination time increasing from 10 s to 8 min. The highest Young's modulus of 80.7 GPa was obtained at recombination time of 6 min, which was increased by 18% as compared with the P2O5-Al2O3 glass. Introducing SiO2-Na2O high-silicate glass particles not only formed the second phase in the matrix glass, but also changed the structure of the P2O5-Al2O3 glass. As the recombination time increases from 10 s to 6 min, coordination number of phosphorus in heterogeneous composite glass network gradually increases, while amount of non-bridging oxygen in the glass network gradually decreases, resulting in a gradual increase in network cross-linking. However, when the recombination time is more than 8 min, it is not conducive to network crosslinking. Therefore, development of heterogeneous composite glass can provide a new route for the preparation of glass materials with good damage resistance. In recent years, phase separation glass has attracted extensive attention because of its unique structure and excellent properties. But its mechanism of phase separation on glass remains insufficient clear, especially, the influence of recombination time on structure and properties is unclear. Here, strengthened P2O5-Al2O3 glass with SiO2-Na2O high-silicate glass particles as the second phase was prepared by melting-quenching method combined with pneumatic atomization and mechanical stirring. The relationship between structure and mechanical properties of the glass was investigated by varying the recombination time. Experiment results showed that Young's modulus of the heterogeneous composite glass was higher than that of the P2O5-Al2O3 glass. Young's modulus of the sample firstly increased and then decreased with the recombination time increasing from 10 s to 8 min. The highest Young's modulus of 80.7 GPa was obtained at recombination time of 6 min, which was increased by 18% as compared with the P2O5-Al2O3 glass. Introducing SiO2-Na2O high-silicate glass particles not only formed the second phase in the matrix glass, but also changed the structure of the P2O5-Al2O3 glass. As the recombination time increases from 10 s to 6 min, coordination number of phosphorus in heterogeneous composite glass network gradually increases, while amount of non-bridging oxygen in the glass network gradually decreases, resulting in a gradual increase in network cross-linking. However, when the recombination time is more than 8 min, it is not conducive to network crosslinking. Therefore, development of heterogeneous composite glass can provide a new route for the preparation of glass materials with good damage resistance.
Journal of Inorganic Materials
- Publication Date: Feb. 20, 2023
- Vol. 38, Issue 2, 170 (2023)
Effect of Surface Treatment of n-type Bi2Te3-based Materials on the Properties of Thermoelectric Units
Siheng HUA, Dongwang YANG, Hao TANG, Xiong YUAN, Ruoyu ZHAN, Zhuoming XU, Jianan LYU, Yani XIAO, Yonggao YAN, and Xinfeng TANG
The smaller the size of the Bi2Te3-based micro thermoelectric device, the more significant the effect of interface bonding strength and contact resistance on the mechanical properties, open circuit voltage and output power of the device. It is of great significance to develop a thermoelectric unit preparation technology with low cost and simple process, and to enable the interface between n-type Bi2Te3 bulk materials and barrier layer with low contact resistance and high bonding strength. Here, surface of n-type Bi2Te3-based thermoelectric material was treated in mixed acid solution (pH~3), followed by electroless plating Ni (5 μm), and then welded with Cu electrode to prepare thermoelectric unit. After corrosion, the anchoring effect between large gully on the surface of n-type Bi2Te3-based thermoelectric materials and Ni barrier layer contributes to the interface bonding strength of 15.88 MPa for the material corroded for 6 min. Furthermore, nano-holes between the Ni barrier layer and the fine branches corroded by further corrosion significantly increase the interface contact resistance, resulting in 2.23 μΩ?cm2 for the material corroded for 2 min. Finally, the output power of the micro thermoelectric device prepared by n-type Bi2Te3-based bulk material for 4 min corrosion treatment is as high as 3.43 mW at 20 K temperature difference (306 K at high temperature end and 286 K at low temperature end). Compared to device with the same size prepared by commercial electroplating coating, the output power is increased by 31.92%. This work provides support to optimize the performance of micro thermoelectric devices. The smaller the size of the Bi2Te3-based micro thermoelectric device, the more significant the effect of interface bonding strength and contact resistance on the mechanical properties, open circuit voltage and output power of the device. It is of great significance to develop a thermoelectric