• Journal of Inorganic Materials
  • Vol. 34, Issue 2, 186 (2019)
Yun GONG1、2, Yan LIU3, Ping GU1, Yu-Fang ZHU2, Xiao-Xia ZHOU3, [in Chinese]1、2, [in Chinese]3, [in Chinese]1, [in Chinese]2, and [in Chinese]3
Author Affiliations
  • 11. Department of Printing and Packing, Shanghai Publishing and Printing College, Shanghai 200093, China
  • 22. School of Material Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China
  • 33. Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
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    DOI: 10.15541/jim20180209 Cite this Article
    Yun GONG, Yan LIU, Ping GU, Yu-Fang ZHU, Xiao-Xia ZHOU, [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese]. Synthesis of Nano Manganese Oxide with Assistance of Ultrasonic for Removal of Low Concentration NO[J]. Journal of Inorganic Materials, 2019, 34(2): 186 Copy Citation Text show less
    Effect of process parameters of the sample MnOx on the NO catalytic removal performance (a) Ultrasonic time; (b) Reactants concentration; (c) Dry temperature; (d) pH
    . Effect of process parameters of the sample MnOx on the NO catalytic removal performance
    (a) Ultrasonic time; (b) Reactants concentration; (c) Dry temperature; (d) pH
    XRD patterns of MnOx-20-0.5-80-7 before and after calcination (a) and corresponding N2 adsorption-desorption curves and the distribution of pore size (b)
    . XRD patterns of MnOx-20-0.5-80-7 before and after calcination (a) and corresponding
    N2 adsorption-desorption curves and the distribution of pore size (b)
    SEM (a-b) and TEM (c) images and the corresponding (d) SAED pattern of MnOx-20-0.5-80-7
    . SEM (a-b) and TEM (c) images and the corresponding (d) SAED pattern of MnOx-20-0.5-80-7
    XPS spectra of the sample MnOx-20-0.5-80-7 before and after catalytic test(a) Mn2p3/2, before; (b) Mn2p3/2, after; (c) O1s, before; (d) O1s, after
    . XPS spectra of the sample MnOx-20-0.5-80-7 before and after catalytic test
    (a) Mn2p3/2, before; (b) Mn2p3/2, after; (c) O1s, before; (d) O1s, after
    Catalytic performance of the sample MnOx-20-0.5-80-7 on low-concentration NO removal ratio at room temperature (Reaction conditions: [NO]=10 cm3/m3, [O2]=21%, N2, 25 ℃ and GHSV = 120000 mL•h-1•g-1)
    . Catalytic performance of the sample MnOx-20-0.5-80-7 on low-concentration NO removal ratio at room temperature (Reaction conditions: [NO]=10 cm3/m3, [O2]=21%, N2, 25 ℃ and GHSV = 120000 mL•h-1•g-1)
    FT-IR spectra of MnOx-20-0.5-80-7 before and after catalytic test
    . FT-IR spectra of MnOx-20-0.5-80-7 before and after catalytic test
    The possible catalytic process of MnOx toward NO oxidation
    . The possible catalytic process of MnOx toward NO oxidation
    ElementPhaseBefore testAfter test
    Binding energy/eVPercentage/%Binding energy/eVPercentage/%
    Mn-surfaceMn2+641.24.8641.14.1
    Mn3+642.526.7642.537.6
    Mn4+643.566.5643.558.3
    Mn-etch 10 sMn2+640.913.5640.810.8
    Mn3+642.154.0642.156.5
    Mn4+644.332.5644.332.7
    O-surfaceOlat530.154.5530.164.0
    Oads531.545.5531.836.0
    O-etch 10 sOlat530.178.5530.070.2
    Oads531.521.5531.529.8
    Table 1. XPS data of catalyst MnOx-20-0.5-80-7 before and after the NO removal test
    Yun GONG, Yan LIU, Ping GU, Yu-Fang ZHU, Xiao-Xia ZHOU, [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese]. Synthesis of Nano Manganese Oxide with Assistance of Ultrasonic for Removal of Low Concentration NO[J]. Journal of Inorganic Materials, 2019, 34(2): 186
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