• Chinese Journal of Quantum Electronics
  • Vol. 41, Issue 3, 514 (2024)
CHANG Jiawei1,*, WANG Yarui1, MA Xinrong1, Han Weiwei1..., Zhang Guoding1, LU Quanfang2 and SUN Duixiong1|Show fewer author(s)
Author Affiliations
  • 1College of Phsics and Electronic Engineering, Northwest Normal University, Lanzhou 730070, China
  • 2College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China
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    DOI: 10.3969/j.issn.1007-5461.2024.03.013 Cite this Article
    Jiawei CHANG, Yarui WANG, Xinrong MA, Weiwei Han, Guoding Zhang, Quanfang LU, Duixiong SUN. Quantitative detection of Cu element in Yellow River water based on LIBS⁃GD combined technology[J]. Chinese Journal of Quantum Electronics, 2024, 41(3): 514 Copy Citation Text show less
    Specific location of sample collection
    Fig. 1. Specific location of sample collection
    Schematic diagram of LIBS-GD combined technology experimental device
    Fig. 2. Schematic diagram of LIBS-GD combined technology experimental device
    Optimization of discharge voltage of LIBS-GD combined experiment
    Fig. 3. Optimization of discharge voltage of LIBS-GD combined experiment
    Optimization of laser parameters for LIBS-GD combined experiment. (a) H I 656.24 nm emission spectrum intensity change with delay time; (b) H I 656.24 nm emission spectrum intensity change with laser energy
    Fig. 4. Optimization of laser parameters for LIBS-GD combined experiment. (a) H I 656.24 nm emission spectrum intensity change with delay time; (b) H I 656.24 nm emission spectrum intensity change with laser energy
    #3 sample Spectrum (insert: Cu element spectrum of the five samples)
    Fig. 5. #3 sample Spectrum (insert: Cu element spectrum of the five samples)
    Calibration curve of Cu I 327.45 nm under internal standard method (insert: copper fitting curve in the concentration range of 0.7-12.5 mg/L)
    Fig. 6. Calibration curve of Cu I 327.45 nm under internal standard method (insert: copper fitting curve in the concentration range of 0.7-12.5 mg/L)
    SampleValue by LIBS-GD/(mg⋅L-1)Value by AAS/(mg⋅L-1)Difference value/(mg⋅L-1)Relative error/%
    #10.340.360.025.6
    #20.290.320.039.4
    #30.330.350.025.7
    #40.270.290.026.9
    #50.380.410.037.3
    Table 1. Comparison between internal standard method and AAS
    Jiawei CHANG, Yarui WANG, Xinrong MA, Weiwei Han, Guoding Zhang, Quanfang LU, Duixiong SUN. Quantitative detection of Cu element in Yellow River water based on LIBS⁃GD combined technology[J]. Chinese Journal of Quantum Electronics, 2024, 41(3): 514
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