unit preparation technology with low cost and simple process, and to enable the interface between n-type Bi2Te3 bulk materials and barrier layer with low contact resistance and high bonding strength. Here, surface of n-type Bi2Te3-based thermoelectric material was treated in mixed acid solution (pH~3), followed by electroless plating Ni (5 μm), and then welded with Cu electrode to prepare thermoelectric unit. After corrosion, the anchoring effect between large gully on the surface of n-type Bi2Te3-based thermoelectric materials and Ni barrier layer contributes to the interface bonding strength of 15.88 MPa for the material corroded for 6 min. Furthermore, nano-holes between the Ni barrier layer and the fine branches corroded by further corrosion significantly increase the interface contact resistance, resulting in 2.23 μΩ?cm2 for the material corroded for 2 min. Finally, the output power of the micro thermoelectric device prepared by n-type Bi2Te3-based bulk material for 4 min corrosion treatment is as high as 3.43 mW at 20 K temperature difference (306 K at high temperature end and 286 K at low temperature end). Compared to device with the same size prepared by commercial electroplating coating, the output power is increased by 31.92%. This work provides support to optimize the performance of micro thermoelectric devices.
Journal of Inorganic Materials
- Publication Date: Feb. 20, 2023
- Vol. 38, Issue 2, 163 (2023)
Evolution of Electric Field and Breakdown Damage Morphology for Flexible PDMS Based Dielectric Composites
Lei CHEN, and Hailong HU
Compared with other electric energy storage devices, dielectric capacitors made of dielectric composites have great advantages in fast charging and discharging capacity with high power density. A dilemma of improving the energy density of dielectric composites and synchronous optimizing their breakdown performance is becoming an intriguing research direction. To further adjust the contradiction between dielectric constant and dielectric breakdown performance, here a finite element numerical simulation based on dielectric breakdown model (DBM) was proposed to study the effect of the distribution of inorganic fillers on the electric field and breakdown damage morphology in flexible polydimethylsiloxane(PDMS) based dielectric composite system. The results show that a large dielectric difference is observed between filler and matrix, which indicates that polymer matrix with a large dielectric constant or inorganic filler with a small dielectric constant can realize reducing the size of the high electric field area at the interface and improving the breakdown resistance of the material. This study further reveals that the more dispersed structure of inorganic fillers, the more likely its dendritic damage channels tend to branch, indicating that this situation is conducive to the increase of damage sites of dielectric breakdown dendritic damage channels, the decrease of damage rate, and the improvement of breakdown resistance of materials. All above data demonstrate that this study provides certain guidance for the development of organic-inorganic dielectric composites with both high energy storage and excellent breakdown performance. Compared with other electric energy storage devices, dielectric capacitors made of dielectric composites have great advantages in fast charging and discharging capacity with high power density. A dilemma of improving the energy density of dielectric composites and synchronous optimizing their breakdown performance is becoming an intriguing research direction. To further adjust the contradiction between dielectric constant and dielectric breakdown performance, here a finite element numerical simulation based on dielectric breakdown model (DBM) was proposed to study the effect of the distribution of inorganic fillers on the electric field and breakdown damage morphology in flexible polydimethylsiloxane(PDMS) based dielectric composite system. The results show that a large dielectric difference is observed between filler and matrix, which indicates that polymer matrix with a large dielectric constant or inorganic filler with a small dielectric constant can realize reducing the size of the high electric field area at the interface and improving the breakdown resistance of the material. This study further reveals that the more dispersed structure of inorganic fillers, the more likely its dendritic damage channels tend to branch, indicating that this situation is conducive to the increase of damage sites of dielectric breakdown dendritic damage channels, the decrease of damage rate, and the improvement of breakdown resistance of materials. All above data demonstrate that this study provides certain guidance for the development of organic-inorganic dielectric composites with both high energy storage and excellent breakdown performance.
