• Chinese Optics Letters
  • Vol. 21, Issue 5, 051602 (2023)
Cong Zhang1, Yunru Chen1, Shihui Ma1、*, Honghua Fan1, Yonggui Yu1、**, Zhanggui Hu1, Ning Ye1, Jiyang Wang2, and Yicheng Wu1
Author Affiliations
  • 1Tianjin Key Laboratory of Functional Crystal Materials, Institute of Functional Crystals, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China
  • 2State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China
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    DOI: 10.3788/COL202321.051602 Cite this Article Set citation alerts
    Cong Zhang, Yunru Chen, Shihui Ma, Honghua Fan, Yonggui Yu, Zhanggui Hu, Ning Ye, Jiyang Wang, Yicheng Wu. Effective warm white-light emission with Dy:YAlO3 single crystal[J]. Chinese Optics Letters, 2023, 21(5): 051602 Copy Citation Text show less
    Energy-level diagram of Dy3+ systems.
    Fig. 1. Energy-level diagram of Dy3+ systems.
    (a) Photographs and test samples of Dy:YAP crystal with a doping concentration of 1%; (b) XRD patterns of 1% Dy:YAP crystal and standard ICSD 4115.
    Fig. 2. (a) Photographs and test samples of Dy:YAP crystal with a doping concentration of 1%; (b) XRD patterns of 1% Dy:YAP crystal and standard ICSD 4115.
    Crystal structure of YAP crystal.
    Fig. 3. Crystal structure of YAP crystal.
    (a) Absorption spectra of Dy:YAP single crystals; (b) excitation spectra of Dy:YAP crystals with different doping concentrations; (c) PL spectra of Dy:YAP crystals with different doping concentrations and excited at 350 nm; (d) PL spectra of Dy:YAP crystals with different doping concentrations and excited at 450 nm.
    Fig. 4. (a) Absorption spectra of Dy:YAP single crystals; (b) excitation spectra of Dy:YAP crystals with different doping concentrations; (c) PL spectra of Dy:YAP crystals with different doping concentrations and excited at 350 nm; (d) PL spectra of Dy:YAP crystals with different doping concentrations and excited at 450 nm.
    CIE chromaticity coordinates of Dy:YAP crystals with different exciting wavelengths and doping concentrations.
    Fig. 5. CIE chromaticity coordinates of Dy:YAP crystals with different exciting wavelengths and doping concentrations.
    (a) Schematic of the Dy:YAP white light; (b) white-light spectrum; (c) CIE chromaticity coordinates.
    Fig. 6. (a) Schematic of the Dy:YAP white light; (b) white-light spectrum; (c) CIE chromaticity coordinates.
    (a) PLQY with the excited wavelength of 350 nm; (b) PLQY with the excited wavelength of 450 nm; (c) PLQY with different doping concentrations; (d) luminescent lifetime of 1% Dy:YAP crystal.
    Fig. 7. (a) PLQY with the excited wavelength of 350 nm; (b) PLQY with the excited wavelength of 450 nm; (c) PLQY with different doping concentrations; (d) luminescent lifetime of 1% Dy:YAP crystal.
    CrystalsEfficiency (%)
    Dy:YAP46.9
    Dy:YAG[7]39.2
    Dy:YVO4[22]7
    Dy:Lu3Al5O12[23]21.7
    Dy, Eu:Ca2ZnSiO7[24]12.88
    Dy:LiCaBO3[25]25
    Dy:Ca3Si2O7[26]15.16
    Dy:LiLuF4[11]16.6
    Table 1. Fluorescence Quantum Efficiency of Various Dy3+-Doped Crystals
    Cong Zhang, Yunru Chen, Shihui Ma, Honghua Fan, Yonggui Yu, Zhanggui Hu, Ning Ye, Jiyang Wang, Yicheng Wu. Effective warm white-light emission with Dy:YAlO3 single crystal[J]. Chinese Optics Letters, 2023, 21(5): 051602
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