• Journal of Inorganic Materials
  • Vol. 34, Issue 7, 791 (2019)
Xiao-Ying LI1、2, Qiang LIU2, Ze-Wang HU1、3, Nan JIANG1、3, Yun SHI1, and Jiang LI1、3、*
Author Affiliations
  • 1Key Laboratory of Transparent Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
  • 2School of Material Science and Engineering, Jiangsu University, Zhenjiang 212013, China
  • 3Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
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    DOI: 10.15541/jim20180574 Cite this Article
    Xiao-Ying LI, Qiang LIU, Ze-Wang HU, Nan JIANG, Yun SHI, Jiang LI. Influence of Ammonium Hydrogen Carbonate to Metal Ions Molar Ratio on Co-precipitated Nanopowders for TGG Transparent Ceramics[J]. Journal of Inorganic Materials, 2019, 34(7): 791 Copy Citation Text show less

    Abstract

    Terbium gallium garnet (TGG) ceramics were successfully fabricated by air sintering at 1500 ℃ for 3 h combined with HIP post-treating at 1550 ℃ for 3 h under 150 MPa argon gas, where the TGG powders were synthesized by the co-precipitation method employing ammonium hydrogen carbonate (AHC) as precipitant. The influences of ammonium hydrogen carbonate to metal ions molar ratio (R value) on phase composition and morphology of the resultant powders as well as optical transmittance and Verdet constant of the TGG ceramics were investigated systematically. The precursors with R=3.6, 4.0 and 4.4 calcined at 1100 ℃ form pure TGG phase, whereas the precursor with R=3.2 treated at the same temperature yields the mixed phases of TGG and Ga2O3. The TGG powder with R=4.0 shows the best dispersity and homogeneity, giving rise to ceramic with the best optical quality. On the contrary, the powder with R=4.4 exhibits a strong agglomeration, which is closely related to the morphology of its precursor. High quality TGG transparent ceramics with the transmittance of 80.1% at 1064 nm can be fabricated by the nanopowder with R=4.0, and the Verdet constant of the TGG ceramics at 633 nm is rather close to that of the commercial TGG single crystals (-134 rad·T -1·m -1).
    Xiao-Ying LI, Qiang LIU, Ze-Wang HU, Nan JIANG, Yun SHI, Jiang LI. Influence of Ammonium Hydrogen Carbonate to Metal Ions Molar Ratio on Co-precipitated Nanopowders for TGG Transparent Ceramics[J]. Journal of Inorganic Materials, 2019, 34(7): 791
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