Journal of Inorganic Materials
- Publication Date: Feb. 20, 2023
- Vol. 38, Issue 2, 155 (2023)
Effects of Al3+ Doping on the Structure and Electrical Transport Property of La0.8Sr0.2Mn1-xAlxO3
Aimei ZHANG, Jiajia ZHU, Tiancheng FANG, and Xixi PAN
As a colossal magnetoresistance material, the perovskite manganese oxide La1–xSrxMnO3 (LSMO) has broad application prospects in magnetic sensors and other fields. However, it is difficult to obtain a significant colossal magnetoresistance effect at a low magnetic field at room temperature. To improve its magnetoresistance effect and transition temperature, La0.8Sr0.2Mn1–xAlxO3 (0≤x≤0.25) (LSMAO) polycrystalline samples were prepared by traditional solid-state reaction method in present work. Effects of Al3+ doping on the electrical transport property and magnetoresistance of LSMO were systematically analyzed. The X-ray diffraction (XRD) results indicate that all samples crystallize in a single rhombohedral structure with the space group of $\text{R}\bar{3}\text{C}$. Result of electrical transport property shows that resistivity of the samples increases exponentially with the increment of Al3+ doping amount, and the metal-insulator transition temperature is increased by an external magnetic field. This phenomenon may be attributed to dilution of the Mn3+/Mn4+ ions network by Al3+, which increases the magnetic disorder but reduces the number of carriers. In addition, the conduction mechanism of LSMAO ceramics change from the small polaron hopping model (SPH) to the variable range hopping model (VRH) after doping of Al3+, reflecting that the non-magnetic Al3+ weakens the carrier exchange between the ferromagnetic clusters. As a result, the thermally activated neighbor transition of small polarons is suppressed. Magnetoresistance effect of LSMAO is enhanced from 21.03% to 59.71% with x increasing from 0 to 0.25, which proves that the doping of Al3+can effectively enhance the magnetoresistance effect of LSMAO. As a colossal magnetoresistance material, the perovskite manganese oxide La1–xSrxMnO3 (LSMO) has broad application prospects in magnetic sensors and other fields. However, it is difficult to obtain a significant colossal magnetoresistance effect at a low magnetic field at room temperature. To improve its magnetoresistance effect and transition temperature, La0.8Sr0.2Mn1–xAlxO3 (0≤x≤0.25) (LSMAO) polycrystalline samples were prepared by traditional solid-state reaction method in present work. Effects of Al3+ doping on the electrical transport property and magnetoresistance of LSMO were systematically analyzed. The X-ray diffraction (XRD) results indicate that all samples crystallize in a single rhombohedral structure with the space group of $\text{R}\bar{3}\text{C}$. Result of electrical transport property shows that resistivity of the samples increases exponentially with the increment of Al3+ doping amount, and the metal-insulator transition temperature is increased by an external magnetic field. This phenomenon may be attributed to dilution of the Mn3+/Mn4+ ions network by Al3+, which increases the magnetic disorder but reduces the number of carriers. In addition, the conduction mechanism of LSMAO ceramics change from the small polaron hopping model (SPH) to the variable range hopping model (VRH) after doping of Al3+, reflecting that the non-magnetic Al3+ weakens the carrier exchange between the ferromagnetic clusters. As a result, the thermally activated neighbor transition of small polarons is suppressed. Magnetoresistance effect of LSMAO is enhanced from 21.03% to 59.71% with x increasing from 0 to 0.25, which proves that the doping of Al3+can effectively enhance the magnetoresistance effect of LSMAO.
Journal of Inorganic Materials
- Publication Date: Feb. 20, 2023
- Vol. 38, Issue 2, 148 (2023)
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